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1.发明授权Conversion of ethylene into butene-1 using additives based on quarternary ammonium salts 失效使用基于季铵盐的添加剂将乙烯转化为丁烯-1
公开(公告)号：US5877376A
公开(公告)日：1999-03-02
申请号：US842421
申请日：1997-04-24
CPC分类号： C07C2/30 , C07C2531/02 , C07C2531/14
摘要： The invention concerns an improved process for the conversion of ethylene into butene-1, wherein the ethylene is brought into contact with a catalyst obtained by the reaction of an alkyl titanate, possibly mixed with an ether, with a compound of aluminium of the formula AlR.sub.3 or AlR.sub.2 H, and in the presence of an additive formed by at least one quaternary ammonium salt.
摘要翻译： 本发明涉及将乙烯转化为丁烯-1的改进方法，其中乙烯与可能与醚混合的钛酸烷基酯与式AlR 3的铝化合物反应获得的催化剂接触 或AlR2H，并且在由至少一种季铵盐形成的添加剂存在下进行。
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2.发明授权
公开(公告)号：US5817905A
公开(公告)日：1998-10-06
申请号：US842504
申请日：1997-04-24
申请人： Dominique Commereuc , Yves Glaize , Fran.cedilla.ois Hugues , Pierre Panzarella , Lucien Saussine
发明人： Dominique Commereuc , Yves Glaize , Fran.cedilla.ois Hugues , Pierre Panzarella , Lucien Saussine
CPC分类号： C07C2/30 , C07C2527/135 , C07C2531/02 , C07C2531/14 , C07C2531/24 , C07C2531/38
摘要： The invention concerns an improved process for the conversion of ethylene into light alpha olefins wherein the ethylene is brought into contact with a catalyst obtained by mixing a compound of zirconium with an organic compound selected from the class of acetals and ketals, esters, ketones, ethers, amines, nitrites, anhydrides, chlorides of acids, amides, aldehydes, thioethers, sulphides and disulphides, thiophenes, thioureas and phosphines, and with a chloro or bromo compound of aluminium hydrocarbyl, in the presence of an additive formed by at least one quaternary ammonium salt.
摘要翻译： 本发明涉及将乙烯转化成轻质α-烯烃的改进方法，其中乙烯与通过将锆化合物与选自缩醛和缩酮类，有机酮，酮类，醚类的有机化合物混合而得到的催化剂接触 ，胺，亚硝酸盐，酸酐，酸的酰胺，酰胺，醛，硫醚，硫化物和二硫化物，噻吩，硫脲和膦以及与烃基的氯或溴化合物在存在由至少一种季铵盐形成的添加剂 铵盐。
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3.发明授权Process for the conversion of ethylene into but-1-ene using additives based on polymethylene glycols and derivatives thereof 失效使用基于聚亚甲基二醇及其衍生物的添加剂将乙烯转化为丁-1-烯的方法
公开(公告)号：US5792895A
公开(公告)日：1998-08-11
申请号：US842502
申请日：1997-04-24
CPC分类号： C07C2/30 , C07C2531/02 , C07C2531/14
摘要： The invention concerns an improved process for the conversion of ethylene into but-1-ene, wherein the ethylene is brought into contact with a catalyst obtained by the interaction of an alkyl titanate, possibly mixed with an ether, with a compound of aluminium of the formula AlR.sub.3 or AlR.sub.2 H, and in the presence of an additive formed by at least one polyethylene glycol and/or one of its derivatives such as a monoether or a monoester of polyethylene glycol.
摘要翻译： 本发明涉及一种将乙烯转化为丁-1-烯的改进方法，其中乙烯与可能与醚混合的钛酸烷基酯与与 在由至少一种聚乙二醇和/或其衍生物之一形成的添加剂存在下，如聚乙二醇的单醚或单酯。
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4.发明授权Method of production of improved purity light alpha olefines by ogliomerisation of ethylene 失效通过乙烯的异构化生产改进的纯度高的α-烯烃的方法
公开(公告)号：US5811619A
公开(公告)日：1998-09-22
申请号：US513982
申请日：1995-11-16
CPC分类号： C07C11/02 , B01J31/0237 , B01J31/143 , B01J31/2226 , C07C2/30 , B01J2231/20 , B01J2531/48 , C07C2527/135 , C07C2531/02 , C07C2531/04 , C07C2531/14 , C07C2531/38
摘要： For obtaining of improved purity of light alpha olefines produced by oligomerization of ethylene, the ethylene is placed in contact with a catalyst obtained by mixture of a zirconium compound with an organic compound selected from the class of acetals and ketals and with a chlorinated or brominated aluminium hydrocarbyl compound, and that the raw oligomerization effluent is firstly treated with an amine, then subjected to vaporization so as to collect the alpha olefines in the vaporized fraction.
摘要翻译： PCT No.PCT / FR95 / 00044 Sec。 371日期：1995年11月16日 102（e）日期1995年11月16日PCT 1995年1月13日PCT PCT。 公开号WO95 / 19332 日期1995年7月20日为了获得通过乙烯低聚产生的轻质α-烯烃的纯度的提高，将乙烯与通过锆化合物与选自缩醛和缩酮类的有机化合物的混合物获得的催化剂接触，并与 氯化或溴化铝烃基化合物，并且首先用胺处理原始低聚流出物，然后进行蒸发以收集蒸发馏分中的α-烯烃。
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5.发明授权Process for the separation of alpha-olefins by distillation of an effluent comprising ethylene and 1-butene 失效通过蒸馏出包含乙烯和1-丁烯的流出物来分离α-烯烃的方法
公开(公告)号：US5853551A
公开(公告)日：1998-12-29
申请号：US720384
申请日：1996-07-23
CPC分类号： C07C7/05
摘要： The invention concerns a process for the separation of a mixture comprising ethylene, 1-butene, alpha-olefins containing at least 6 carbon atoms per molecule and possibly heavier hydrocarbon products, the ethylene content of the mixture being in the range 30% to 70% by weight, in which separation is effected in a distillation zone to obtain an overhead fraction comprising the major portion of the ethylene present in the mixture and between 0% and 100% by weight of the 1-butene present in the mixture, the process being characterized in that the zone is also supplied with supplemental 1-butene in an amount in the range 1 to 40 times the quantity (by weight) of 1-butene present in the mixture. In a preferred implementation of the process of the invention, the mixture originates form a homogenous liquid phase ethylene oligomerisation zone.
摘要翻译： 本发明涉及一种分离包含乙烯，1-丁烯，每分子含有至少6个碳原子的α-烯烃和可能较重烃产物的混合物的混合物的方法，该混合物的乙烯含量在30％至70％的范围内， ，其中在蒸馏区中进行分离以获得包含混合物中存在的乙烯的主要部分和0重量％至100重量％的混合物中存在的1-丁烯的塔顶馏分，该方法为 其特征在于，该区域还提供了在混合物中存在的1-丁烯的量（重量）的1至40倍的量的补充的1-丁烯。 在本发明方法的优选实施方案中，混合物起始形成均相液相乙烯齐聚区。
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6.发明授权Process for producing a hydrocarbon cut of high octane number by etherification of olefins 失效通过烯烃醚化生产高辛烷值的烃馏分的方法
公开(公告)号：US4647703A
公开(公告)日：1987-03-03
申请号：US753465
申请日：1985-07-10
申请人： Bernard Torck , Pierre Amigues , Yves Glaize , Henri Grangette , Jean Laurent , Fred Fitoussi
发明人： Bernard Torck , Pierre Amigues , Yves Glaize , Henri Grangette , Jean Laurent , Fred Fitoussi
摘要： Process for producing a hydrocarbon cut of high octane number by etherification of an olefin-containing hydrocarbon cut.The olefinic cut, to which methanol is added, passes into an etherification reactor (1) wherefrom are separated (3) a bottom product (15) containing ethers, and a top product (14) containing residual methanol and unreacted light olefins. This top product passes into an etherification reactor (2) and then is washed with water (8).The top product is finally admixed with the bottom product.The so-obtained motor-fuel has a higher octane number than that of the initial hydrocarbon cut.
摘要翻译： 通过含烯烃的烃馏分的醚化生产高辛烷值的烃馏分的方法。 向其中加入甲醇的烯属馏分进入醚化反应器（1），从其中分离出（3）含有醚的底部产物（15）和含有残余甲醇和未反应的轻质烯烃的顶部产物（14）。 该顶部产物进入醚化反应器（2），然后用水（8）洗涤。 最终的产品最终与底部产品混合。 所得到的电动机燃料具有比初始碳氢化合物馏分高的辛烷值。
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