摘要:
A photosensitive member having at least two electrically operative layers is disclosed. The first layer comprises a photoconductive layer which is capable of photogenerating holes and injecting photogenerated holes into a contiguous charge transport layer. The charge transport layer comprises an electrically inactive organic resinous material containing from about 10 to about 75 percent by weight of: ##STR1## R.sub.1 is selected from the group consisting of hydrogen (ortho) CH.sub.3, (meta) CH.sub.3, (para) CH.sub.3, and R.sub.2 is selected from the group consisting of hydrogen, (ortho) CH.sub.3, (meta) CH.sub.3, and (para) CH.sub.3. The charge transport layer while substantially non-absorbing in the spectral region of intended use is "active" in that it allows injection of photogenerated holes from the photoconductive layer, and allows these holes to be transported through the charge transport layer. This structure may be imaged in the conventional xerographic mode which usually includes charging, exposure to light and development.
摘要:
A photosensitive member having at least two electrically operative layers is disclosed. The first layer comprises a photoconductive layer which is capable of photogenerating holes and injecting photogenerated holes into a contiguous charge transport layer. The charge transport layer comprises a polycarbonate resin containing from about 25 to about 75 percent by weight of one or more of a compound having a general formula: ##STR1## wherein R is selected from the group consisting of an alkyl group having from 1 to about 4 carbon atoms and chlorine in the ortho, meta or para position. This structure may be imaged in the conventional xerographic mode which usually includes charging, exposure to light and development.
摘要:
A conductive polymer composition selected from the group consisting ofa first composition includinga polymer containing halomethylated aromatic groups, anda charge transporting material selected from the group consisting ofat least one charge transport monomer containing arylamine groups,at least one charge transport polymer containing arylamine units in the main polymer chain,and mixtures thereof, anda second composition includingat least one monomer containing a halomethylated aromatic group,at least one charge transport monomer containing arylamine groups anda polymer binder, anda third composition including:at least one monomer containing a halomethylated aromatic group, andat least one charge transport polymer with arylamine units in the main polymer chain.The aforementioned compositions may be applied as coatings and used in high speed laser printing and related printing processes. These conductive polymeric compositions and processes therefor provide improved stability and a broad range of conductivities, manufacturing and compositional latitude, and dielectric strength.
摘要:
A photosensitive member having at least two electrically operative layers is disclosed. The first layer comprises a photoconductive layer which is capable of photogenerating holes and injecting photogenerated holes into a contiguous charge transport layer. The charge transport layer comprises an electrically inactive organic resinous material containing from about 15 to about 75 percent by weight of N,N'-diphenyl-N,N'-bis(phenylmethyl)-[1,1'-biphenyl]-4,4'-diamine. The charge transport layer while substantially non-absorbing in the spectral region of intended use is "active" in that it allows injection of photogenerated holes from the photoconductive layer, and allows these holes to be transported through the charge transport layer. This structure may be imaged in the conventional xerographic mode which usually includes charging, exposure to light and development.
摘要:
An imaging member comprising a charge generation layer comprising a layer of photoconductive material and a contiguous charge transport layer of a polycarbonate resin material having dispersed therein from about 25 to about 75 percent by weight of one or more diamine compound having the general formula: ##STR1## wherein X.sub.1 and X.sub.2 are independently selected from the group consisting of a lower alkyl group having from 1 to about 4 carbon atoms, chlorine in the ortho, meta or para position, a para phenyl group and combinations thereof.
摘要:
A photosensitive member having at least two electrically operative layers is disclosed. The first layer comprises an electrically conductive layer. The second layer comprises a charge transport layer. The third layer is a photoconductive layer contiguous with the transport layer. The photoconductive layer is capable of photogenerating and injecting photogenerated holes into the contiguous or adjacent electrically active part. The electrically active material comprises a polycarbonate resin material having dispersed therein from about 25 to 75 percent by weight of one or more compounds having the general formula: ##STR1## wherein X is selected from the group consisting of an alkyl group having from 1 to about 4 carbon atoms (e.g. methyl, ethyl, propyl, butyl, etc.) and chlorine in the ortho, meta or para position. This structure may be imaged in the conventional xerographic mode which usually includes charging, exposure to light and development.
摘要:
A photosensitive member having at least two electrically operative layers is disclosed. The first layer comprises a photoconductive layer which is capable of photogenerating holes and injecting photogenerated holes into a contiguous charge transport layer. The charge transport layer comprises an electrically inactive organic resinous material containing from about 10 to about 75 percent by weight of: ##STR1## where R.sub.1 is selected from the group consisting of an alkyl with from 1 to 12 carbon atoms and an alkyl with from 1 to 12 carbon atoms substituted by aryl groups selected from the group consisting of phenyl, maphthyl, anthryl, and biphenyl and R.sub.2 is selected from the group consisting of methyl, ethyl, chloro, bromo and hydrogen. The charge transport layer while substantially non-absorbing in the spectral region of intended use is "active" in that it allows injection of photogenerated holes from the photoconductive layer, and allows these holes to be transported through the charge transport layer. This structure may be imaged in the conventional xerographic mode which usually includes charging, exposure to light and development.
摘要:
A photosensitive member having at least two electrically operative layers is disclosed. The first layer comprises a photoconductive layer which is capable of photogenerating holes and injecting photogenerated holes into a contiguous charge transport layer. The charge transport layer comprises a polycarbonate resin containing from about 25 to about 75 percent by weight of one or more of a compound having the general formula: ##STR1## wherein X is selected from the group consisting of an alkyl group having from 1 to about 4 carbon atoms (e.g. methyl, ethyl, propyl, butyl, etc.) and chlorine in the ortho, meta or para position. This structure may be imaged in the conventional xerographic mode which usually includes charging, exposure to light and development.
摘要:
Process for preparation of 2-anthryl and substituted 2-anthryl functional monomers and polymers. In the process for preparation of these monomers, an anthracenic reactant of the formula: ##STR1## wherein X and Y are independently selected from hydrogen, chlorine, bromine, alkyl of 1 to 4 carbon atoms or phenylIs acylated in nitrobenzene under conditions which favor reaction at the two position. The resulting acylated product can then be (a) reacted with an alkylidenephosphorane (Wittig synthesis) or (b) reduced to the corresponding alcohol. Subsequent to such reduction, this alcohol can undergo further modification at the hydroxyl function to form a polymerizable addition monomer. Through the proper selection of the relative concentration of reactants and control over processing conditions, it is possible not only to prepare such monomers in high yields but also upon polymerization of such monomers, to obtain high molecular weight 2-anthryl and substituted 2-anthryl functional polymers (molecular weight of at least 10.sup.4). Polymers of such high molecular weight can readily be formed without the use of binders into self-supporting films. Such films are intrinsically photoconductive in the ultraviolet region of the electromagnetic spectrum and have good transport capabilities for charge carriers of both polarities.
摘要:
Process for preparation of 2-anthryl and substituted 2-anthryl functional monomers and polymers. In the process for preparation of these monomers, an anthracenic reactant of the formula: ##STR1## wherein X and Y are independently selected from hydrogen, chlorine, bromine, alkyl of 1 to 4 carbon atoms or phenylIs acylated in nitrobenzene under conditions which favor reaction at the two position. The resulting acylated product can then be (a) reacted with an alkylidenephosphorane (Wittig synthesis) or (b) reduced to the corresponding alcohol. Subsequent to such reduction, this alcohol can undergo further modification at the hydroxyl function to form a polymerizable addition monomer. Through the proper selection of the relative concentration of reactants and control over processing conditions, it is possible not only to prepare such monomers in high yields but also upon polymerization of such monomers, to obtain high molecular weight 2-anthryl and substituted 2-anthryl functional polymers (molecular weight of at least 10.sup.4). Polymers of such high molecular weight can readily be formed without the use of binders into self-supporting films. Such films are intrinsically photoconductive in the ultraviolet region of the electromagnetic spectrum and have good transport capabilities for charge carriers of both polarities.