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公开(公告)号：US4798877A
公开(公告)日：1989-01-17
申请号：US720769
申请日：1985-04-08
IPC分类号： C08F299/02 , C08G59/14 , C08F283/10
CPC分类号： C08F299/026 , C08G59/1433
摘要： Novel radiation-curable, water-compatible, resinous compositions result from (1) terminally unsaturated molecules which are the esters of an epoxy compound and (2) the reaction product of a glycidyl ether and an unsaturated acid having at least one glycidyl group per molecule converted to an onium salt of a quaternary ammonium or amine salt, with the anion of an inorganic or organic acid.
摘要翻译： 新的可辐射固化的水溶性树脂组合物来自（1）作为环氧化合物的酯的末端不饱和分子和（2）每分子具有至少一个缩水甘油基的缩水甘油醚和不饱和酸的反应产物 转化为季铵盐或胺盐的鎓盐与无机或有机酸的阴离子。
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公开(公告)号：US4338232A
公开(公告)日：1982-07-06
申请号：US137706
申请日：1980-04-07
CPC分类号： C08G59/1433 , Y10S522/904 , Y10S525/922
摘要： Novel sulfonium-stabilized, radiation-curable, water-compatible, water-in-oil emulsions and a method of preparation are described. As an example, one such emulsion was prepared by reacting the diglycidyl ether of a polypropylene glycol with essentially a stoichiometric equivalent of acrylic acid, about 0.3 equivalent of bis(2-hydroxyethyl)-sulfide and 1.5 equivalents of H.sub.2 O.
摘要翻译： 描述了新的锍稳定的，可辐射固化的，水相容的油包水乳液和制备方法。 作为实例，通过使聚丙二醇的二缩水甘油醚与基本上化学计量当量的丙烯酸，约0.3当量的双（2-羟乙基） - 硫化物和1.5当量的H 2 O反应来制备一种这样的乳液。
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3.发明授权Stable dispersions of polymers in polyfunctional compounds having a plurality of active hydrogens and polyurethanes therefrom 失效聚合物在具有多个活性氢的多官能化合物中的稳定分散体和聚氨酯
公开(公告)号：US4390645A
公开(公告)日：1983-06-28
申请号：US97070
申请日：1979-11-23
IPC分类号： C08G18/00 , C08F291/08 , C08F299/06 , C08G18/40 , C08G18/63 , C08G18/67 , C08G18/72 , C08G18/81 , C08G18/14
CPC分类号： C08F291/08 , C08F299/06 , C08G18/40 , C08G18/635 , C08G18/728 , C08G18/8108
摘要： A stable copolymer dispersion is prepared by addition copolymerization of (1) an adduct of an active hydrogen compound, e.g., a polyether polyol, and an active ethylenically unsaturated isocyanate, e. g., 2-isocyanatoethyl methacrylate with (2) ethylenically unsaturated monomers(s), e.g., styrene or mixture thereof with acrylonitrile, while (1) and (2) are dispersed or dissolved in an excess of an active hydrogen polyfunctional compound. The resulting dispersion has a controlled particle size and a viscosity such that it is suitably employed in the production of polyurethane foams.
摘要翻译： 通过（1）活性氢化合物例如聚醚多元醇和活性烯键式不饱和异氰酸酯的加合物的加成共聚制备稳定的共聚物分散体， （2）烯键式不饱和单体，例如苯乙烯或其与丙烯腈的混合物，而（1）和（2）分散或溶解在过量的活性氢多官能化合物中。 所得到的分散体具有受控的粒度和粘度，使得它适合用于生产聚氨酯泡沫体。
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4.发明授权Stable dispersions of polymers in polyfunctional compounds having a plurality of active hydrogens and polyurethanes produced therefrom 失效聚合物在具有多种活性氢的多官能化合物和由其制备的聚氨酯中的稳定分散体
公开(公告)号：US4460715A
公开(公告)日：1984-07-17
申请号：US320160
申请日：1981-11-10
IPC分类号： C08F283/06 , C08F291/08 , C08G18/40 , C08G18/63 , C08G18/81 , C08G18/14 , C08G18/30
CPC分类号： C08F291/08 , C08F283/06 , C08G18/40 , C08G18/63 , C08G18/81
摘要： A stable copolymer dispersion is prepared by addition copolymerization of (1) a monomeric adduct of an active hydrogen compound, e.g., a polyether polyol, and an acrylyl compound such as methacryloyl chloride with (2) ethylenically unsaturated monomer(s), e.g., styrene or a mixture thereof with acrylonitrile, while (1) and (2) are dispersed or dissolved in an excess of an active hydrogen polyfunctional compound such as a polyether polyol. The molar ratio of acrylyl moiety to active hydrogen compound is less than 0.1:1. The resulting dispersion has a controlled particle size and a viscosity such that it is suitably employed in the production of polyurethane foams.
摘要翻译： 通过（1）活性氢化合物例如聚醚多元醇和丙烯酰基化合物如甲基丙烯酰氯与（2）烯键式不饱和单体的单体加合物（例如苯乙烯）的加成共聚制备稳定的共聚物分散体 或其与丙烯腈的混合物，而（1）和（2）分散或溶解在过量的活性氢多官能化合物如聚醚多元醇中。 丙烯酰部分与活性氢化合物的摩尔比小于0.1：1。 所得到的分散体具有受控的粒度和粘度，使得它适合用于生产聚氨酯泡沫体。
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5.发明授权Process for the preparation of radiation-curable, water-thinnable vinyl ester resins 失效用于制备可辐射固化的，可水解的乙烯基酯树脂的方法
公开(公告)号：US4431782A
公开(公告)日：1984-02-14
申请号：US456225
申请日：1983-01-07
IPC分类号： C08G59/14 , C08G59/66 , C09D163/10 , C08F283/00
CPC分类号： C08G59/66 , C08G59/1433 , C08G59/1483 , C09D163/10 , Y10S525/922
摘要： Sulfonium-stabilized, water-compatible, radiation-curable vinyl ester resins are prepared by the process of reacting an epoxy resin having on the average at least one vicinal epoxy group with a mercaptan and with an unsaturated monocarboxylic acid to form vinyl ester resins containing sulfide moieties which are then reacted with a protonic acid and an alkylene oxide.Compounds so prepared can be diluted with water and used as coatings.
摘要翻译： 通过使具有平均至少一个邻位环氧基的环氧树脂与硫醇和不饱和一元羧酸反应形成含硫化物的乙烯基酯树脂的方法制备锍稳定的水溶性的可辐射固化的乙烯基酯树脂 然后其与质子酸和烯化氧反应。 如此制备的化合物可以用水稀释并用作涂层。
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6.发明授权Hydroxy-functional polyethers containing urea, biuret, thiourea, dithiobiuret, thioamide, and/or amide moieties in their backbone and urethane/urea prepolymers and polymers made therefrom 失效在其主链中含有尿素，缩二脲，硫脲，二硫代尿苷，硫代酰胺和/或酰胺部分的羟基官能聚醚和由其制备的氨基甲酸酯/脲预聚物和聚合物
公开(公告)号：US5272244A
公开(公告)日：1993-12-21
申请号：US774013
申请日：1991-10-08
CPC分类号： C08G18/5024 , C08G18/5036 , C08G18/5072 , C08G71/02 , C08G2120/00
摘要： Described herein are modified polyahls comprising (a) a backbone portion containing at least one polyalkyleneoxy moiety and one or more internal urea, amide, biuret, thiourea, dithiobiuret, or thioamide moieties, (b) end groups selected from the group consisting of amino, hydroxy amide or hydroxyester amide, wherein at least one end group is hydroxy amide or hydroxyester amide, wherein each internal moiety is separated from each other and from each end group by at lit least one alkylene, cycloalkylene, aralkylene, arylene, or alkyleneoxy moiety with 4-20 carbon atoms, or at least one polyalkyleneoxy moiety containing from 2-50 alkyleneoxy units. Also described are urethane/urea prepolymers and polymers prepared therefrom.
摘要翻译： 本文描述的是修饰的多元体，其包含（a）包含至少一个聚亚烷基氧基部分和一个或多个内部尿素，酰胺，缩二脲，硫脲，二硫代比例或硫代酰胺部分的主链部分，（b）选自氨基， 羟基酰胺或羟基酯酰胺，其中至少一个端基是羟基酰胺或羟基酯酰胺，其中每个内部部分通过至少一个亚烷基，亚环烷基，亚芳基亚烷基，亚芳基或亚烷氧基部分彼此和每个末端基彼此分开， 4-20个碳原子，或至少一个含有2-50个亚烷氧基单元的聚亚烷基氧基部分。 还描述了由其制备的氨基甲酸酯/脲预聚物和聚合物。
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公开(公告)号：US5084528A
公开(公告)日：1992-01-28
申请号：US272593
申请日：1988-11-17
申请人： Robert F. Harris
发明人： Robert F. Harris
IPC分类号： C08G64/00
CPC分类号： C08G64/00
摘要： Ester-modified poly(alkylene carbonate) polyahls comprising the residues of at least one polyahl, polyalkyleneoxy moieties, poly(alkylene carbonate) moieties, the residues of at least one ester of a carboxylic acid, and a plurality of active hydrogen end group are disclosed. The ester-modified poly(alkylene carbonate) polyahl has a number average molecular weight higher than the number average molecular weight of any known poly(alkylene carbonate) polyahl comprising the same monomeric components. Also disclosed are isocyanate-functional prepolymers of these ester-modified poly(alkylene carbonate) polyahls formed by reactions of the ester-modified poly(alkylene carbonate) polyahls of this invention with excess organic polyisocyanates. Urethane/urea polymers formed by the reactions of the isocyanate-functional prepolymers with polyahls are also disclosed. Also disclosed are urethane/urea polymers comprising the residue of at least one ester-modified poly(alkylene carbonate) polyahl of this invention, the residue of a polyisocyanate and the residue of at least one other polyahl selected from the group consisting of polyamines, polymercaptans and polyfunctional hydroxyl compounds. The novel compositions of this invention are useful in urethane/urea polymer applications such as foams, elastomers, plastics, adhesives, coatings and the like.
摘要翻译： 公开了包含至少一个多芳基，聚亚烷氧基部分，聚（碳酸亚烷基酯）部分，至少一个羧酸酯的残基和多个活性氢端基的残基的酯改性的聚（碳酸亚烷基酯）多元素 。 酯改性的聚（碳酸亚烷基酯）多元醇的数均分子量高于包含相同单体组分的任何已知的聚碳酸亚烷基酯多元素的数均分子量。 还公开了通过本发明的酯改性的聚（碳酸亚烷基酯）多元醇与过量的有机多异氰酸酯的反应形成的这些酯改性的聚（碳酸亚烷基酯）多元素的异氰酸酯官能的预聚物。 还公开了通过异氰酸酯官能的预聚物与聚乙烯的反应形成的聚氨酯/尿素聚合物。 还公开了包含本发明的至少一种酯改性的聚（碳酸亚烷基酯）多元醇的残基的聚氨酯/脲聚合物，多异氰酸酯的残基和至少一种选自多胺，聚硫醇 和多官能羟基化合物。 本发明的新型组合物可用于聚氨酯/脲聚合物应用如泡沫，弹性体，塑料，粘合剂，涂料等。
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8.发明授权Amino-functional polyethers containing urea, biuret, thiourea, dithiobiuret, thioamide, and/or amide moieties in their backbone and urethane/urea prepolymers and polymers made therefrom 失效在其主链中含有尿素，缩二脲，硫脲，二硫代尿苷，硫代酰胺和/或酰胺部分的氨基官能聚醚和由其制备的氨基甲酸酯/脲预聚物和聚合物
公开(公告)号：US4916201A
公开(公告)日：1990-04-10
申请号：US247460
申请日：1988-09-21
CPC分类号： C08G18/5024 , C08G18/5036 , C08G18/5072 , C08G71/02 , C08G2120/00
摘要： This invention relates to novel polymeric polyamines containing internal urea, biuret, thiourea, dithiobiuret, and/or thioamide moieties, and to polymers prepared therefrom. This invention also relates to novel isocyanate-functional prepolymers containing urea, biuret, amide, thiourea, dithiobiuret, and/or thioamide moieties and to polymers prepared therefrom.
摘要翻译： 本发明涉及含有内部尿素，缩二脲，硫脲，二硫代尿苷和/或硫代酰胺部分的新型聚合多胺，以及由其制备的聚合物。 本发明还涉及含有尿素，缩二脲，酰胺，硫脲，二硫代尿素和/或硫代酰胺部分的新型异氰酸酯官能预聚物和由其制备的聚合物。
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9.发明授权Poly (alkylene carbonate) polyahls having on the average up to one acid-terminal moiety and salts thereof 失效具有平均至多一个酸末端部分的聚（碳酸亚烷基酯）多聚体及其盐
公开(公告)号：US4870127A
公开(公告)日：1989-09-26
申请号：US156105
申请日：1988-02-16
申请人： Robert F. Harris
发明人： Robert F. Harris
CPC分类号： C08G64/34 , C08F8/44 , Y10S516/01 , Y10S516/03 , Y10S516/04 , Y10S516/06
摘要： Novel acid-functional poly(alkylene carbonate) polyahls and their salts having surfactant activities are disclosed. These polyahls have, on the average, at least about 0.05 and up to about and including one hydrophilic terminus per molecule and can be produced by the reaction of a random non-ionic poly(alkylene carbonate) polyahl obtained by reacting a monofunctional alcohol, mercaptan, carboxylic acid, primary or secondary amine, alkyl substituted phenol or alkoxylates thereof with an alkylene carbonate and/or an alkylene oxide and/or carbon dioxide and/or a poly(alkylene carbonate) polyahl, and admixing a compound capable of adding an acidic end group thereto. Novel anionic poly(alkylene carbonate) polyahls are also disclosed. Surfactant compositions comprising the acid-functional polyahls of the invention and other non-ionic surfactants are also disclosed. Moreover, surfactant compositions comprising the novel acid-functional polyahls and other anionic surfactants are also disclosed.
摘要翻译： 公开了具有表面活性活性的新型酸官能聚（碳酸亚烷基酯）多烯及其盐。 平均来说，这些多聚乙烯平均每分子具有至少约0.05个至多约一个亲水性末端并且包含一个亲水性末端，并且可以通过使单官能醇，硫醇反应获得的随机非离子聚（碳酸亚烷基酯）多元醇 ，羧酸，伯或仲胺，烷基取代的苯酚或其烷氧基化物与碳酸亚烷基酯和/或烯化氧和/或二氧化碳和/或聚（碳酸亚烷基酯）多元醇，并且混合能够加入酸性 端组。 还公开了新的阴离子聚（碳酸亚烷基酯）多元素。 还公开了包含本发明的酸官能多聚体和其它非离子表面活性剂的表面活性剂组合物。 此外，还公开了包含新的酸官能聚乙烯和其它阴离子表面活性剂的表面活性剂组合物。
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10.发明授权Addition polymerizable polyethers having pendant ethylenically unsaturated urethane groups 失效具有侧链烯属不饱和氨基甲酸酯基团的加成聚合聚醚
公开(公告)号：US4287323A
公开(公告)日：1981-09-01
申请号：US1125
申请日：1979-01-05
IPC分类号： C08F299/02 , C08G18/63 , C08G18/81 , C08G65/333 , C09D171/02 , C08L75/08
CPC分类号： C08F299/024 , C08G18/635 , C08G18/81 , C08G18/8116 , C08G65/33396 , C09D171/02 , Y10S525/912 , Y10S525/925
摘要： Addition polymerizable polyethers having pendant ethylenically unsaturated urethane groups are usefully employed as flooring materials and in other applications utilizing radiation curable or chemically curable materials. Such urethane polyethers are advantageously prepared by reacting a polyether polyol such as a hydroxy terminated polypropylene glycol with an isocyanatoalkyl ester of an ethylenically unsaturated acid such as 2-isocyanatoethyl methacrylate.
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