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公开(公告)号：US08754268B2
公开(公告)日：2014-06-17
申请号：US13094657
申请日：2011-04-26
申请人： David Lee , Adam Orosco , Nathan Powell , Manuel Salado , Lincoln Sarager , R. Jay Warner , Trinity Horton , Radmila Jevtic , Victor J. Johnston
发明人： David Lee , Adam Orosco , Nathan Powell , Manuel Salado , Lincoln Sarager , R. Jay Warner , Trinity Horton , Radmila Jevtic , Victor J. Johnston
CPC分类号： C07C29/149 , C07C29/80 , C07C51/12 , C07C31/08 , C07C53/12
摘要： A process for removing water from an alcohol mixture, such as an ethanol mixture in the production of ethanol by hydrogenating acetic acid. The water is removed from a distillate of a first column using an adsorption unit, membrane, extractive column distillation, or a combination thereof.
摘要翻译： 通过氢化乙酸从醇混合物中除去乙醇的方法，例如乙醇混合物生产乙醇。 使用吸附单元，膜，萃取柱蒸馏或其组合从第一塔的馏出物中除去水。
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公开(公告)号：US08884080B2
公开(公告)日：2014-11-11
申请号：US13094537
申请日：2011-04-26
申请人： David Lee , Adam Orosco , Nathan Powell , Manuel Salado , Lincoln Sarager , R. Jay Warner , Trinity Horton , Radmila Jevtic , Victor J. Johnston
发明人： David Lee , Adam Orosco , Nathan Powell , Manuel Salado , Lincoln Sarager , R. Jay Warner , Trinity Horton , Radmila Jevtic , Victor J. Johnston
IPC分类号： C07C31/08 , B01D3/14 , C07C29/149 , B01D3/00 , C07C29/80
CPC分类号： B01D3/002 , B01D3/143 , C07C29/149 , C07C29/80 , C07C31/08
摘要： Recovery of alcohols, in particular ethanol, from a crude ethanol product obtained from the hydrogenation of acetic acid using a reduced energy process. The crude ethanol product may be fed to a distillation column in which a substantial portion of the water is removed with the acetic acid in the residue. The ethanol product is obtained from the distillate.
摘要翻译： 从使用减少的能量过程的乙酸氢化获得的粗乙醇产物中回收醇，特别是乙醇。 粗乙醇产物可以进料到蒸馏塔中，其中大部分水用残余物中的乙酸除去。 乙醇产物从馏出物获得。
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公开(公告)号：US08686200B2
公开(公告)日：2014-04-01
申请号：US13094588
申请日：2011-04-26
申请人： David Lee , Fred Ronald Olsson , Adam Orosco , Nathan Powell , Manuel Salado , Lincoln Sarager , R. Jay Warner , Trinity Horton , Radmila Jevtic , Victor J. Johnston
发明人： David Lee , Fred Ronald Olsson , Adam Orosco , Nathan Powell , Manuel Salado , Lincoln Sarager , R. Jay Warner , Trinity Horton , Radmila Jevtic , Victor J. Johnston
CPC分类号： C07C51/12 , C07C29/149 , C07C29/80 , C07C67/08 , Y02P20/127 , C07C31/08 , C07C53/08 , C07C69/14
摘要： Recovery of ethanol from a crude ethanol product obtained from the hydrogenation of acetic acid using a low energy process. The crude ethanol product is separated in a column to produce a distillate stream comprising ethyl acetate and a residue stream comprising ethanol, acetic acid, and water. The ethanol product is recovered from the residue stream.
摘要翻译： 从使用低能量过程的乙酸氢化获得的粗乙醇产物中回收乙醇。 将粗乙醇产物在柱中分离以产生包含乙酸乙酯和包含乙醇，乙酸和水的残余物流的馏出物流。 从残余物流中回收乙醇产物。
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公开(公告)号：US08927784B2
公开(公告)日：2015-01-06
申请号：US13292914
申请日：2011-11-09
申请人： David Lee , Fred Ronald Olsson , Adam Orosco , Nathan Kirk Powell , Manuel Salado , Lincoln Sarager , R. Jay Warner , Radmila Jevtic , Victor J. Johnston
发明人： David Lee , Fred Ronald Olsson , Adam Orosco , Nathan Kirk Powell , Manuel Salado , Lincoln Sarager , R. Jay Warner , Radmila Jevtic , Victor J. Johnston
IPC分类号： C07C29/149 , C07C29/80 , C07C51/12
摘要： Recovery of ethanol from a crude ethanol product obtained from the hydrogenation of acetic acid using a low energy process. The crude ethanol product is separated in a column to produce a distillate stream comprising acetaldehyde and a residue stream comprising ethanol, acetic acid, ethyl acetate and water. The ethanol product is recovered from the residue stream.
摘要翻译： 从使用低能量过程的乙酸氢化获得的粗乙醇产物中回收乙醇。 将粗乙醇产物在柱中分离以产生包含乙醛的馏出物流和包含乙醇，乙酸，乙酸乙酯和水的残余物流。 从残余物流中回收乙醇产物。
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公开(公告)号：US20120277490A1
公开(公告)日：2012-11-01
申请号：US13292914
申请日：2011-11-09
申请人： David Lee , Fred Ronald Olsson , Adam Orosco , Nathan Kirk Powell , Manuel Salado , Lincoln Sarager , R. Jay Warner , Radmila Jevtic , Victor J. Johnston
发明人： David Lee , Fred Ronald Olsson , Adam Orosco , Nathan Kirk Powell , Manuel Salado , Lincoln Sarager , R. Jay Warner , Radmila Jevtic , Victor J. Johnston
摘要： Recovery of ethanol from a crude ethanol product obtained from the hydrogenation of acetic acid using a low energy process. The crude ethanol product is separated in a column to produce a distillate stream comprising acetaldehyde and a residue stream comprising ethanol, acetic acid, ethyl acetate and water. The ethanol product is recovered from the residue stream.
摘要翻译： 从使用低能量过程的乙酸氢化获得的粗乙醇产物中回收乙醇。 将粗乙醇产物在柱中分离以产生包含乙醛的馏出物流和包含乙醇，乙酸，乙酸乙酯和水的残余物流。 从残余物流中回收乙醇产物。
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公开(公告)号：US20120273339A1
公开(公告)日：2012-11-01
申请号：US13094641
申请日：2011-04-26
申请人： David Lee , Adam Orosco , Lincoln Sarager , R. Jay Warner , Trinity Horton , Radmila Jevtic , Victor J. Johnston
发明人： David Lee , Adam Orosco , Lincoln Sarager , R. Jay Warner , Trinity Horton , Radmila Jevtic , Victor J. Johnston
CPC分类号： C07C29/149 , C07C29/76 , C07C29/80 , C07C31/08 , C07C67/08 , Y02P20/127 , C07C69/14
摘要： Recovery of alcohol, in particular ethanol, from a crude product obtained from the hydrogenation of acetic acid using various combinations of membranes and/or distillation columns.
摘要翻译： 从使用膜和/或蒸馏塔的各种组合的乙酸氢化获得的粗产物中回收醇，特别是乙醇。
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公开(公告)号：US20120277480A1
公开(公告)日：2012-11-01
申请号：US13094473
申请日：2011-04-26
申请人： David Lee , Adam Orosco , Lincoln Sarager , R. Jay Warner , Trinity Horton , Radmila Jevtic , Victor J. Johnston
发明人： David Lee , Adam Orosco , Lincoln Sarager , R. Jay Warner , Trinity Horton , Radmila Jevtic , Victor J. Johnston
CPC分类号： C07C29/149 , C07C29/80 , C07C31/08
摘要： Recovery of ethanol from a crude ethanol product obtained from the hydrogenation of acetic acid. The crude ethanol product is fed to a distillation column to yield an ethanol sidestream.
摘要翻译： 从乙酸氢化得到的粗乙醇产物中回收乙醇。 将粗乙醇产物进料至蒸馏塔以产生乙醇侧流。
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公开(公告)号：US20120046501A1
公开(公告)日：2012-02-23
申请号：US13178659
申请日：2011-07-08
申请人： R. Jay Warner , Trinity Horton , Radmila Jevtic , Victor J. Johnston , David Lee , Adam Orosco , Lincoln Sarager
发明人： R. Jay Warner , Trinity Horton , Radmila Jevtic , Victor J. Johnston , David Lee , Adam Orosco , Lincoln Sarager
IPC分类号： C07C29/149
CPC分类号： C07C29/149 , C07C29/141 , C07C29/88 , C07C29/90 , C07C67/08 , C07C31/08 , C07C69/14
摘要： Recovery of ethanol from a crude ethanol product obtained from the hydrogenation of acetic acid and by reacting a portion of the crude ethanol product or one or more derivative streams containing ethyl acetate obtained therefrom in the presence of hydrogen, via hydrogenolysis. The one or more derivative streams comprise ethyl acetate that are reacted via hydrogenolysis to form additional ethanol that may be directly or indirectly fed to the separation zone or the hydrogenation reactor.
摘要翻译： 从乙酸氢化获得的粗制乙醇产物中回收乙醇，并通过氢解将一部分粗乙醇产物或含有由其获得的乙酸乙酯的一种或多种衍生物流在氢的存在下反应。 一种或多种衍生物流包含乙酸乙酯，其通过氢解反应以形成可以直接或间接进料至分离区或氢化反应器的另外的乙醇。
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公开(公告)号：US08846986B2
公开(公告)日：2014-09-30
申请号：US13094641
申请日：2011-04-26
申请人： David Lee , Adam Orosco , Lincoln Sarager , R. Jay Warner , Trinity Horton , Radmila Jevtic , Victor J. Johnston
发明人： David Lee , Adam Orosco , Lincoln Sarager , R. Jay Warner , Trinity Horton , Radmila Jevtic , Victor J. Johnston
IPC分类号： C07C29/149 , C07C29/76 , C07C29/80 , C07C31/08 , C07C67/08
CPC分类号： C07C29/149 , C07C29/76 , C07C29/80 , C07C31/08 , C07C67/08 , Y02P20/127 , C07C69/14
摘要： Recovery of alcohol, in particular ethanol, from a crude product obtained from the hydrogenation of acetic acid using various combinations of membranes and/or distillation columns.
摘要翻译： 从使用膜和/或蒸馏塔的各种组合的乙酸氢化获得的粗产物中回收醇，特别是乙醇。
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公开(公告)号：US08710280B2
公开(公告)日：2014-04-29
申请号：US13094722
申请日：2011-04-26
申请人： R. Jay Warner , Trinity Horton , Radmila Jevtic , Victor J. Johnston , David Lee , Adam Orosco , Lincoln Sarager
发明人： R. Jay Warner , Trinity Horton , Radmila Jevtic , Victor J. Johnston , David Lee , Adam Orosco , Lincoln Sarager
IPC分类号： C07C27/04
CPC分类号： C07C29/149 , B01D3/002 , B01D3/143 , C07C29/80 , C07C31/08
摘要： Recovery of ethanol from a crude ethanol product obtained from the hydrogenation of acetic acid and recovery of unreacted acetic acid from a weak acid stream. The unreacted acetic acid may be recovered as a dry acetic acid composition and may be directly or indirectly fed to the hydrogenation reactor.
摘要翻译： 从乙酸氢化获得的粗乙醇产物中回收乙醇，并从弱酸流中回收未反应的乙酸。 未反应的乙酸可以作为干燥乙酸组合物回收，并且可以直接或间接地进料至氢化反应器。
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