公开(公告)号：US20180230099A1

公开(公告)日：2018-08-16

申请号：US15574051

申请日：2016-05-27

申请人： Dow Global Technologies LLC

发明人： Chunming Zhang ,  Arvind Jaganathan ,  Heqi Pan ,  Philip Fontaine ,  Jerzy Klosin

IPC分类号： C07D209/86 ,  C07F7/08 ,  C07D209/88

CPC分类号： C07D209/86 ,  C07D209/88 ,  C07F7/083

摘要： A process for preparing one or more carbazoles comprising (a) contacting one or more compounds represented by formula (1) below with diboron reagents in the presence of PdCl2(dppf) to form one or more 2,2′-dichlorobiaryl represented by formula (2) below; and (b) contacting the one or more 2,2′-dichlorobiaryls with one or more H2N—Y compounds, in the presence of one or more palladium containing catalytic components; thereby forming one or more carbazoles represented by formula (3) below is provided.

公开(公告)号：US10167301B2

公开(公告)日：2019-01-01

申请号：US15575083

申请日：2016-05-25

申请人： Dow Global Technologies LLC

发明人： Chunming Zhang ,  Heqi Pan ,  Jerzy Klosin ,  Philip Fontaine ,  David Wilson

IPC分类号： C07F7/12

摘要： The instant invention provides a process for the preparation of bis(chloromethyl)dichlorosilane (BCMCS) or bis(chloromethyl) (aryl)chlorosilane (BCMACS) comprising reacting bis(chloromethyl) diphenylsilane and one or more chloride compounds in the presence of a Lewis acid in an inert solvent and under an inert atmosphere.

公开(公告)号：US10246415B2

公开(公告)日：2019-04-02

申请号：US15574051

申请日：2016-05-27

申请人： Dow Global Technologies LLC

发明人： Chunming Zhang ,  Arvind Jaganathan ,  Heqi Pan ,  Philip Fontaine ,  Jerzy Klosin

IPC分类号： C07D209/86 ,  C07D209/88 ,  C07F7/08

摘要： A process for preparing one or more carbazoles comprising (a) contacting one or more compounds represented by formula (1) below with diboron reagents in the presence of PdCl2(dppf) to form one or more 2,2′-dichlorobiaryl represented by formula (2) below; and (b) contacting the one or more 2,2′-dichlorobiaryls with one or more H2N—Y compounds, in the presence of one or more palladium containing catalytic components; thereby forming one or more carbazoles represented by formula (3) below is provided.

公开(公告)号：US20180155369A1

公开(公告)日：2018-06-07

申请号：US15575083

申请日：2016-05-25

申请人： Dow Global Technologies LLC

发明人： Chunming Zhang ,  Heqi Pan ,  Jerzy Klosin ,  Philip Fontaine ,  David Wilson

IPC分类号： C07F7/12

CPC分类号： C07F7/123

摘要： The instant invention provides a process for the preparation of bis(chloromethyl)dichlorosilane (BCMCS) or bis(chloromethyl) (aryl)chlorosilane (BCMACS) comprising reacting bis(chloromethyl) diphenylsilane and one or more chloride compounds in the presence of a Lewis acid in an inert solvent and under an inert atmosphere.