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公开(公告)号：US10766997B2
公开(公告)日：2020-09-08
申请号：US15563021
申请日：2016-03-30
Applicant: Dow Global Technologies LLC
Inventor： Francois M. Casati , Irena Amici-Kroutilova , Paul Cookson , Hamideh Ahmadloo , Alberto Lora Lamia
Abstract: Embodiments of the present disclosure are directed towards polyether polyol compositions that can be utilized to form semi-rigid foams. As an example, a polyether polyol composition can include a first polyether polyol having an average nominal hydroxyl functionality from 2 to 4 and a number average equivalent weight from 120 to 1500, a second polyether polyol having a having an average nominal hydroxyl functionality from 4 to 8 and a number average equivalent weight from 120 to 800, and a third polyether polyol having an average nominal hydroxyl functionality from 2 to 4 a number average equivalent weight from 200 to 500.
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2.发明公开公开(公告)号：US20240150516A1
公开(公告)日：2024-05-09
申请号：US18546841
申请日：2022-05-19
Applicant: Dow Global Technologies LLC
Inventor： Hamideh Ahmadloo , Paul Cookson , Nasim Hooshyar , Nebojsa Jelic
IPC: C08G18/38 , C08G18/10 , C08G18/16 , C08G18/18 , C08G18/22 , C08G18/24 , C08G18/32 , C08G18/48 , C08G18/66 , C08G18/76 , C08J9/12
CPC classification number: C08G18/3868 , C08G18/10 , C08G18/165 , C08G18/1808 , C08G18/1833 , C08G18/222 , C08G18/244 , C08G18/3281 , C08G18/4833 , C08G18/6688 , C08G18/7621 , C08J9/125 , C08G2110/0083 , C08J2203/10 , C08J2375/12
Abstract: The present invention provides a sulfur containing polyisocyanate polyaddition (PIPA) polyether polyol dispersion at a readily processible viscosity for use in making flexible polyurethane foams having inherent flame retardant properties that comprises a polyether polyol carrier and from 10 to 25 wt. %, based on the total weight of the dispersion, of particles of a sulfur containing polyisocyanate polyaddition (PIPA) polyether polyol having a particle size diameter (PSD), as determined by laser light scattering, of 90%, by volume, of the particles in the dispersion having a maximum PSD of from 0.2 to 4.5 am and that, further, contain two or more aromatic carbamate groups. The dispersion may further comprise water or a blowing agent, g) one or more catalysts; and f) one or more polyisocyanates in a foam forming mixture. In addition, the present invention provides methods for making the sulfur containing PIPA polyether polyol dispersion comprising mixing polyol reactants under shear and delaying the addition of the sulfur containing polyol or extender reactant.
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公开(公告)号：US20180371150A1
公开(公告)日：2018-12-27
申请号：US15563021
申请日：2016-03-30
Applicant: Dow Global Technologies LLC
Inventor： Francois M. Casati , Irena Amici-Kroutilova , Paul Cookson , Hamideh Ahmadloo , Alberto Lora Lamia
Abstract: Embodiments of the present disclosure are directed towards polyether polyol compositions that can be utilized to form semi-rigid foams. As an example, a polyether polyol composition can include a first polyether polyol having an average nominal hydroxyl functionality from 2 to 4 and a number average equivalent weight from 120 to 1500, a second polyether polyol having a having an average nominal hydroxyl functionality from 4 to 8 and a number average equivalent weight from 120 to 800, and a third polyether polyol having an average nominal hydroxyl functionality from 2 to 4 a number average equivalent weight from 200 to 500.
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4.发明公开公开(公告)号：US20240228692A9
公开(公告)日：2024-07-11
申请号：US18546857
申请日：2022-05-19
Applicant: Dow Global Technologies LLC
Inventor： Hamideh Ahmadloo , Nebojsa Jelic , Paul Cookson , Oguz Türünç , Nasim Hooshyar
CPC classification number: C08G18/5096 , C08G18/2027 , C08G18/246 , C08G18/302 , C08G18/4841 , C08G18/5045 , C08G18/7614 , C08J9/125 , C08G2110/0008 , C08G2110/0083 , C08J2205/06 , C08J2375/04
Abstract: Provides a silicon containing polyisocyanate polyaddition (PIPA) polyether polyol dispersion at readily processible viscosity for use in making flexible polyurethane foams having inherent flame retardant properties that comprises polyether polyol carrier and from 10 to 25 wt. %, based on total weight of dispersion, of particles of a silicon containing (PIPA) polyether polyol having a particle size diameter wherein 90%, by volume, of the particles in dispersion have maximum PSD of from 0.1 to 3 m and that, further, contain two or more aromatic carbamate groups. Dispersion may further comprise water or blowing agent, i) one or more catalysts, and f) one or more polyisocyanates in a foam forming mixture. In addition, provides methods for making the silicon containing PIPA polyether polyol dispersion comprising forming and mixing under shear a base polyol dispersion and delaying the addition of g) one or more polyisocyantes and h) a catalyst while mixing under shear.
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公开(公告)号：US11124595B2
公开(公告)日：2021-09-21
申请号：US16475119
申请日：2017-12-19
Applicant: Dow Global Technologies LLC
Inventor： Hamideh Ahmadloo , Paul Cookson , Ricco B. Borella , Jean-Paul Masy , Lucie Porcelli , Francois Casati
Abstract: A polyol composition is made by polymerizing a mixture of ethylene oxide and propylene oxide onto a mixture of at least one diol initiator and at least one triol initiator, followed by polymerizing 100% propylene oxide or a mixture of at least 90 weight percent propylene oxide and at most 10 weight percent ethylene oxide. The resulting polyol composition has a hydroxyl equivalent weight of 200 to 400 and an average nominal functionality of 2.05 to 2.95 hydroxyl groups/molecule. 5 to 30 percent of the hydroxyl groups of the coinitiated polyether polyol are primary hydroxyl groups and polymerized ethylene oxide constitutes 40 to 63 percent of the total weight of the coinitiated polyether polyol.
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Patent Agency Ranking
公开(公告)号：US10858489B2
公开(公告)日：2020-12-08
申请号：US15563070
申请日：2016-03-30
Applicant: Dow Global Technologies LLC
Inventor： Paul Cookson , Irena Amici-Kroutilova , Francois M. Casati , Hamideh Ahmadloo , Alberto Lora Lamia
Abstract: Embodiments of the present disclosure are directed towards semi-flexible foam formulations that can be utilized to form semi-flexible foams. As an example, a semiflexible foam formulation can include a first polyether polyol having an average nominal hydroxyl functionality from 2 to 4 and a number average equivalent weight from 120 to 1500, a second polyether polyol having a having an average nominal hydroxyl functionality from 4 to 8 and a number average equivalent weight from 120 to 800, and a third polyether polyol having an average nominal hydroxyl functionality from 2 to 4 a number average equivalent weight from 200 to 500 and toluene diisocyanate.
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7.发明公开公开(公告)号：US20240132658A1
公开(公告)日：2024-04-25
申请号：US18546857
申请日：2022-05-18
Applicant: Dow Global Technologies LLC
Inventor： Hamideh Ahmadloo , Nebojsa Jelic , Paul Cookson , Oguz Türünç , Nasim Hooshyar
CPC classification number: C08G18/5096 , C08G18/2027 , C08G18/246 , C08G18/302 , C08G18/4841 , C08G18/5045 , C08G18/7614 , C08J9/125 , C08G2110/0008 , C08G2110/0083 , C08J2205/06 , C08J2375/04
Abstract: Provides a silicon containing polyisocyanate polyaddition (PIPA) polyether polyol dispersion at readily processible viscosity for use in making flexible polyurethane foams having inherent flame retardant properties that comprises polyether polyol carrier and from 10 to 25 wt. %, based on total weight of dispersion, of particles of a silicon containing (PIPA) polyether polyol having a particle size diameter wherein 90%, by volume, of the particles in dispersion have maximum PSD of from 0.1 to 3 m and that, further, contain two or more aromatic carbamate groups. Dispersion may further comprise water or blowing agent, i) one or more catalysts, and f) one or more polyisocyanates in a foam forming mixture. In addition, provides methods for making the silicon containing PIPA polyether polyol dispersion comprising forming and mixing under shear a base polyol dispersion and delaying the addition of g) one or more polyisocyantes and h) a catalyst while mixing under shear.
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公开(公告)号：US11608421B2
公开(公告)日：2023-03-21
申请号：US16767628
申请日：2018-12-13
Applicant: Dow Global Technologies LLC
Inventor： Oguz Türünç , Francois M. Casati , Hamideh Ahmadloo , Alex Stepuk , Paul Cookson
Abstract: Dispersions of silicate particles are formed in a polyol phase. The polyol, an alkoxysilane, water and catalyst are combined and reacted under specific temperature conditions to form the silicate particles in-situ in a liquid polyol phase. The dispersions are characterized in having excellent stability.
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公开(公告)号：US20190330406A1
公开(公告)日：2019-10-31
申请号：US16475119
申请日：2017-12-19
Applicant: Dow Global Technologies LLC
Inventor： Hamideh Ahmadloo , Paul Cookson , Ricco B. Borella , Jean-Paul Masy , Lucie Porcelli , Francois Casati
Abstract: A polyol composition is made by polymerizing a mixture of ethylene oxide and propylene oxide onto a mixture of at least one diol initiator and at least one triol initiator, followed by polymerizing 100% propylene oxide or a mixture of at least 90 weight percent propylene oxide and at most 10 weight percent ethylene oxide. The resulting polyol composition has a hydroxyl equivalent weight of 200 to 400 and an average nominal functionality of 2.05 to 2.95 hydroxyl groups/molecule. 5 to 30 percent of the hydroxyl groups of the coinitiated polyether polyol are primary hydroxyl groups and polymerized ethylene oxide constitutes 40 to 63 percent of the total weight of the coinitiated polyether polyol.
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公开(公告)号：US20200369845A1
公开(公告)日：2020-11-26
申请号：US16767628
申请日：2018-12-13
Applicant: Dow Global Technologies LLC
Inventor： Oguz Türünç , Francois M. Casati , Hamideh Ahmadloo , Alex Stepuk , Paul Cookson
Abstract: Dispersions of silicate particles are formed in a polyol phase. The polyol, an alkoxysilane, water and catalyst are combined and reacted under specific temperature conditions to form the silicate particles in-situ in a liquid polyol phase. The dispersions are characterized in having excellent stability.
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