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    Process for alcohol production by selective ether decomposition
    5.
    发明授权
    Process for alcohol production by selective ether decomposition 失效
    通过选择性醚分解生产酒精的方法

    公开(公告)号：US07399891B2

    公开(公告)日：2008-07-15

    申请号：US11147919

    申请日：2005-06-08

    申请人： Charles M Yarbrough ,  Brian William Roberts ,  Dennis Jay Davoren ,  Kenneth Joseph Buturla ,  Carl Stotz Katzenstein ,  Doron Levin ,  Hans Georg Korsten ,  Vijay Swarup

    发明人： Charles M Yarbrough ,  Brian William Roberts ,  Dennis Jay Davoren ,  Kenneth Joseph Buturla ,  Carl Stotz Katzenstein ,  Doron Levin ,  Hans Georg Korsten ,  Vijay Swarup

    IPC分类号： C07C33/02

    CPC分类号： B01J23/24 ,  B01J21/06 ,  B01J21/066 ,  B01J23/10 ,  C07C29/04 ,  C07C29/10 ,  C07C31/10 ,  C07C31/12

    摘要： This invention relates to a process for the production of an alcohol, the process comprising (a) reacting an olefin and water in the presence of a catalyst under conditions sufficient to form a crude alcohol stream comprising alcohol, and a dialkyl ether; (b) separating at least a portion of the crude alcohol stream into an alcohol-containing stream and a dialkyl ether stream; (c) contacting at least a portion of the dialkyl ether stream with an ether decomposition catalyst, the ether decomposition catalyst comprising a mixed metal oxide having the following composition XmYnZpOq where X is at least one metal selected from Group 4 of the Periodic Table of Elements, Y is at least one metal selected from Group 3 (including the Lanthanides and Actinides) and Group 6 of the Periodic Table of Elements and Z is at least one metal selected from Groups 7, 8, and 11 of the Periodic Table of Elements; m, n, p, and q are the atomic ratios of their respective components and, when m is 1, n is from about 0.01 to about 0.75, p is from 0 to about 0.1, and q is the number of oxygen atoms necessary to satisfy the valence of the other components, to form a crude dialkyl ether decomposition stream comprising alcohol and olefin; (d) recovering at least a portion of the olefin from the crude dialkyl ether decomposition stream; and (e) recycling at least a portion of the olefin recovered in step (d) to step (a).

    摘要翻译： 本发明涉及一种生产醇的方法，该方法包括（a）在足以形成包含醇和二烷基醚的粗醇物流的条件下，在催化剂存在下使烯烃和水反应; （b）将至少一部分粗醇流分离成含醇流和二烷基醚流; （c）使至少一部分二烷基醚料流与醚分解催化剂接触，所述醚分解催化剂包含具有以下组成的混合金属氧化物： 其中X是选自元素周期表第4族的至少一种金属，Y是选自第3族（包括镧系元素）中的至少一种金属 和锕系元素）和元素周期表第6族，Z是选自元素周期表第7,8和11族中的至少一种金属; m，n，p和q是它们各自成分的原子比，当m为1时，n为约0.01至约0.75，p为0至约0.1，q为必需的氧原子数 满足其他组分的化合价，形成包含醇和烯烃的粗二烷基醚分解物流; （d）从粗二烷基醚分解流中回收至少一部分烯烃; 和（e）将步骤（d）中回收的烯烃的至少一部分再循环到步骤（a）。