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    METHOD FOR PREPARING TRANSITION METAL COMPLEXES, TRANSITION METAL COMPLEXES PREPARE USING THE METHOD, CATALYTS COMPOSITION CONTAINING THE COMPLEXES
    7.
    发明申请
    METHOD FOR PREPARING TRANSITION METAL COMPLEXES, TRANSITION METAL COMPLEXES PREPARE USING THE METHOD, CATALYTS COMPOSITION CONTAINING THE COMPLEXES 有权
    制备过渡金属络合物的方法，使用该方法的过渡金属络合物的制备，包含复合物的催化剂组合物

    公开(公告)号：US20100062927A1

    公开(公告)日：2010-03-11

    申请号：US12448825

    申请日：2007-12-28

    申请人： Choong-Hoon Lee ,  Eun-Jung Lee ,  Seung-Whan Jung ,  Jung-A Lee ,  Bo-Ram Lee ,  Bun-Yeoul Lee

    发明人： Choong-Hoon Lee ,  Eun-Jung Lee ,  Seung-Whan Jung ,  Jung-A Lee ,  Bo-Ram Lee ,  Bun-Yeoul Lee

    IPC分类号： B01J31/18 ,  C07F7/28 ,  C07F7/00

    CPC分类号： C07F17/00 ,  C08F4/65908 ,  C08F2420/02 ,  Y02P20/55 ,  C08F210/16 ,  C08F210/08 ,  C08F2500/08 ,  C08F2500/12 ,  C08F4/6592

    摘要： The present invention provides a novel transition metal complex where a monocy-clopentadienyl ligand to which an amido group is introduced is coordinated, a method for synthesizing the complex, and olefin polymerization using the same. The method for preparing a transition metal complex according to the present invention comprises a step of blocking a by-reaction of a nitrogen atom using a compound containing a protecting group, and thus it is possible to prepare a transition metal complex in a simpler manner in a high yield. Further, the transition metal complex according to the present invention has a pentagon ring structure having an amido group connected by a phenylene bridge in which a stable bond is formed in the vicinity of a metal site, and thus, sterically monomers can easily approach the transition metal complex. When a catalyst composition comprising the transition metal complex is applied in copoly-merization of ethylene and monomers having large steric hindrance, a very low density polyolefin copolymer having a density of less than 0.910 g/cc, in addition to a polyolefin having a high molecular weight and a linear low density, can be prepared. Furthermore, the reactivity is also very high.

    摘要翻译： 本发明提供了一种新型的过渡金属配合物，其中引入了酰氨基的单环氯苯二酮配体被配位，合成络合物的方法和使用它的烯烃聚合。 本发明的过渡金属络合物的制造方法包括使用含有保护基的化合物阻断氮原子的副反应的工序，因此可以简单地制备过渡金属络合物 高产量。 此外，根据本发明的过渡金属络合物具有通过在金属部位附近形成稳定的键的亚苯基连接的酰胺基的五
    元环结构，因此空间单体容易接近转变 金属复合体。 当包含过渡金属络合物的催化剂组合物被应用于乙烯和具有大的空间位阻的单体的共聚时，除了具有高分子量的聚烯烃之外，密度小于0.910g / cc的非常低密度的聚烯烃共聚物 重量和线性低密度，可以制备。 此外，反应性也非常高。

    Transition metal complexes and preparation methods thereof
    9.
    发明授权
    Transition metal complexes and preparation methods thereof 有权
    过渡金属络合物及其制备方法

    公开(公告)号：US07678933B2

    公开(公告)日：2010-03-16

    申请号：US12087215

    申请日：2006-12-29

    申请人： Choong-Hoon Lee ,  Eun-Jung Lee ,  Seung-Whan Jung ,  Jung-A Lee ,  Bo-Ram Lee ,  Bun-Yeoul Lee

    发明人： Choong-Hoon Lee ,  Eun-Jung Lee ,  Seung-Whan Jung ,  Jung-A Lee ,  Bo-Ram Lee ,  Bun-Yeoul Lee

    IPC分类号： C07F7/00 ,  C07C211/00 ,  C07C49/00

    CPC分类号： C07F17/00 ,  C08F4/65908 ,  C08F210/16 ,  C08F2410/03 ,  C08F2420/02 ,  Y10S526/943 ,  C08F4/6592 ,  C08F210/14

    摘要： The present invention provides a novel mononuclear transition metal compound, a novel binuclear transition metal compound, a novel organic amine or phosphorous compound, and a method for preparing the same. The mononuclear transition metal compound according to the present invention is configured such that a cyclopentadienyl group and an amido or phosphorous group are bridged via a phenylene bridge. The binuclear transition metal compound according to the present invention is configured such that the two bridged mononuclear transition metal compounds configured such that a cyclopentadienyl group and an amido or phosphorous group are bridged via a phenylene bridge are linked via a bridging group located at the phenylene bridge. According to the present invention, the mononuclear transition metal compound, the binuclear transition metal compound, the organic amine or phosphorous compound can be prepared in a simple manner by using suzuki-coupling reaction with a high yield.

    摘要翻译： 本发明提供新颖的单核过渡金属化合物，新型双核过渡金属化合物，新型有机胺或磷化合物及其制备方法。 根据本发明的单核过渡金属化合物被配置为使得环戊二烯基和酰氨基或磷基通过亚苯桥桥连。 根据本发明的双核过渡金属化合物被配置为使得配置成使得环戊二烯基和酰氨基或磷基经由亚苯桥桥连的两个桥连单核过渡金属化合物通过位于亚苯桥的桥连基团连接 。 根据本发明，单体过渡金属化合物，双核过渡金属化合物，有机胺或磷化合物可以通过以高产率使用Suzuki偶联反应简单地制备。

    Transition Metal Complexes and Preparation Methods Thereof
    10.
    发明申请
    Transition Metal Complexes and Preparation Methods Thereof 有权
    过渡金属络合物及其制备方法

    公开(公告)号：US20090030221A1

    公开(公告)日：2009-01-29

    申请号：US12087215

    申请日：2006-12-29

    申请人： Choong-Hoon Lee ,  Eun-Jung Lee ,  Seung-Whan Jung ,  Jung-A Lee ,  Bo-Ram Lee ,  Bun-Yeoul Lee

    发明人： Choong-Hoon Lee ,  Eun-Jung Lee ,  Seung-Whan Jung ,  Jung-A Lee ,  Bo-Ram Lee ,  Bun-Yeoul Lee

    IPC分类号： C07F7/28 ,  C07C49/00 ,  C07C211/44

    CPC分类号： C07F17/00 ,  C08F4/65908 ,  C08F210/16 ,  C08F2410/03 ,  C08F2420/02 ,  Y10S526/943 ,  C08F4/6592 ,  C08F210/14

    摘要： The present invention provides a novel mononuclear transition metal compound, a novel binuclear transition metal compound, a novel organic amine or phosphorous compound, and a method for preparing the same. The mononuclear transition metal compound according to the present invention is configured such that a cyclopentadienyl group and an amido or phosphorous group are bridged via a phenylene bridge. The binuclear transition metal compound according to the present invention is configured such that the two bridged mononuclear transition metal compounds configured such that a cyclopentadienyl group and an amido or phosphorous group are bridged via a phenylene bridge are linked via a bridging group located at the phenylene bridge. According to the present invention, the mononuclear transition metal compound, the binuclear transition metal compound, the organic amine or phosphorous compound can be prepared in a simple manner by using suzuki-coupling reaction with a high yield.

    摘要翻译： 本发明提供新颖的单核过渡金属化合物，新型双核过渡金属化合物，新型有机胺或磷化合物及其制备方法。 根据本发明的单核过渡金属化合物被配置为使得环戊二烯基和酰氨基或磷基通过亚苯桥桥连。 根据本发明的双核过渡金属化合物被配置为使得配置成使得环戊二烯基和酰氨基或磷基经由亚苯桥桥连的两个桥连单核过渡金属化合物通过位于亚苯桥的桥连基团连接 。 根据本发明，单体过渡金属化合物，双核过渡金属化合物，有机胺或磷化合物可以通过以高产率使用偶联偶联反应以简单的方式制备。