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公开(公告)号：US4565881A
公开(公告)日：1986-01-21
申请号：US405677
申请日：1982-08-06
IPC分类号： C09K19/34 , C07D319/06
CPC分类号： C09K19/3402 , C09K2019/3422
摘要： Liquid crystal substituted 1,3-dioxanes and mixtures containing the same.The invention relates to liquid crystal substituted 1,3-dioxanes and substances containing the same, for electro-optical arrays for the modulation of incident or transmitted light as well as for the reproduction of figures, symbols and images.The object of the invention is nematic liquid-crystal substances with favorable properties with respect to melting and clear points, stability toward thermal stress, effect of light, chemicals and electric fields as well as loss of color and processes for their production.The object is accomplished by the creation of new nematic liquid-crystal substances.According to the invention, liquid crystal 2,5-disubstituted derivatives of 1,3-dioxane of the general formula ##STR1## are proposed, wherein ##STR2## The new substances may be used in mixtures containing at least one of the substances according to the invention.
摘要翻译： 液晶取代1,3-二恶烷及含有它们的混合物。 本发明涉及液晶取代的1,3-二恶烷及其含有物质的物质，用于调制入射或透射光的电光阵列，以及图形，符号和图像的再现。 本发明的目的是在熔融和清除点方面具有良好的性能，对热应力的稳定性，光，化学品和电场的作用以及颜色的丧失和它们的生产方法的向列型液晶物质。 该目的是通过创建新的向列液晶物质来实现的。 根据本发明，提出了具有通式“IMAGE”的1,3-二恶烷的液晶2,5-二取代衍生物，其中
+ TR R2 = OR4，CnH2n + 1，R3 = Br，CN，CnH2n + 1和R4 = CnH2n + 1，其中n = 1至10.新物质可用于含有至少一种根据 发明。 -
2.发明授权Crystalline-liquid substituted 1,3-dioxanes and mixtures containing them 失效结晶液体取代的1,3-二氧杂环己烷和含有它们的混合物
公开(公告)号：US4344856A
公开(公告)日：1982-08-17
申请号：US110857
申请日：1980-01-10
IPC分类号： C09K19/34 , C09K19/54 , C09K3/34 , C07D319/04 , G02F1/13
CPC分类号： C09K19/3402 , C09K19/54 , C09K2019/3422
摘要： The invention concerns crystalline liquid substituted 1,3-dioxanes and compositions containing the same for use in electro-optical components, characterized by at least one compound of the general formula: ##STR1## R.sup.3 =C.sub.n H.sub.2n+1 ; C.sub.n H.sub.2n+1 O, Cl, Br, CN, NO.sub.2, and where R.sup.4 =C.sub.n H.sub.2n+1 and n=1 to 10.
摘要翻译： 本发明涉及结晶液体取代的1,3-二恶烷及其用于电光部件的组合物，其特征在于至少一种以下通式的化合物：
CnH2n + 1（CH3）N，CN，NO2，F，Cl，Br，NCCHCH，图像R2 = CnH2n + 1; OH，CN，OR4，OCOR4，OCOOR4，图像，R3 = CnH2n + 1; CnH2n + 10，Cl，Br，CN，NO2，其中R4 = CnH2n + 1，n = 1〜10。 -
公开(公告)号：US4363767A
公开(公告)日：1982-12-14
申请号：US202958
申请日：1980-10-03
IPC分类号： C07C255/34 , C09K19/00 , C09K19/08 , C09K19/34 , C09K19/42 , C07C121/70 , C09K3/34
CPC分类号： C07C255/00 , C09K19/42
摘要： The invention relates to liquid-crystalline nematic mixtures which are used in electro-optical components, as well as to methods for their preparation.The object of the invention is liquid-crystalline mixtures for electro-optical arrangements possessing high positive electrical anisotropy at a high clarification point, as well as methods for their preparation.According to the invention, liquid-crystalline nematic mixtures are used, wherein at least one component is a 1,4-disubstituted benzene derivative and the other compound is an ester of 4-[2,2-dicyano-ethenyl]-phenol of the general formula ##STR1## wherein R.sup.1 denotes added groups of various characters such as alkyl or alkoxy for example, X is aromatic, cycloaliphatic or a heterocyclic ring system such as phenyl or cyclohexyl for example; and Y is a connector such as carbonyloxy, azomethine, azoxy.These are prepared by reaction with reactive acid derivatives, particularly acid chlorides, or by a Knoevenagel-condensation by reacting respective 4-subst.-benzoic acid-[4-formyl-phenyl esters] or 4-alkyl-cyclohexanecarboxylic acid-[4-formyl-phenyl esters] with malonic acid dinitrile.
摘要翻译： 本发明涉及用于电光元件的液晶向列混合物及其制备方法。 本发明的目的是在高澄清点具有高正电各向异性的电光装置的液晶混合物及其制备方法。 根据本发明，使用液晶向列混合物，其中至少一种组分是1,4-二取代的苯衍生物，而另一种化合物是4- [2,2-二氰基 - 乙烯基] - 苯酚的酯 其中R1表示各种特征的加成基团，例如烷基或烷氧基，例如X是芳族的，脂环族的或杂环系统，例如苯基或环己基; 并且Y是诸如羰基氧基，偶氮甲碱基，偶氮氧基之类的连接体。 这些通过与各种4-取代苯甲酸 - [4-甲酰基 - 苯基酯]或4-烷基 - 环己烷甲酸 - [4-甲氧基苯基]酯反应而与反应性酸衍生物，特别是酰氯反应或通过Knoevenagel缩合反应制备， 甲酰基 - 苯基酯]与丙二酸二腈。
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4.发明授权
公开(公告)号：US4348324A
公开(公告)日：1982-09-07
申请号：US102944
申请日：1979-12-12
IPC分类号： C09K19/34 , C09K3/34 , C07D319/04 , C07D319/06
CPC分类号： C09K19/3402 , C09K2019/3422
摘要： Liquid crystal substituted 1,3 dioxanes and mixtures containing the same.The invention relates to liquid crystalline substituted 1,3 dioxanes and substances containing the same, for electrooptical arrays for the modulation of incident or transmitted light as well as for the reproduction of figures, symbols and images.The objects of the invention are nematic crystal liquid substances with favorable properties with respect to melting and clear points; stability toward thermal stress, effect of light, chemicals and electric fields as well as loss of color; and processes for their production.The task is solved by the creation of new nematic liquid-crystal substances.As per invention, liquid crysalline 2,5-disubstituted derivatives of 1,3-dioxane of the general formula: ##STR1## are proposed, wherein: ##STR2## The new substances are used in mixtures containing at least one of the substances according to the invention.
摘要翻译： 液晶取代1,3-二恶烷及含有它们的混合物。 本发明涉及液晶取代的1,3-二恶烷及其含有物质的物质，用于调制入射或透射光的电光阵列以及图形，符号和图像的再现。 本发明的目的是相对于熔点和澄清点具有良好性能的向列型液晶物质; 对热应力的稳定性，光的影响，化学品和电场以及颜色的丧失; 和生产过程。 通过创建新的向列液晶物质来解决这个任务。 根据本发明，提出了通式为：IMAGE的1,3-二恶烷的液体crysalline 2,5-二取代衍生物，其中：＆lt; IMAGE＆gt;＆lt; IMAGE＆gt; CnH2n + 1（ CH 3）N，CN，NO 2，F，Cl，Br，NCCHCH，+ TR NCCH 2 CH 2，NCCH 2 R 2 = C n H 2n + 1; 哦; CN; OR4; OCOR4; OCOOR 4; + TR
R3 = CnH2n + 1，CnH2n + 10，Cl，Br，CN，NO2，R4 = CnH2n + 1和n = 1至10.新物质用于含有至少一种物质的混合物 涉及本发明。 -
5.发明授权Liquid crystalline 2-substituted-5-(1-alkyl-piperid-4-yl)-1,3-dioxanes 失效液晶2-取代-5-（1-烷基 - 哌啶-4-基）-1,3-二氧杂环己烷
公开(公告)号：US4597892A
公开(公告)日：1986-07-01
申请号：US749042
申请日：1985-06-26
IPC分类号： C07D211/22 , C07D211/34 , C07D405/04 , C09K19/34 , C07D407/00 , G02F1/13
CPC分类号： C07D405/04 , C07D211/22 , C07D211/34 , C09K19/3483
摘要： 2-Substituted-5-(1-alkyl-piperid-yl)-1,3-dioxanes of the formula I ##STR1## wherein R= ##STR2## R.sup.1 =--C.sub.n H.sub.2n+1, --OC.sub.n H.sub.2n+1, --OOCC.sub.n H.sub.2n+1, --COC.sub.n H.sub.2n+1, --OOCOC.sub.n H.sub.2n+1, --F, --Cl, --Br, --I, --NO.sub.2, --CN --(CH.sub.2).sub.2 CN, ##STR3## and n=1 to 10, are novel liquid crystalline compounds, which can be produced in high yields by means of reacting 2-(1-alkyl-piperid-4-yl)-propane-1,3-diols with aldehydes in the presence of acid catalysts, such as p-toluenesulfonic acid, mineral acids and Lewis acids. Because of their high thermal and chemical stability, which is also transferred to mixtures, the compounds of the formula I are very well suited for utilization in optoelectronic displays.
摘要翻译： 2-取代的式I的2-取代的5-（1-烷基 - 哌啶基）-1,3-二氧杂环己烷，其中R = R 1 = C n H 2n + 1，-OC n H 2n + 1，-OOCCnH2n + 1，-COCnH2n + 1，-OOCOCnH2n + 1，-F，-Cl，-Br，-I，-NO2，-CN-（CH2）2CN，
+ TR 和n = 1至10是新的液晶化合物，其可以通过使2-（1-烷基 - 哌啶-4-基） - 丙烷-1,3-二醇与醛在酸存在下反应而以高产率制备 催化剂，如对甲苯磺酸，无机酸和路易斯酸。 由于其高的热和化学稳定性，其也转移到混合物中，式I的化合物非常适合于在光电显示器中的应用。 -
公开(公告)号：US4521327A
公开(公告)日：1985-06-04
申请号：US463377
申请日：1983-02-03
IPC分类号： C07D319/06 , C09K19/34 , C09K3/34 , C09K11/06
CPC分类号： C09K19/3402 , C07D319/06 , C09K2019/3422
摘要： The invention relates to nematic liquid crystals, especially for electro-optical components for the modulation of transmitted or reflected light, as well as for the display of numbers, symbols and images, exhibiting favorable physical characteristics, as well as to a method for the production of the new substances.It has been found that new liquid crystal 2-substituted-1,3-dioxane-5-carboxylic acid esters of the general formula ##STR1## are suited for use in electro-optical components for the modulation of the light, as well as for the display of numbers, symbols and images, and can be used alone, in mixtures with each other and/or in mixtures with additional liquid crystal or non-liquid crystal substances.In the method for the production of the new liquid crystal trans-2-substituted-1,3-dioxane-5-carboxylic acid esters, 2-substituted-1,3-dioxane carboxylic acids, with halogen donors such as thionyl chloride, sulfuryl chloride or phosphoric halides, preferably in the absence of organic bases, are converted into the corresponding acid chlorides, which are subsequently esterified in well-known fashion with alcohols or substituted phenols.
摘要翻译： 本发明涉及向列液晶，特别是用于调制透射或反射光的电光元件，以及显示有利的物理特性的数字，符号和图像的显示，以及生产方法 的新物质。 已经发现，具有通式“IMAGE”的新的液晶2-取代-1,3-二恶烷-5-羧酸酯适用于用于调制光的电光部件，以及用于 数字，符号和图像的显示，并且可以单独使用，彼此混合和/或与额外的液晶或非液晶物质混合使用。 在制备新的液晶反式-2-取代-1,3-二恶烷-5-羧酸酯，2-取代-1,3-二恶烷羧酸与卤素供体如亚硫酰氯的方法中， 氯化物或磷酸盐，优选在不存在有机碱的情况下，转化为相应的酰氯，随后以众所周知的方式用醇或取代的酚酯化。
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公开(公告)号：US4486332A
公开(公告)日：1984-12-04
申请号：US405214
申请日：1982-08-04
IPC分类号： C07D319/06 , C09K19/34 , G02F1/13 , C07D319/04 , C09K3/34
CPC分类号： C07D319/06 , C09K19/3402 , C09K2019/3422
摘要： The invention relates to liquid crystal nematic substances based on new derivatives of 1,3-dioxanes in electro-optical components, which are used, for instance, as displays in electronic clocks and computer systems.The subject of the invention is nematic liquid crystal substances with favorable properties concerning melting and clear temperatures, stability against thermal stress and electrical fields, low viscosity and low threshold voltage.It was found that liquid crystal 2,5-di-substituted cyclohexyl derivatives of 1,3 dioxanes, having the general formula ##STR1## R.sup.1 =C.sub.n H.sub.2n+1 ; C.sub.n H.sub.2n+1 O; C.sub.n H.sub.2n+1 COO; CN; NO.sub.2 ; F; Cl; Brand R.sup.2 =C.sub.n H.sub.2n+1 with n+1 to 9are suitable for use in electro-optical components.
摘要翻译： 本发明涉及基于电光部件中1,3-二恶烷的新衍生物的液晶向列物质，其用于例如电子时钟和计算机系统中的显示器。 本发明的主题是具有熔融和透明温度，耐热应力和电场稳定性，低粘度和低阈值电压的有利性质的向列型液晶物质。 发现1,3-二恶烷的液晶2,5-二取代的环己基衍生物具有通式为：＆lt; IMAGE＆gt;＆lt; IMAGE＆gt; R1 = CnH2n + 1; CnH2n + 10 CnH2n + 1COO; CN; NO2; F; Cl; Br和R2 = CnH2n + 1，n + 1〜9适用于电光元件。
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8.发明授权
公开(公告)号：US4961876A
公开(公告)日：1990-10-09
申请号：US245962
申请日：1988-09-15
申请人： Dietrich Demus , Horst Zaschke , Wolfgang Weissflog , Kristina Mohr , Saskia Kohler , Kerstin Worm
发明人： Dietrich Demus , Horst Zaschke , Wolfgang Weissflog , Kristina Mohr , Saskia Kohler , Kerstin Worm
IPC分类号： C07D319/06 , C07C67/00 , C07C69/63 , C07C69/773 , C07C69/90 , C07C69/92 , C07C69/94 , C07C227/00 , C07C227/16 , C07C229/52 , C07C241/00 , C07C245/04 , C07C245/06 , C07C253/00 , C07C255/50 , C07C255/57 , C07C291/04 , C07C291/08 , C07C313/00 , C07C323/17 , C07C323/19 , C07C323/20 , C07C323/48 , C07D239/26 , C07D285/12 , C07D339/08 , C09K19/10 , C09K19/20 , C09K19/22 , C09K19/26 , C09K19/30 , C09K19/34 , G02F1/13
CPC分类号： C07D239/26 , C09K19/2021 , C09K19/3001 , C09K19/3402 , C09K19/3444 , C09K19/3463 , C09K19/3472 , C09K19/3483 , C09K19/3491 , C09K19/3497 , C09K2019/3422
摘要： Liquid crystalline ferroelectric derivatives of branched acyclic alpha-chlorocarboxylic acids of the general formula I ##STR1## wherein n=0 or 1; m=0 or 1, o=0 or 1; p=0 or 1X=--COO--, --OOC--, or --CH.sub.2 --CH.sub.2 --Y=X, --CH.sub.2 --, --N.dbd.N--, or --N.dbd.N(O)--, ##STR2## It was discovered that, by reacting chiral alpha-chlorocarboxylic acids or alpha-chlorocarboxylic acid chlorides or bromides, synthesized from natural alpha-amino acids by reaction with nitric and hydrochloric acids, with appropriate hydroxy compounds directly or in the presence of strongly dehydrating substances, preferably carbodiimides, liquid crystalline ferroelectric substances of the general formula I are formed.The inventive substances by themselves, in mixtures with one another as well as with other liquid crystalline substances or substances which are not liquid crystalline, can form liquid crystalline ferroelectric phases, which make them suitable for use in displays.
摘要翻译： 具有通式I的支链非环状α-氯羧酸的液晶铁电衍生物，其中n = 0或1; m = 0或1，o = 0或1; p = 0或1 X = -COO - ， - OOC-或-CH 2 -CH 2 - Y = X，-CH 2 - ， - N = N-或-N = N（O） - ，
R1 =（CH3）2CH，（CH3）2CHCH2或C2H5CH（CH3）R2 = ClH2l + 1，OClH2l + 1，SClH2l + 1，COClH2l + 1， + TROCOC1H1 + 1，COOClH2I + 1或NHClH2I + 11 = 1-12。 已经发现，通过与天然α-氨基酸反应的手性α-氯代羧酸或α-氯代羧酸酰氯或溴化物，通过与硝酸和盐酸反应，直接或在强脱水物质存在下与适当的羟基化合物反应， 优选碳二亚胺，形成通式I的液晶铁电物质。 本发明的物质本身以彼此的混合物以及其它液晶物质或不是液晶的物质可以形成液晶铁电相，这使得它们适用于显示器。 -
9.发明授权Liquid-crystalline, 2,5-disubstituted, 1,3,4-thiadiazoles with extended smectic C phases 失效具有延长的近晶C相的液晶，2,5-二取代的1,3,4-噻二唑
公开(公告)号：US4952699A
公开(公告)日：1990-08-28
申请号：US209400
申请日：1988-06-20
申请人： Bak G Yong , Dietrich Demus , Horst Kresse , Annelore Madicke , Gerhard Pelzl , Wolfgang Schafer , Carsten Tschierske , Horst Zaschke
发明人： Bak G Yong , Dietrich Demus , Horst Kresse , Annelore Madicke , Gerhard Pelzl , Wolfgang Schafer , Carsten Tschierske , Horst Zaschke
IPC分类号： C07D285/12 , C09K19/34 , C09K19/46 , G02F1/13
CPC分类号： C07D285/12 , C09K19/3497
摘要： 2,5-substituted 1,3,4-thiadiazoles of the general formula ##STR1##The aforementioned compounds are used in amounts of 0.1 to 80 mole percent in mixtures for electrooptical arrangements for the modulation of transmitted and reflected light, as well as for the colored or black-and-white display of numerals, symbols and moving or still pictures. The compounds endow the liquid-crystalline mixtures with an extended phase field of the smectic C phase, negative dielectric anisotropy and the property of forming optically active C phases upon admixture with optically active compounds.
摘要翻译： 具有通式的2,5-取代的1,3,4-噻二唑上述化合物的用量为0.1至80摩尔％，用于调制透射和反射光的电光装置，以及用于 数字，符号和移动或静态图片的彩色或黑白显示。 该化合物赋予液晶混合物具有近晶相C的延伸相场，负介电各向异性以及与光学活性化合物混合形成光学活性C相的性质。
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公开(公告)号：US4099856A
公开(公告)日：1978-07-11
申请号：US381324
申请日：1973-07-20
IPC分类号： C07C69/78 , C07C69/773 , C09K19/20 , C09K3/34 , G02F1/13
CPC分类号： C09K19/2007
摘要： As the liquid crystal substance in electro-optical devices or as the stationary phase in gas chromatography is employed a compound of the formula ##STR1## in which R.sub.1 and R.sub.2 each is C.sub.n H.sub.2n+1 --, C.sub.n H.sub.2n+1 O--, C.sub.n H.sub.2n+1 COO-- or C.sub.n H.sub.2n+1 OCOO--, n being an integer of from 1 to 10, and R.sub.3 is Cl--, Br--, CH.sub.3 --, C.sub.2 H.sub.5 --, CH.sub.3 CO-- or CH.sub.3 OOC--.
摘要翻译： 由于电光装置中的液晶物质或气相色谱法中的固定相采用式（Ⅰa）的化合物，其中R 1和R 2各自为C n H 2n + 1，C n H 2n + 1 O - ，C n H 2n + 1 COO-或 C n H 2n + 1 COOO-，n为1〜10的整数，R 3为Cl - ，Br - ，CH 3 - ，C 2 H 5 - ，CH 3 CO-或CH 3 OOC-。
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