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公开(公告)号:US20240052075A1
公开(公告)日:2024-02-15
申请号:US18277322
申请日:2022-02-10
发明人: Joseph F. DeWilde , Ruth Figueroa , Leslie E. O'Leary , Susan Brown , David M. Pearson , Jerzy Klosin
IPC分类号: C08F210/16
CPC分类号: C08F210/16
摘要: Embodiments are directed towards a use of a biphenylphenol polymerization catalyst to make a polymer in a gas-phase or slurry-phase polymerization process conducted in a single gas-phase or slurry-phase polymerization reactor, wherein the biphenylphenol polymerization catalyst is made from a biphenylphenol polymerization precatalyst of Formula I, and wherein the biphenylphenol polymerization catalyst has a kinetic induction time of greater than 40 seconds as determined by a least squares fit of a first-order exponential for a rate of increase of an instantaneous polymerization rate for the gas-phase or slurry-phase polymerization process.
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公开(公告)号:US11542350B2
公开(公告)日:2023-01-03
申请号:US17043154
申请日:2019-03-22
发明人: Richard J. Keaton , Rafael Huacuja , David R. Wilson , Jerzy Klosin , David M. Pearson , Todd D. Senecal , Sukrit Mukhopadhyay , William H. H. Woodward
摘要: Embodiments of the disclosure include processes of polymerizing olefins. The process includes contacting ethylene and a (C3-C40)alpha-olefin comonomer in the presences of a catalyst system. The catalyst system comprises a procatalyst and a bimetallic activator complex. The bimetallic activator complex comprises an anion and a countercation, and the anion has a structure according to formula (I).
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公开(公告)号:US11447586B2
公开(公告)日:2022-09-20
申请号:US17043304
申请日:2019-03-26
发明人: Richard J. Keaton , Rafael Huacuja , David R. Wilson , Jerzy Klosin , David M. Pearson , Todd D. Senecal , Sukrit Mukhopadhyay , William H. H. Woodward
摘要: Embodiments of this disclosure include processes of polymerizing olefins, the process comprising contacting ethylene and a (C3-C40)alpha-olefin comonomer in the presence of a catalyst system, the catalyst system comprising a Group IV metal-ligand complex and an ionic metallic activator complex, the ionic metallic activator complex comprising an anion and a countercation, the anion having a structure according to formula (I):formula (I)
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公开(公告)号:US11111318B2
公开(公告)日:2021-09-07
申请号:US16317996
申请日:2017-07-28
发明人: Hien Q. Do , Philip P. Fontaine , Andrew J. Young , Susan G. Brown , Johnathan E. DeLorbe , Tulaza Vaidya , Zach T. Rickaway , Amy E. Floeck (nee Duchnowski) , Chunming Zhang , Ruth Figueroa , Jerzy Klosin
IPC分类号: C08F4/64 , C08F210/16 , C08F2/38
摘要: Embodiments are directed to a metal complex formed, wherein the metal complexes are used as pro-catalyst in polyolefin polymerization and comprise the following structure (Formula (I)).
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公开(公告)号:US20210221927A1
公开(公告)日:2021-07-22
申请号:US16310912
申请日:2017-06-21
摘要: The present disclosure provides a composition containing a sulfonamide aliphatic anhydride grafted olefin-based polymer. The present disclosure also provides a multilayer structure. In an embodiment, a multilayer film is provided and includes: a layer (A) comprising an olefin-based polymer; a layer (B) that is a tie layer comprising a sulfonamide aliphatic anhydride grafted olefin-based polymer (SAA-g-PO); and a layer (C) comprising a polar component.
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公开(公告)号:US20210002467A1
公开(公告)日:2021-01-07
申请号:US16982514
申请日:2019-03-18
发明人: Matthias Ober , Longyan Liao , Jasson T. Patton , Sukrit Mukhopadhyay , Jerzy Klosin , David D. Devore
摘要: A process to functionalized organo-metal compounds with silyl-based electrophiles. The process includes combining an organo-metal compound, a silyl-based functionalization agent, and an optional solvent. Functionalized silanes and silyl-terminated polyolefins can be prepared by this process.
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公开(公告)号:US10519260B2
公开(公告)日:2019-12-31
申请号:US15311299
申请日:2015-06-29
发明人: Philip P. Fontaine , Jerzy Klosin , Endre Szuromi , Carl N. Iverson , Zach T. Rickaway , Andrew J. Young , Susan G. Brown , Ruth Figueroa , Mehmet Demirors , Mridula Kapur
IPC分类号: C08F4/76 , C08F4/64 , C08F210/16 , C08F4/659
摘要: The invention provides a process to form an olefin-based polymer, said process comprising polymerizing at least one olefin in the presence of at least one catalyst system comprising the reaction product of the following: A) at least one cocatalyst; and B) a procatalyst comprising a metal-ligand complex of Formula (I), as described herein: (Formula I).
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公开(公告)号:US10376869B2
公开(公告)日:2019-08-13
申请号:US15557920
申请日:2016-03-10
发明人: Jerzy Klosin , Kara A. Milbrandt , Scott D. Boelter , David R. Wilson , Mari S. Rosen , Dean M. Welsh , Peter M. Margl , Kyoung Moo Koh , David M. Pearson , Rafael Huacuja
IPC分类号: C07C2/36 , B01J31/14 , B01J31/18 , B01J31/22 , B01J31/24 , C07C11/02 , C07F11/00 , C07F17/02 , C07C11/107 , C07F9/6568 , C07F9/6571 , C07F9/6584
摘要: The invention relates to oligomerization of olefins, such as ethylene, to higher olefins, such as a mixture of 1-hexene and 1-octene, using a catalyst system that comprises a) a source of chromium b) one or more activators and c) a phosphacycle-containing ligating compound. Additionally, the invention relates to a phosphacycle-containing ligating compound and a process for making said compound.
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9.
公开(公告)号:US10301412B2
公开(公告)日:2019-05-28
申请号:US15518672
申请日:2015-12-02
发明人: Jerzy Klosin , Endre Szuromi , Liam P. Spencer
摘要: The invention provides a molecular transition metal complex selected from Formula 1, as described herein; an ethylene-based polymer; and a process to form the ethylene-based polymer, said process comprising polymerizing ethylene in the presence of at least one molecular transition metal complex selected from Formula 1, as described herein, and wherein either Z1 or Z2 is dative covalent (coordinate) to the metal (M).
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公开(公告)号:US10246415B2
公开(公告)日:2019-04-02
申请号:US15574051
申请日:2016-05-27
发明人: Chunming Zhang , Arvind Jaganathan , Heqi Pan , Philip Fontaine , Jerzy Klosin
IPC分类号: C07D209/86 , C07D209/88 , C07F7/08
摘要: A process for preparing one or more carbazoles comprising (a) contacting one or more compounds represented by formula (1) below with diboron reagents in the presence of PdCl2(dppf) to form one or more 2,2′-dichlorobiaryl represented by formula (2) below; and (b) contacting the one or more 2,2′-dichlorobiaryls with one or more H2N—Y compounds, in the presence of one or more palladium containing catalytic components; thereby forming one or more carbazoles represented by formula (3) below is provided.
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