摘要:
A quasi monofilament having a high strength polyethylene fiber core with an adherent, abrasion resistant polymer sheath is prepared by feeding the core yarn through a crosshead die, while simultaneously supplying a polymer melt at a temperature greater than the melting point of the core yarn to the die, for sheathing the core yarn within the die with the melt under a sufficient pressure to cause the melt to adhere to the core yarn. The abrasion resistant polymer sheath includes an effective amount of a first polymer having ethylene crystallinity, a density of at least about 0.94 g/cm.sup.3, and a melt index of less than about 0.1 g/10 min. The composition used to sheathe the core yarn is characterized by a weight average tensile strength at yield of greater than about 13.8 MPa. The quasi monofilament has utility in applications subjected to high abrasion, such as sports fishing lines, kite lines, dental floss, "weedeater" lines and tennis racket strings.
摘要翻译:通过将芯纱线通过十字头模头进给,同时在大于芯纱线的熔点的温度下向聚合物熔体提供聚合物熔体,制备具有粘附耐磨聚合物护套的高强度聚乙烯纤维芯的准单丝 模具,用于在足够的压力下用熔体将模具内的芯线包覆以使熔体粘附到芯纱上。 耐磨聚合物护套包括有效量的具有乙烯结晶度的第一聚合物,至少约0.94g / cm 3的密度和小于约0.1g / 10min的熔体指数。 用于包芯纱的组合物的特征在于产率大于约13.8MPa的重均拉伸强度。 准单丝可用于运动钓鱼线,风筝线,牙线,“除草机”线和网球拍线等高磨损应用。
摘要:
A quasi monofilament having a high strength polyethylene fiber core with an adherent, abrasion resistant polymer sheath is prepared by feeding the core yarn through a crosshead die, while simultaneously supplying a polymer melt at a temperature greater than the melting point of the core yarn to the die, for sheathing the core yarn within the die with the melt under a sufficient pressure to cause the melt to adhere to the core yam. The abrasion resistant polymer sheath includes an effective amount of a first polymer having ethylene crystallinity, a density of at least about 0.94 g/cm.sup.3, and a melt index of less than about 0.1 g/10 min. The composition used to sheathe the core yarn is characterized by a weight average tensile strength at yield of greater than about 13.8 MPa. The quasi monofilament has utility in applications subjected to high abrasion, such as sports fishing lines, kite lines, dental floss, "weedeater" lines and tennis racket strings.
摘要翻译:通过将芯纱线通过十字头模头进给,同时在大于芯纱线的熔点的温度下向聚合物熔体提供聚合物熔体,制备具有粘附耐磨聚合物护套的高强度聚乙烯纤维芯的准单丝 模具,用于在足够的压力下用熔体将模具内的芯纱线包覆以使熔体粘附到芯纱线上。 耐磨聚合物护套包括有效量的具有乙烯结晶度的第一聚合物,至少约0.94g / cm 3的密度和小于约0.1g / 10min的熔体指数。 用于包芯纱的组合物的特征在于产率大于约13.8MPa的重均拉伸强度。 准单丝可用于运动钓鱼线,风筝线,牙线,“除草机”线和网球拍线等高磨损应用。
摘要:
Solutions of intermediate molecular weight polymers from about 200,000 to about 4,000,000, such as polyethylene, in a relatively non-volatile solvent are extruded through an aperature at constant concentration and thereafter stretched at a ratio of at least about 3:1 prior to cooling to form a first gel. The first gels are extracted with a volatile solvent to form a second gel, and the second gel is dried to form a low porosity xerogel. Stretching occurs with any one or more of the first gel, second gel or xerogel. The polyethylene products produced by our process include products having a molecular weight between about 200,000 and about 4,000,000 a tenacity of at least about 13 grams/denier, a modulus of at least about 350 gram/denier, a porosity of less than 10% by volume, a crystalline orientation function of at least about 0.95, and a main melting temperature of at least about 140.degree. C.
摘要:
The present invention relates to high strength, high modulus polyethylene filaments which form composites having improved shear strength and composites formed from said filaments.
摘要:
Ultrahigh molecular weight polyethylene fibers of high tenacity and modulus shrink controlled amounts at temperatures in the range of 100.degree.-155.degree. C. Fabrics and twisted multifilament yarns of these fibers are heat-shrunk or heat-set at these temperatures.
摘要:
Polyvinyl alcohol of molecular weight over 500,000 (i.e. 1,500,000 to 2,500,000) is spun as a dilute solution (2-15%) in a relatively non-volatile solvent such as glycerin. The resultant gel fiber is extracted with a volatile solvent such as methanol and dried. Upon stretching at one or more stages during the process, fibers of tenacity above 10 g/denier and modulus above 200 g/denier (e.g. 18 and 450, respectively) are produced.
摘要:
The present invention provides an improved fabric which comprises at least one network of fibers selected from the group consisting of extended chain polyethylene (ECPE) extended chain polypropylene (ECPP) fibers, extended chain polyvinyl alcohol fibers and extended chain polyacrylonitrile fibers. A low modulus elastomeric material, which has a tensile modulus of less than about 6,000 psi, measured at about 23.degree. C., substantially coats the fibers of the network. Preferably, the fibers have a tensile modulus of at least about 500 grams/denier and an energy-to-break of at least about 22 Joules/gram.
摘要:
The present invention provides an improved, ballistic-resistant composite article of manufacture which comprises a network of high strength fibers having a tensile modulus of at least about 500 grams/denier and an energy-to-break of at least about 22 Joules/gram. An elastomeric matrix material substantially coats each of the individual fibers, and has a tensile modulus of less than about 6,000 psi, measured at 25.degree. C.
摘要:
Replacing iron with small amounts of molybdenum, i.e., about 1 to 8 atom percent, in a glass-forming alloy consisting essentially of about 9 to 24 atom percent boron, the balance essentially iron and incidental impurities, results in substantial improvement in filament strength.
摘要:
A robust process for the continuous preparation of solutions of high molecular weight UHMW PO that is capable of producing strong materials at high production capacity, is conservative of capital and energy requirements, and the articles made therefrom.