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    Photographic element with dye-forming coupler and stabilizing compound
    1.
    发明授权
    Photographic element with dye-forming coupler and stabilizing compound 失效
    具有染料成色剂和稳定化合物的摄影元件

    公开(公告)号：US06444412B1

    公开(公告)日：2002-09-03

    申请号：US09934107

    申请日：2001-08-21

    申请人： David Clarke ,  Llewellyn J. Leyshon ,  Christopher P. Moore

    发明人： David Clarke ,  Llewellyn J. Leyshon ,  Christopher P. Moore

    IPC分类号： G03C1100

    CPC分类号： G03C7/39288 ,  G03C7/34 ,  G03C7/36 ,  G03C7/38 ,  G03C7/384 ,  G03C7/3885

    摘要： The invention relates to a photographic element comprising a light sensitive silver halide emulsion layer having associated therewith one or more dye-forming couplers and a stabilizer compound of formula (I): wherein R1 and R2 are independently selected from hydrogen or an unsubstituted or substituted alkyl, aryl, alkoxy, aryloxy or amino group or may combine to complete a 5-10 membered heterocyclic ring which may contain in addition to the silicon atom one or more heteroatoms selected from nitrogen, oxygen and sulfur, which ring is unsubstituted or substituted; each Z independently represents the atoms necessary to complete a substituted or unsubstituted arene or heteroaromatic ring system; X is a single bond or a linking group having a single atom which connects the arene rings or heteroaromatic ring systems; or X forms, together with substituents ortho to X on the arene rings or heteroaromatic ring systems, a fused unsubstituted or substituted 5-, 6- or 7-membered ring, which may contain one or two heteroatoms selected from nitrogen, oxygen and sulfur. The stabilizer is used to enhance the image stability of the dye formed from a cyan, magenta or yellow dye-forming coupler without significantly degrading other photographic properties.

    摘要翻译： 本发明涉及一种照相元件，其包含与其相关联的一种或多种成色成色剂的光敏卤化银乳剂层和式（I）的稳定剂化合物：其中R 1和R 2独立地选自氢或未取代或取代的烷基， 芳基，烷氧基，芳氧基或氨基，或者可以结合形成5-10元杂环，除了硅原子外还可以含有一个或多个选自氮，氧和硫的杂原子，该环是未取代的或被取代的;每个Z 独立地表示完成取代或未取代的芳族或杂芳族环系统所必需的原子; X是单键或具有连接芳环或杂芳族环系的单个原子的连接基团; 或与X取代基在芳烃环或杂芳族环系统上的取代基，稠合的未取代或取代的5-，6-或7-元环，其可含有一个或两个选自氮，氧和硫的杂原子。 稳定剂用于增强由青色，品红色或黄色染料形成成色剂形成的染料的图像稳定性，而不会显着降低其它照相性能。

    Photographic couplers having improved image dye light stability
    3.
    发明授权
    Photographic couplers having improved image dye light stability 失效
    具有改善的图像染料光稳定性的照相成色剂

    公开(公告)号：US06699650B1

    公开(公告)日：2004-03-02

    申请号：US09856396

    申请日：2001-05-22

    申请人： David Clarke ,  Llewellyn J. Leyshon ,  Katie E. Smith

    发明人： David Clarke ,  Llewellyn J. Leyshon ,  Katie E. Smith

    IPC分类号： G03C746

    CPC分类号： C07C311/08 ,  G03C7/346

    摘要： There is provided a photographic element comprising at least one silver halide emulsion layer having associated therewith a novel phenolic cyan dye-forming coupler of formula (I) wherein X is hydrogen or a group that can be split off by the reaction of the coupler with an oxidised colour developing agent, and one of Y and Z is the group  wherein each R is independently an unsubstituted or substituted alkyl or aryl group or a 5-10 membered heterocyclic ring which contains one or more heteroatoms selected from nitrogen, oxygen and sulfur, which ring is unsubstituted or substituted; R1 is hydrogen or an unsubstituted or substituted alkyl or aryl group, R2 is an unsubstituted or substituted alkyl or aryl group or a 5-10 membered heterocyclic ring which contains one or more heteroatoms selected from nitrogen, oxygen and sulfur, which ring is unsubstituted or substituted; R3 is hydrogen or an unsubstituted or substituted alkyl or aryl group, n is 1 or 2, and the other of Y and Z is an unsubstituted or substituted alkyl or aryl group or a 5-10 membered heterocyclic ring which contains one or more heteroatoms selected from nitrogen, oxygen and sulfur, which ring is unsubstituted or substituted. The couplers for use in the element of the invention yield cyan images of good hue, with good stability to heat, humidity and light, whilst retaining the other properties desirable for good photographic performance.

    摘要翻译： 提供了一种照相元件，其包含至少一个卤化银乳剂层，其具有式（I）的新型酚类青色染料形成成色剂，其中X是氢或可以通过成色剂与氧化的反应分离的基团 颜色显影剂，Y和Z的一个是基团，其中R独立地是未取代或取代的烷基或芳基或含有一个或多个选自氮，氧和硫的杂原子的5-10元杂环，该环是未取代的或 取代的; R1是氢或未取代或取代的烷基或芳基，R2是未取代或取代的烷基或芳基或含有一个或多个选自氮，氧和硫的杂原子的5-10元杂环，该环是 未取代或取代的; R3是氢或未取代或取代的烷基或芳基，n是1或2，Y和Z中的另一个是未取代的或 取代的烷基或芳基或含有一个或多个选自氮，氧和硫的杂原子的5-10元杂环，该环是未取代或取代的。用于本发明元件的成色剂产生良好色调的青色图像 对于热，湿度和光线具有良好的稳定性，同时保持其它性能对于良好的照相性能是理想的。

    High contrast photographic element containing a novel nucleator
    6.
    发明授权
    High contrast photographic element containing a novel nucleator 失效
    含有新型成核剂的高对比度照相元件

    公开(公告)号：US06245480B1

    公开(公告)日：2001-06-12

    申请号：US09591774

    申请日：2000-06-12

    申请人： Judith A. Bogie ,  Philip J. Coldrick ,  John D. Goddard ,  Llewellyn J. Leyshon

    发明人： Judith A. Bogie ,  Philip J. Coldrick ,  John D. Goddard ,  Llewellyn J. Leyshon

    IPC分类号： G03C108

    CPC分类号： G03C1/061 ,  G03C2001/108

    摘要： The invention relates to an ultrahigh contrast photographic material comprising a support bearing a silver halide emulsion layer, containing a hydrazide nucleating agent in the emulsion layer or a hydrophilic colloid layer, characterised in that the nucleating agent of formula (I) comprises (a) two nicotinamide moieties, which may be the same or different, which are linked by a linking group, and (b) a hydrazide moiety linked to only one of the nicotinamide moieties. The nucleator of formula (I) may be in combination with a nucleator of formula (II) which comprises a dimeric molecule comprising two monomers linked by a linking group, each monomer of which (a) may be the same or different and (b) comprises a hydrazide moiety and a nicotinamide moiety. The photographic material provides unexpectedly good nucleation in the absence of, or with reduced amounts of, booster and in a developer whose pH is variable, and further with lower chemical spread and pepper fog. When the synthesis provides both a compound of formula (I) and (II), the products can be used directly without a separation step, providing a cost advantage.

    摘要翻译： 本发明涉及一种超高对比度照相材料，其特征在于，式（I）的成核剂包括：（a）两个（II）的成核剂，其特征在于，所述超高对比度照相材料包含载体，所述载体含有在所述乳剂层中的酰肼成核剂或亲水胶体层的卤化银乳剂层， 烟酰胺部分，其可以相同或不同，其通过连接基团连接，和（b）仅与一个烟酰胺部分连接的酰肼部分。 式（I）的成核剂可以与式（II）的成核剂组合，其包含包含通过连接基团连接的两个单体的二聚体分子，其各自的单体（a）可以相同或不同，和（b） 包含酰肼部分和烟酰胺部分。照相材料在不存在或具有减少量的助催化剂和在pH可变的显影剂中进一步具有较低的化学扩散和胡椒雾的情况下提供出人意料的良好成核。 当合成提供式（I）和（II）的化合物时，可以直接使用产物而不进行分离步骤，从而提供成本优势。

    Bisphenol derivative stabilizers
    7.
    发明授权
    Bisphenol derivative stabilizers 失效
    双酚衍生物稳定剂

    公开(公告)号：US4782011A

    公开(公告)日：1988-11-01

    申请号：US035970

    申请日：1987-04-08

    申请人： John D. Goddard ,  Nigel E. Milner ,  Llewellyn J. Leyshon

    发明人： John D. Goddard ,  Nigel E. Milner ,  Llewellyn J. Leyshon

    IPC分类号： G03C7/26 ,  C07C43/23 ,  G03C7/32 ,  G03C7/392 ,  G03C1/34

    CPC分类号： C07C43/23 ,  G03C7/39216

    摘要： A photographic element comprising a support having thereon at least one silver halide emulsion layer having associated therewith a dye-forming coupler and a dye stabilizer comprising a bisphenol derivative having two linked phenol rings, one of the phenolic hydroxy groups being substituted and at least one of the phenol rings being substituted.In a preferred embodiment, the bisphenol derivative has the following formula: ##STR1## wherein A is a substituted or unsubstituted alkyl, cycloalkyl, alkenyl, aryl, acyl, alkylsulfonyl or arylsulfonyl group;X is a single bond or a linking group selected from alkylidene, a heteroatom or sulfonyl; and,each R independently represents one or more substituents, each substituent independently being a substituted or unsubstituted alkyl, alkenyl, cycloalkyl or aryl group; or each R in combination with the benzene ring to which it is attached independently represents the atoms necessary to complete a fused ring system.

    摘要翻译： 一种照相元件，包括其上具有至少一个卤化银乳剂层的载体，所述卤化银乳剂层具有染料形成成色剂和染料稳定剂，所述染料稳定剂包含具有两个连接的酚环的双酚衍生物，一个酚羟基被取代，以及至少一个 酚环被取代。 在优选的实施方案中，双酚衍生物具有下式：其中A是取代或未取代的烷基，环烷基，烯基，芳基，酰基，烷基磺酰基或芳基磺酰基; X是单键或选自亚烷基，杂原子或磺酰基的连接基团; 每个R独立地表示一个或多个取代基，每个取代基独立地是取代或未取代的烷基，烯基，环烷基或芳基; 或每个R与其所连接的苯环组合，独立地表示完成稠环体系所必需的原子。

    Photographic element with yellow dye-forming coupler and stabilizing compounds
    8.
    发明授权
    Photographic element with yellow dye-forming coupler and stabilizing compounds 失效
    具有黄色染料成色剂和稳定化合物的摄影元件

    公开(公告)号：US06312881B1

    公开(公告)日：2001-11-06

    申请号：US09483396

    申请日：2000-01-14

    申请人： Danuta Gibson ,  James S. Honan ,  Llewellyn J. Leyshon ,  Thomas A. Rosiek ,  Brian Thomas

    发明人： Danuta Gibson ,  James S. Honan ,  Llewellyn J. Leyshon ,  Thomas A. Rosiek ,  Brian Thomas

    IPC分类号： G03C108

    CPC分类号： G03C7/3013 ,  G03C7/30535 ,  G03C7/36 ,  G03C7/362 ,  G03C7/367 ,  G03C7/39236 ,  G03C7/39276

    摘要： In accordance with one embodiment of the invention, a photographic element is disclosed comprising a silver halide emulsion layer having associated therewith an acetanilide-based yellow dye forming coupler and a stabilizer compound of the formula S-I: wherein R0 represents an aryl or heterocyclic group; Ra is H or a substituent group; L represents an alkylene linking group and p represents 0 or 1; and Rb is a substituent group, provided that substituent groups represented by Ra and Rb may be joined to form a ring. The presence of substituted amine compounds of formula S-I improves the efficiency of dye formation reaction for acetanilide-based couplers. When used in combination with known bis-phenolic stabilizers, substantial improvements in the light stability of the image dyes can be also be obtained. Accordingly, photographic elements of the present invention upon exposure and photographic processing exhibit good activity and yield yellow dye images that have low fading when exposed to light.

    摘要翻译： 根据本发明的一个实施方案，公开了一种照相材料，其包含卤化银乳剂层，其具有与基于乙酰苯胺的黄色染料形成成色剂和式S-I的稳定剂化合物：其中R 0表示芳基或杂环基; Ra是H或取代基; L表示亚烷基连接基团，p表示0或1; 并且R b是取代基，条件是由R a和R b表示的取代基可以连接形成环。 式S-1的取代的胺化合物的存在提高了基于乙酰苯胺的成色剂的染料形成反应的效率。 当与已知的双酚稳定剂组合使用时，也可以获得图像染料的光稳定性的显着改善。 因此，本发明的照相元件在曝光和照相处理时表现出良好的活性，并产生当暴露于光时具有低褪色的黄色染料图像。

    Image dye-forming couplers and photographic elements containing them
    9.
    发明授权
    Image dye-forming couplers and photographic elements containing them 失效
    图像染料形成成色剂和含有它们的摄影元件

    公开(公告)号：US6071683A

    公开(公告)日：2000-06-06

    申请号：US131851

    申请日：1998-08-07

    申请人： John D. Goddard ,  Danuta Gibson ,  Llewellyn J. Leyshon ,  Brian Thomas

    发明人： John D. Goddard ,  Danuta Gibson ,  Llewellyn J. Leyshon ,  Brian Thomas

    IPC分类号： C07C235/80 ,  C07C311/08 ,  C07D263/44 ,  G03C7/30 ,  G03C7/305 ,  G03C7/36 ,  G03C7/392 ,  G03C1/08

    CPC分类号： C07D263/44 ,  C07C235/80 ,  C07C311/08 ,  G03C7/3013 ,  G03C7/30535 ,  G03C7/36 ,  G03C7/39216

    摘要： The present invention relates to a silver halide photographic element comprising a dye-forming coupler of formula (I) ##STR1## wherein R.sup.1 is selected from an alkyl group, an aryl group, a 5-10 membered heterocyclic group containing one or more O, N or S atoms, each of which groups is unsubstituted or substituted, or a substituted amino group;R.sup.2 is an unsubstituted alkyl group having a secondary or tertiary carbon atom attached to the oxygen atom;X is hydrogen or a coupling-off group; andR.sup.3 is a substituent and n is 0 to 4; orwherein R.sup.2, as defined above, and an R.sup.3 substituent may together with the O atom form a 5-10 membered heterocyclic group which may contain one or more further heteroatoms selected from O, N and S, said group being unsubstituted or substituted; andwherein at least one of R.sup.1, R.sup.2 and R.sup.3 separately or in combination constitutes a ballast group,the couplers providing enhanced light stability together with acceptable dye hue in images produced from photographic materials containing them.

    摘要翻译： 本发明涉及一种卤化银照相元件，其包含式（I）的染料形成成色剂，其中R 1选自烷基，芳基，含有一个或多个O，N或S的5-10元杂环基 原子，其各自为未取代或取代的基团，或取代的氨基; R2是与氧原子连接的具有仲或叔碳原子的未取代的烷基; X是氢或偶合离去基团; R3为取代基，n为0〜4; 或其中如上定义的R 2和R 3取代基可以与O原子一起形成5-10元杂环基团，其可以含有一个或多个另外的选自O，N和S的杂原子，所述基团是未取代的或取代的; 并且其中R 1，R 2和R 3中的至少一个分别或组合构成镇流器基团，所述成色剂提供增强的光稳定性以及由含有它们的照相材料产生的图像中可接受的染料色调。