-
公开(公告)号：US5756591A
公开(公告)日：1998-05-26
申请号：US865041
申请日：1997-05-29
IPC分类号： C08L101/00 , C08F2/00 , C08F8/00 , C08F10/00 , C08F14/04 , C08F16/16 , C08F18/08 , C08F20/08 , C08F20/10 , C08F212/06 , C08F246/00 , C09D5/03 , C09D133/04 , C08F8/30 , B05D3/02 , B32B27/28
CPC分类号： C08F246/00 , C08F8/12 , C08F8/42 , C08F220/08 , C08F220/14 , C08F220/20 , C08F2800/20 , C08F2810/20 , C08F2810/50 , Y10T428/31855
摘要： A network polymer that contains: (a) a plurality of polymer chains which are derived from one or more ethylenically-unsaturated monomer(s), and (b) at least one linking group which links the polymer chains and which contains anhydride, carbonate, or uretidinedione moieties. The network polymer and other network polymers which contain similar dissociating groups are useful in curable formulations which contain a curable compound that contains: (a) a central moiety, and (b) a plurality of reactive groups which are bonded to the central moiety and which react with acid, hydroxyl, or isocyanate moieties liberated by dissociation of the anhydride, carbonate, or uretidinedione moieties. The curable composition builds viscosity more slowly and more controllably during curing than equivalent systems which do not contain the network polymer. It is useful in coatings and other uses for curable compositions.
摘要翻译： 一种网络聚合物，其包含：（a）多个聚合物链，其衍生自一种或多种烯键式不饱和单体，和（b）至少一个连接所述聚合物链并且含有酸酐，碳酸酯， 或脲基二酮部分。 含有相似解离基团的网状聚合物和其它网状聚合物可用于含有可固化化合物的可固化制剂，该可固化化合物包含：（a）中心部分，和（b）多个结合至中心部分的反应性基团， 与酸酐，羟基或异氰酸酯部分与酸酐，碳酸酯或脲基二酮部分解离而释放出来。 固化组合物在固化期间比不含网络聚合物的等效体系更缓慢地和更可控地增加粘度。 它可用于可固化组合物的涂料和其它用途。
-
公开(公告)号：US5663259A
公开(公告)日：1997-09-02
申请号：US455730
申请日：1995-05-31
IPC分类号： C08L101/00 , C08F2/00 , C08F8/00 , C08F10/00 , C08F14/04 , C08F16/16 , C08F18/08 , C08F20/08 , C08F20/10 , C08F212/06 , C08F246/00 , C09D5/03 , C09D133/04 , C08F220/08 , C08F18/24 , C08F226/02
CPC分类号： C08F246/00 , C08F8/12 , C08F8/42 , C08F220/08 , C08F220/14 , C08F220/20 , C08F2800/20 , C08F2810/20 , C08F2810/50 , Y10T428/31855
摘要： A network polymer that contains:(a) a plurality of polymer chains which are derived from one or more ethylenically-unsaturated monomer(s), and(b) at least one linking group which links the polymer chains and which contains anhydride, carbonate, or uretidinedione moieties.The network polymer and other network polymers which contain similar dissociating groups are useful in curable formulations which contain a curable compound that contains:(a) a central moiety, and(b) a plurality of reactive groups which are bonded to the central moiety and which react with acid, hydroxyl, or isocyanate moieties liberated by dissociation of the anhydride, carbonate, or uretidinedione moieties.The curable composition builds viscosity more slowly and more controllably during curing than equivalent systems which do not contain the network polymer. It is useful in coatings and other uses for curable compositions.
摘要翻译： 一种网络聚合物，其包含：（a）多个聚合物链，其衍生自一种或多种烯键式不饱和单体，和（b）至少一个连接所述聚合物链并且含有酸酐，碳酸酯， 或脲基二酮部分。 含有相似解离基团的网状聚合物和其它网状聚合物可用于含有可固化化合物的可固化组合物，该可固化化合物含有：（a）中心部分，和（b）多个结合至中心部分的反应性基团， 与酸酐，羟基或异氰酸酯部分与酸酐，碳酸酯或脲基二酮部分解离而释放出来。 固化组合物在固化期间比不含网络聚合物的等效体系更缓慢地和更可控地增加粘度。 它可用于可固化组合物的涂料和其它用途。
-
公开(公告)号：US07049388B2
公开(公告)日：2006-05-23
申请号：US10658049
申请日：2003-09-09
IPC分类号： C07D301/03 , C07D301/12 , C07D301/19 , C08G59/02
CPC分类号： C07D303/22 , C07D301/14
摘要： A process for manufacturing an α-dihydroxy derivative from an aryl allyl ether wherein such α-dihydroxy derivative can be used to prepare an α-halohydrin intermediate and an epoxy resin prepared therefrom including epoxidizing an α-halohydrin intermediate produced from a halide substitution of an α-dihydroxy derivative which has been obtained by a dihydroxylation reaction of an aryl allyl ether in the presence of an oxidant or in the presence of an oxidant and a catalyst.
-
4.发明授权Process for making carboxylic acid esters using a crosslinked acrylic resin as the catalyst 失效使用交联丙烯酸树脂作为催化剂制备羧酸酯的方法
公开(公告)号：US4970333A
公开(公告)日：1990-11-13
申请号：US114893
申请日：1987-10-29
CPC分类号： C07C67/26
摘要： The production of esters via the reaction of an epoxide with a carboxylic acid hasbeen shown to give improved activity when a strong base macroporous anion exchange resin having an acrylic backbone is used in place of a styrene-divinylbenzene based anion exchange resin having an equivalent exchange capacity. Excellent results are obtained when acrylic acid and propylene oxide are reacted together in the presence of strong base macroporous anion exchange resins which have an acrylic backbone.
摘要翻译： 通过环氧化物与羧酸的反应制备酯已经显示出，当使用具有丙烯酸骨架的强碱性大孔性阴离子交换树脂代替具有等效交换容量的苯乙烯 - 二乙烯基苯阴离子交换树脂时，可提供更好的活性 。 丙烯酸和环氧丙烷在具有丙烯酸骨架的强碱性大孔阴离子交换树脂的存在下一起反应时，可获得优异的结果。
-
公开(公告)号：US6087513A
公开(公告)日：2000-07-11
申请号：US316854
申请日：1999-05-21
申请人： Zeng K. Liao , Clinton J. Boriack
发明人： Zeng K. Liao , Clinton J. Boriack
IPC分类号： C07D301/03 , C07D301/19 , C07D303/22 , C07D303/23 , C07D303/24
CPC分类号： C07D301/19 , C07D303/22 , C07D303/24 , Y02P20/582
摘要： A process for making an aromatic glycidyl ether epoxy compound by contacting an allyl ether made from the hydroxy moiety of a hydroxy-containing aromatic compound with an inorganic or organic hydroperoxide oxidant in the presence of a transition metal complex catalyst, wherein at least (a) the allyl ether is conformationally restricted or (b) the transition metal complex catalyst contains at least one or more stable ligands attached to the transition metal. The process of the present invention provides for epoxidizing aryl allyl ethers with high epoxidation yield (for example, greater than 70% to 90%) and high hydroperoxide selectivity (for example, greater than 70% to 90%).
摘要翻译： 在过渡金属络合物催化剂的存在下，使由含羟基的芳族化合物的羟基部分制备的烯丙基醚与无机或有机氢过氧化物氧化剂接触制备芳族缩水甘油醚环氧化合物的方法，其中至少（a） 烯丙基醚被构象限制，或（b）过渡金属络合物催化剂含有至少一个或多个与过渡金属连接的稳定配体。 本发明的方法提供具有高环氧化产率（例如，大于70％至90％）和高氢过氧化物选择性（例如，大于70％至90％）的环氧化芳基烯丙基醚。
-
公开(公告)号：US5354896A
公开(公告)日：1994-10-11
申请号：US12104
申请日：1993-02-01
IPC分类号： C07C67/26
CPC分类号： C07C67/26
摘要： Strong base anion exchange resins that contain quaternary ammonium groups derived from higher molecular weight amines, such as triethylamine or tripropylamine instead of trimethylamine, have a higher reactivity for catalyzing the reaction of an epoxide compound with an acid compound to form an ester.
摘要翻译： 含有衍生自较高分子量胺（例如三乙胺或三丙胺）代替三甲胺的季铵基的强碱阴离子交换树脂具有较高的催化环氧化合物与酸化合物反应形成酯的反应性。
-
公开(公告)号：US4336349A
公开(公告)日：1982-06-22
申请号：US219071
申请日：1980-12-22
IPC分类号： C08F20/22 , C07C67/04 , C08F18/20 , C08F299/00
CPC分类号： C08F20/22 , Y10T428/31649
摘要： Chlorinated cycloaliphatic (meth) acrylate compositions are prepared by the reaction of chlorine at a temperature in the range from -30.degree. C. to 50.degree. C. with compositions made by reacting (meth) acrylic acid with crude dicyclopentadiene in the presence of a Friedel-Crafts catalyst such as BF.sub.3. The chlorinated compositions have a pleasant fruity odor and are useful to make homopolymers or copolymers which find use as metal coatings, inks, ultraviolet light curable coatings and the like.
摘要翻译： 氯化脂环族（甲基）丙烯酸酯组合物是通过在-30℃至50℃的温度下与氯反应制备的，其中组合物是通过使（甲基）丙烯酸与粗二环戊二烯在Friedel - 催化剂如BF3。 氯化组合物具有令人愉快的果香气味，并且可用于制备用作金属涂料，油墨，紫外光固化涂料等的均聚物或共聚物。
-
公开(公告)号：US08461286B2
公开(公告)日：2013-06-11
申请号：US12933840
申请日：2009-03-24
申请人： Thomas C. Young , Clinton J. Boriack , Elwin G. Collier , Robert M. Drake , Joachim Drewing , Edward J. Kronenberger , Shuji Maeda , Paulo Alfonso Dos Santos Pereira , Andreas Tigges , Roland Werner , Mark S. Burkinshaw
发明人： Thomas C. Young , Clinton J. Boriack , Elwin G. Collier , Robert M. Drake , Joachim Drewing , Edward J. Kronenberger , Shuji Maeda , Paulo Alfonso Dos Santos Pereira , Andreas Tigges , Roland Werner , Mark S. Burkinshaw
IPC分类号： C08G59/06 , C08L61/12 , C07D301/27
CPC分类号： C08G59/063
摘要： A process for the production of liquid epoxy resins, including: contacting a polyhydric phenol and an epihalohydrin in the presence of an ionic catalyst to form a halohydrin intermediate reaction product; concurrently: reacting a portion of the halohydrin intermediate reaction product with an alkali hydroxide to form a solid salt suspended in a liquid mixture including a dehydrohalogenated product and unreacted halohydrin intermediate, wherein the alkali hydroxide is used at less than a stoichiometric amount; and removing water and epihalohydrin as a vapor from the reacting mixture; separating the solid salt from the liquid mixture; reacting at least a portion of the unreacted halohydrin intermediate with an alkali hydroxide in the presence of water to form an organic mixture including an epoxy resin and unreacted epihalohydrin and an aqueous solution including a salt; separating the aqueous mixture from the organic mixture; and separating the unreacted epihalohydrin from the liquid epoxy resin.
摘要翻译： 一种制备液体环氧树脂的方法，包括：在离子催化剂存在下使多元酚与表卤醇接触以形成卤代醇中间体反应产物; 同时：将一部分卤代醇中间体反应产物与碱金属氢氧化物反应以形成悬浮在包含脱卤化氢产物和未反应的卤代醇中间体的液体混合物中的固体盐，其中碱金属氢氧化物以小于化学计量的量使用; 并从反应混合物中除去作为蒸汽的水和表卤代醇; 从液体混合物中分离出固体盐; 在水的存在下使至少一部分未反应的卤代醇中间体与碱金属氢氧化物反应，形成包含环氧树脂和未反应的表卤代醇的有机混合物和包含盐的水溶液; 从有机混合物中分离含水混合物; 并从液态环氧树脂中分离出未反应的表卤代醇。
-
公开(公告)号：US20110028744A1
公开(公告)日：2011-02-03
申请号：US12933840
申请日：2009-03-24
申请人： Thomas C. Young , Clinton J. Boriack , Elwin G. Collier , Robert M. Drake , Joachim Drewing , Edward J. Kronenberger , Shuji Maeda , Paulo Alfonso Dos Santos Pereira , Andreas Tigges , Roland Werner , Mark S. Burkinshaw
发明人： Thomas C. Young , Clinton J. Boriack , Elwin G. Collier , Robert M. Drake , Joachim Drewing , Edward J. Kronenberger , Shuji Maeda , Paulo Alfonso Dos Santos Pereira , Andreas Tigges , Roland Werner , Mark S. Burkinshaw
IPC分类号： C07D301/27
CPC分类号： C08G59/063
摘要： A process for the production of liquid epoxy resins, including: contacting a polyhydric phenol and an epihalohydrin in the presence of an ionic catalyst to form a halohydrin intermediate reaction product; concurrently: reacting a portion of the halohydrin intermediate reaction product with an alkali hydroxide to form a solid salt suspended in a liquid mixture including a dehydrohalogenated product and unreacted halohydrin intermediate, wherein the alkali hydroxide is used at less than a stoichiometric amount; and removing water and epihalohydrin as a vapor from the reacting mixture; separating the solid salt from the liquid mixture; reacting at least a portion of the unreacted halohydrin intermediate with an alkali hydroxide in the presence of water to form an organic mixture including an epoxy resin and unreacted epihalohydrin and an aqueous solution including a salt; separating the aqueous mixture from the organic mixture; and separating the unreacted epihalohydrin from the liquid epoxy resin.
摘要翻译： 一种制备液体环氧树脂的方法，包括：在离子催化剂存在下使多元酚与表卤醇接触以形成卤代醇中间体反应产物; 同时：将一部分卤代醇中间体反应产物与碱金属氢氧化物反应以形成悬浮在包含脱卤化氢产物和未反应的卤代醇中间体的液体混合物中的固体盐，其中碱金属氢氧化物以小于化学计量的量使用; 并从反应混合物中除去作为蒸汽的水和表卤代醇; 从液体混合物中分离出固体盐; 在水的存在下使至少一部分未反应的卤代醇中间体与碱金属氢氧化物反应，形成包含环氧树脂和未反应的表卤代醇的有机混合物和包含盐的水溶液; 从有机混合物中分离含水混合物; 并从液态环氧树脂中分离出未反应的表卤代醇。
-
10.发明授权公开(公告)号：US06646102B2
公开(公告)日：2003-11-11
申请号：US09899409
申请日：2001-07-05
IPC分类号： C07D30103
CPC分类号： C07D303/22 , C07D301/14
摘要： A process for manufacturing an &agr;-dihydroxy derivative from an aryl allyl ether wherein such &agr;-dihydroxy derivative can be used to prepare an &agr;-halohydrin intermediate and an epoxy resin prepared therefrom including epoxidizing an &agr;-halohydrin intermediate produced from a halide substitution of an &agr;-dihydroxy derivative which has been obtained by a dihydroxylation reaction of an aryl allyl ether in the presence of an oxidant or in the presence of an oxidant and a catalyst.
摘要翻译： 从芳基烯丙基醚制备α-二羟基衍生物的方法，其中这种α-二羟基衍生物可用于制备α-卤代醇中间体和由其制备的环氧树脂，其包括环氧化由卤代烃取代的α-卤代醇中间体 通过芳基烯丙基醚在氧化剂或氧化剂和催化剂存在下的二羟基化反应得到的α-二羟基衍生物。
-
-
-
-
-
-
-
-
-
搜索结果
13 条记录 (耗时 0.023 秒)
