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    Photographic element with yellow dye-forming coupler and stabilizing compounds
    1.
    发明授权
    Photographic element with yellow dye-forming coupler and stabilizing compounds 失效
    具有黄色染料成色剂和稳定化合物的摄影元件

    公开(公告)号：US06312881B1

    公开(公告)日：2001-11-06

    申请号：US09483396

    申请日：2000-01-14

    申请人： Danuta Gibson ,  James S. Honan ,  Llewellyn J. Leyshon ,  Thomas A. Rosiek ,  Brian Thomas

    发明人： Danuta Gibson ,  James S. Honan ,  Llewellyn J. Leyshon ,  Thomas A. Rosiek ,  Brian Thomas

    IPC分类号： G03C108

    CPC分类号： G03C7/3013 ,  G03C7/30535 ,  G03C7/36 ,  G03C7/362 ,  G03C7/367 ,  G03C7/39236 ,  G03C7/39276

    摘要： In accordance with one embodiment of the invention, a photographic element is disclosed comprising a silver halide emulsion layer having associated therewith an acetanilide-based yellow dye forming coupler and a stabilizer compound of the formula S-I: wherein R0 represents an aryl or heterocyclic group; Ra is H or a substituent group; L represents an alkylene linking group and p represents 0 or 1; and Rb is a substituent group, provided that substituent groups represented by Ra and Rb may be joined to form a ring. The presence of substituted amine compounds of formula S-I improves the efficiency of dye formation reaction for acetanilide-based couplers. When used in combination with known bis-phenolic stabilizers, substantial improvements in the light stability of the image dyes can be also be obtained. Accordingly, photographic elements of the present invention upon exposure and photographic processing exhibit good activity and yield yellow dye images that have low fading when exposed to light.

    摘要翻译： 根据本发明的一个实施方案，公开了一种照相材料，其包含卤化银乳剂层，其具有与基于乙酰苯胺的黄色染料形成成色剂和式S-I的稳定剂化合物：其中R 0表示芳基或杂环基; Ra是H或取代基; L表示亚烷基连接基团，p表示0或1; 并且R b是取代基，条件是由R a和R b表示的取代基可以连接形成环。 式S-1的取代的胺化合物的存在提高了基于乙酰苯胺的成色剂的染料形成反应的效率。 当与已知的双酚稳定剂组合使用时，也可以获得图像染料的光稳定性的显着改善。 因此，本发明的照相元件在曝光和照相处理时表现出良好的活性，并产生当暴露于光时具有低褪色的黄色染料图像。

    Photographic elements containing blend of cyan dye-forming couplers
    2.
    发明授权
    Photographic elements containing blend of cyan dye-forming couplers 失效
    含有青色染料成色剂的混合物的照相元件

    公开(公告)号：US06261755B1

    公开(公告)日：2001-07-17

    申请号：US09514632

    申请日：2000-02-28

    申请人： Danuta Gibson ,  James S. Honan ,  Thomas A. Rosiek

    发明人： Danuta Gibson ,  James S. Honan ,  Thomas A. Rosiek

    IPC分类号： G03C108

    CPC分类号： G03C7/342 ,  G03C1/34 ,  G03C1/815 ,  G03C7/3006 ,  G03C7/3212 ,  G03C7/34 ,  G03C7/3885 ,  G03C7/39216 ,  G03C7/39256

    摘要： The invention provides a photographic element comprising at least one light-sensitive silver halide emulsion layer having associated therewith: (A) a phenolic cyan dye-forming narrow bandwidth “NB coupler”; (B) a phenolic cyan dye-forming coupler of formula (II): wherein: R3 is an unsubstituted or substituted alkyl or aryl group or a 5-10 membered heterocyclic ring which contains one or more heteroatoms selected from nitrogen, oxygen and sulfur, which ring is unsubstituted or substituted; R4 is an unsubstituted or substituted alkyl group; R5 is hydrogen, halogen or an unsubstituted or substituted alkyl or aryl group or a 5-10 membered heterocyclic ring which contains one or more heteroatoms selected from nitrogen, oxygen and sulfur, which ring is unsubstituted or substituted; and Z is a hydrogen atom or a group which can be split off by the reaction of the coupler with an oxidized color-developing agent; and (C) a stabilizer of formula (III) wherein: each Y is an independently selected substituent and m is 0 to 4; and each T is an independently selected substituent and p is 0 to 4. Preferably the element has associated therewith one or more high-boiling solvents of formula (IV) wherein: R1 is an unsubstituted or substituted alkyl or aryl group; and G is an unsubstituted or substituted alkyl group.

    摘要翻译： 本发明提供了一种照相元件，其包含至少一种与之相关的感光卤化银乳剂层：（A）形成苯酚青色染料的窄带宽“NB成色剂”;（B）式（B）的酚青色染料成色剂 II）：其中：R3是未取代或取代的烷基或芳基或含有一个或多个选自氮，氧和硫的杂原子的5-10元杂环，该环是未取代或取代的; R4是未取代或取代的 烷基; R5是氢，卤素或未取代或取代的烷基或芳基或含有一个或多个选自氮，氧和硫的杂原子的5-10元杂环，该环是未取代的或被取代的; Z为氢原子或可通过偶合剂与氧化显色剂的反应而分离的基团; 和（C）式（III）的稳定剂，其中：每个Y是独立选择的取代基，m是0-4; 所述T是独立选择的取代基，p是0至4.优选所述元素与一种或多种式（Ⅳ）的高沸点溶剂缔合，其中：R 1为未取代或取代的烷基或芳基; G是未取代或取代的烷基。

    Image dye-forming couplers and photographic elements containing them
    3.
    发明授权
    Image dye-forming couplers and photographic elements containing them 失效
    图像染料形成成色剂和含有它们的摄影元件

    公开(公告)号：US6071683A

    公开(公告)日：2000-06-06

    申请号：US131851

    申请日：1998-08-07

    申请人： John D. Goddard ,  Danuta Gibson ,  Llewellyn J. Leyshon ,  Brian Thomas

    发明人： John D. Goddard ,  Danuta Gibson ,  Llewellyn J. Leyshon ,  Brian Thomas

    IPC分类号： C07C235/80 ,  C07C311/08 ,  C07D263/44 ,  G03C7/30 ,  G03C7/305 ,  G03C7/36 ,  G03C7/392 ,  G03C1/08

    CPC分类号： C07D263/44 ,  C07C235/80 ,  C07C311/08 ,  G03C7/3013 ,  G03C7/30535 ,  G03C7/36 ,  G03C7/39216

    摘要： The present invention relates to a silver halide photographic element comprising a dye-forming coupler of formula (I) ##STR1## wherein R.sup.1 is selected from an alkyl group, an aryl group, a 5-10 membered heterocyclic group containing one or more O, N or S atoms, each of which groups is unsubstituted or substituted, or a substituted amino group;R.sup.2 is an unsubstituted alkyl group having a secondary or tertiary carbon atom attached to the oxygen atom;X is hydrogen or a coupling-off group; andR.sup.3 is a substituent and n is 0 to 4; orwherein R.sup.2, as defined above, and an R.sup.3 substituent may together with the O atom form a 5-10 membered heterocyclic group which may contain one or more further heteroatoms selected from O, N and S, said group being unsubstituted or substituted; andwherein at least one of R.sup.1, R.sup.2 and R.sup.3 separately or in combination constitutes a ballast group,the couplers providing enhanced light stability together with acceptable dye hue in images produced from photographic materials containing them.

    摘要翻译： 本发明涉及一种卤化银照相元件，其包含式（I）的染料形成成色剂，其中R 1选自烷基，芳基，含有一个或多个O，N或S的5-10元杂环基 原子，其各自为未取代或取代的基团，或取代的氨基; R2是与氧原子连接的具有仲或叔碳原子的未取代的烷基; X是氢或偶合离去基团; R3为取代基，n为0〜4; 或其中如上定义的R 2和R 3取代基可以与O原子一起形成5-10元杂环基团，其可以含有一个或多个另外的选自O，N和S的杂原子，所述基团是未取代的或取代的; 并且其中R 1，R 2和R 3中的至少一个分别或组合构成镇流器基团，所述成色剂提供增强的光稳定性以及由含有它们的照相材料产生的图像中可接受的染料色调。

    METHOD OF PREPARING STIMULUS-RESPONSIVE POLYMERIC PARTICLES
    9.
    发明申请
    METHOD OF PREPARING STIMULUS-RESPONSIVE POLYMERIC PARTICLES 审中-公开
    制备刺激性聚合物颗粒的方法

    公开(公告)号：US20120046407A1

    公开(公告)日：2012-02-23

    申请号：US13141702

    申请日：2009-12-17

    申请人： Andrew Clarke ,  Stephanie Vronique Desrousseaux ,  Danuta Gibson ,  John Martin Higgins ,  Andrew Michael Howe ,  Trevor John Wear

    发明人： Andrew Clarke ,  Stephanie Vronique Desrousseaux ,  Danuta Gibson ,  John Martin Higgins ,  Andrew Michael Howe ,  Trevor John Wear

    IPC分类号： C09D11/10 ,  C08L21/02 ,  B01J13/02 ,  H01B1/20 ,  H01F1/00 ,  C08F257/02 ,  C08F265/10 ,  C08L51/06

    CPC分类号： C08F2/22 ,  B01J13/14 ,  C08F2/20 ,  C08F222/38 ,  C08F265/10 ,  C09D11/30 ,  C08F222/385

    摘要： A method of making a polymeric compound, comprising discrete particles responsive to an external stimulus, that is resistant to aggregation in high-shear fields, which includes the addition of a polymerization initiator to a reaction mixture comprising a monomer corresponding to the polymeric compound, wherein the method comprises the portion-wise addition of aliquots of a cross-linking agent to the reaction mixture, wherein an aliquot of the cross-linking agent is added to the reaction mixture both before the addition of the polymerization initiator and after the polymerization has progressed substantially to completion. The polymer particles are largely immune to the effects of transient shear rates at least as high as 106 s−1, whilst maintaining their thermal responsiveness and being present at moderate concentration. The structural and chemical modifications brought by the delayed portion-wise addition of the cross-linking agent allow an improvement in stability in a high-shear field.

    摘要翻译： 一种制备高分子化合物的方法，包括响应于外部刺激的离散颗粒，其对高剪切场中的聚集具有抗性，其包括向包含对应于聚合物的单体的反应混合物中加入聚合引发剂，其中 该方法包括向反应混合物中分批加入交联剂的等分试样，其中在加入聚合引发剂之前和聚合进行后将等份的交联剂加入到反应混合物中 大致完成。 聚合物颗粒很大程度上免受瞬态剪切速率的影响，至少高达106s-1，同时保持其热响应性并以适中的浓度存在。 通过延迟分批加入交联剂引起的结构和化学改性允许提高高剪切场中的稳定性。

    Surfactants and hydrophilic colloid compositions and materials containing them
    10.
    发明授权
    Surfactants and hydrophilic colloid compositions and materials containing them 失效
    表面活性剂和亲水胶体组合物和含有它们的材料

    公开(公告)号：US5763150A

    公开(公告)日：1998-06-09

    申请号：US685082

    申请日：1996-07-23

    申请人： Alan Robert Pitt ,  Trevor John Wear ,  Danuta Gibson

    发明人： Alan Robert Pitt ,  Trevor John Wear ,  Danuta Gibson

    IPC分类号： C07C309/17 ,  G03C1/38 ,  G03C7/388 ,  C07C143/67 ,  C07C149/20

    CPC分类号： C07C309/17 ,  G03C1/38 ,  G03C7/388 ,  Y10S516/04 ,  Y10S516/902

    摘要： Surfactants useful as dispersing aids in the preparation of compositions comprising a hydrophilic colloid having hydrophobic particles dispersed therein have the structure ##STR1## wherein M is a cation; X represents a group having the structure ##STR2## wherein each of R.sup.1, R.sup.2, R.sup.3 and R.sup.4 independently represents hydrogen or alkyl; or R.sup.1 and R.sup.2 taken together represent cycloalkyl; or R.sup.3 and R.sup.4 taken together represent cycloalkyl; and, n represents 0 or 1; provided that the total number of carbon atoms in each X group is 3 or 4, and when R.sup.1 is hydrogen R.sup.2 is other than methyl. Such surfactants offer coating and photographic property advantages when incorporated in multilayer photographic materials comprising a support bearing a plurality of hydrophilic colloid layers.

    摘要翻译： 可用作分散助剂用于制备包含其中分散有疏水性颗粒的亲水胶体的组合物的表面活性剂具有其中M是阳离子的结构， X表示具有结构的基团，其中R 1，R 2，R 3和R 4各自独立地表示氢或烷基; 或者R 1和R 2一起代表环烷基; 或者R 3和R 4一起代表环烷基; 和n表示0或1; 条件是每个X基团中的碳原子总数为3或4，并且当R 1为氢时，R 2不是甲基。 这种表面活性剂当掺入含有多个亲水胶体层的载体的多层照相材料中时，具有涂层和照相性能优点。