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公开(公告)号：US4798877A
公开(公告)日：1989-01-17
申请号：US720769
申请日：1985-04-08
IPC分类号： C08F299/02 , C08G59/14 , C08F283/10
CPC分类号： C08F299/026 , C08G59/1433
摘要： Novel radiation-curable, water-compatible, resinous compositions result from (1) terminally unsaturated molecules which are the esters of an epoxy compound and (2) the reaction product of a glycidyl ether and an unsaturated acid having at least one glycidyl group per molecule converted to an onium salt of a quaternary ammonium or amine salt, with the anion of an inorganic or organic acid.
摘要翻译： 新的可辐射固化的水溶性树脂组合物来自（1）作为环氧化合物的酯的末端不饱和分子和（2）每分子具有至少一个缩水甘油基的缩水甘油醚和不饱和酸的反应产物 转化为季铵盐或胺盐的鎓盐与无机或有机酸的阴离子。
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2.发明授权Stable dispersions of polymers in polyfunctional compounds having a plurality of active hydrogens and polyurethanes produced therefrom 失效聚合物在具有多种活性氢的多官能化合物和由其制备的聚氨酯中的稳定分散体
公开(公告)号：US4460715A
公开(公告)日：1984-07-17
申请号：US320160
申请日：1981-11-10
IPC分类号： C08F283/06 , C08F291/08 , C08G18/40 , C08G18/63 , C08G18/81 , C08G18/14 , C08G18/30
CPC分类号： C08F291/08 , C08F283/06 , C08G18/40 , C08G18/63 , C08G18/81
摘要： A stable copolymer dispersion is prepared by addition copolymerization of (1) a monomeric adduct of an active hydrogen compound, e.g., a polyether polyol, and an acrylyl compound such as methacryloyl chloride with (2) ethylenically unsaturated monomer(s), e.g., styrene or a mixture thereof with acrylonitrile, while (1) and (2) are dispersed or dissolved in an excess of an active hydrogen polyfunctional compound such as a polyether polyol. The molar ratio of acrylyl moiety to active hydrogen compound is less than 0.1:1. The resulting dispersion has a controlled particle size and a viscosity such that it is suitably employed in the production of polyurethane foams.
摘要翻译： 通过（1）活性氢化合物例如聚醚多元醇和丙烯酰基化合物如甲基丙烯酰氯与（2）烯键式不饱和单体的单体加合物（例如苯乙烯）的加成共聚制备稳定的共聚物分散体 或其与丙烯腈的混合物，而（1）和（2）分散或溶解在过量的活性氢多官能化合物如聚醚多元醇中。 丙烯酰部分与活性氢化合物的摩尔比小于0.1：1。 所得到的分散体具有受控的粒度和粘度，使得它适合用于生产聚氨酯泡沫体。
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3.发明授权Process for the preparation of radiation-curable, water-thinnable vinyl ester resins 失效用于制备可辐射固化的，可水解的乙烯基酯树脂的方法
公开(公告)号：US4431782A
公开(公告)日：1984-02-14
申请号：US456225
申请日：1983-01-07
IPC分类号： C08G59/14 , C08G59/66 , C09D163/10 , C08F283/00
CPC分类号： C08G59/66 , C08G59/1433 , C08G59/1483 , C09D163/10 , Y10S525/922
摘要： Sulfonium-stabilized, water-compatible, radiation-curable vinyl ester resins are prepared by the process of reacting an epoxy resin having on the average at least one vicinal epoxy group with a mercaptan and with an unsaturated monocarboxylic acid to form vinyl ester resins containing sulfide moieties which are then reacted with a protonic acid and an alkylene oxide.Compounds so prepared can be diluted with water and used as coatings.
摘要翻译： 通过使具有平均至少一个邻位环氧基的环氧树脂与硫醇和不饱和一元羧酸反应形成含硫化物的乙烯基酯树脂的方法制备锍稳定的水溶性的可辐射固化的乙烯基酯树脂 然后其与质子酸和烯化氧反应。 如此制备的化合物可以用水稀释并用作涂层。
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公开(公告)号：US4338232A
公开(公告)日：1982-07-06
申请号：US137706
申请日：1980-04-07
CPC分类号： C08G59/1433 , Y10S522/904 , Y10S525/922
摘要： Novel sulfonium-stabilized, radiation-curable, water-compatible, water-in-oil emulsions and a method of preparation are described. As an example, one such emulsion was prepared by reacting the diglycidyl ether of a polypropylene glycol with essentially a stoichiometric equivalent of acrylic acid, about 0.3 equivalent of bis(2-hydroxyethyl)-sulfide and 1.5 equivalents of H.sub.2 O.
摘要翻译： 描述了新的锍稳定的，可辐射固化的，水相容的油包水乳液和制备方法。 作为实例，通过使聚丙二醇的二缩水甘油醚与基本上化学计量当量的丙烯酸，约0.3当量的双（2-羟乙基） - 硫化物和1.5当量的H 2 O反应来制备一种这样的乳液。
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5.发明授权Stable dispersions of polymers in polyfunctional compounds having a plurality of active hydrogens and polyurethanes therefrom 失效聚合物在具有多个活性氢的多官能化合物中的稳定分散体和聚氨酯
公开(公告)号：US4390645A
公开(公告)日：1983-06-28
申请号：US97070
申请日：1979-11-23
IPC分类号： C08G18/00 , C08F291/08 , C08F299/06 , C08G18/40 , C08G18/63 , C08G18/67 , C08G18/72 , C08G18/81 , C08G18/14
CPC分类号： C08F291/08 , C08F299/06 , C08G18/40 , C08G18/635 , C08G18/728 , C08G18/8108
摘要： A stable copolymer dispersion is prepared by addition copolymerization of (1) an adduct of an active hydrogen compound, e.g., a polyether polyol, and an active ethylenically unsaturated isocyanate, e. g., 2-isocyanatoethyl methacrylate with (2) ethylenically unsaturated monomers(s), e.g., styrene or mixture thereof with acrylonitrile, while (1) and (2) are dispersed or dissolved in an excess of an active hydrogen polyfunctional compound. The resulting dispersion has a controlled particle size and a viscosity such that it is suitably employed in the production of polyurethane foams.
摘要翻译： 通过（1）活性氢化合物例如聚醚多元醇和活性烯键式不饱和异氰酸酯的加合物的加成共聚制备稳定的共聚物分散体， （2）烯键式不饱和单体，例如苯乙烯或其与丙烯腈的混合物，而（1）和（2）分散或溶解在过量的活性氢多官能化合物中。 所得到的分散体具有受控的粒度和粘度，使得它适合用于生产聚氨酯泡沫体。
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公开(公告)号：US5461106A
公开(公告)日：1995-10-24
申请号：US353850
申请日：1994-12-12
IPC分类号： C08F220/06 , C08F222/02
CPC分类号： C08F220/06
摘要： A solid polymeric latent initiator which is a dehydrated aqueous emulsion polymer of a monomer having an ethylenically unsaturated group and an organic salt group, the salt group being a product of an acid and a base, wherein either the acid or the base or the acid and the base are initiators capable of opening a strained heterocyclic ring system, provides rapid cure-on-demand one-part adhesives with improved shelf stability.
摘要翻译： 一种固体聚合物潜在引发剂，其是具有烯键式不饱和基团和有机盐基团的单体的脱水水性乳液聚合物，该盐基团是酸和碱的产物，其中酸或碱或酸和/ 碱是能够打开应变杂环系统的引发剂，提供快速的按需单组分粘合剂，具有改进的储存稳定性。
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7.发明授权Addition polymerizable adduct of a polymeric monoahl and an unsaturated isocyanate 失效聚合单烯烃和不饱和异氰酸酯的加成聚合加合物
公开(公告)号：US4394491A
公开(公告)日：1983-07-19
申请号：US195155
申请日：1980-10-08
申请人： Dwight K. Hoffman
发明人： Dwight K. Hoffman
CPC分类号： C08F283/06 , C08G18/283 , C08G18/635 , C08G18/8108 , Y10S525/92
摘要： An adduct of a monoahl, e.g., a monohydroxyl polyalkylene oxide, and an active ethylenically unsaturated isocyanate, e.g., 2-isocyanatoethyl methacrylate, is usefully employed in the preparation of stable copolymer dispersions of the type used in the production of polyurethane foams and polyurethane elastomers.The copolymer dispersion is prepared by addition copolymerization of (1) the adduct with (2) ethylenically unsaturated monomer(s), e.g., styrene or mixture thereof with acrylonitrile, while (1) and (2) are dispersed or dissolved in an excess of an active hydrogen polyfunctional compound.
摘要翻译： 单醛，例如单羟基聚环氧烷和活性烯键式不饱和异氰酸酯，例如甲基丙烯酸2-异氰酸酯基乙酯的加合物可用于制备用于生产聚氨酯泡沫和聚氨酯弹性体的类型的稳定的共聚物分散体 。 通过（1）加合物与（2）烯属不饱和单体（例如苯乙烯或其混合物）与丙烯腈的加成共聚合制备共聚物分散体，而（1）和（2）分散或溶解在过量的 一种活性氢多官能化合物。
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公开(公告)号：US5055532A
公开(公告)日：1991-10-08
申请号：US69997
申请日：1987-07-06
IPC分类号： C08F299/02
CPC分类号： C08F299/026
摘要： Vinylized epoxy resins, such as vinyl ester resins, comprise polymerizable ethylenic unsaturation and an in situ polymerized polymer, such as a polyalkyl acrylate. The vinylized epoxy resins can form stable dispersions and are useful in thermoset applications.
摘要翻译： 乙烯基酯树脂等乙烯基化环氧树脂包括可聚合的烯属不饱和基团和原位聚合的聚合物，如聚丙烯酸烷基酯。 乙烯基化环氧树脂可以形成稳定的分散体，并且可用于热固性应用。
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公开(公告)号：US4789712A
公开(公告)日：1988-12-06
申请号：US83135
申请日：1987-08-10
IPC分类号： C08F283/10 , C08F299/02 , C08L63/10
CPC分类号： C08F299/026 , C08F283/10 , Y10S525/922
摘要： Dispersions of polymers and optional dispersion stabilizers in a polyepoxide resin continuous phase is characterized in that the dispersion remains stable above 60.degree. C. The compositions are curable and are useful as coatings, in preparing laminates and reinforced plastics, and as adhesives. The compositions exhibit properties which are superior to compositions containing reactive liquid polymers.
摘要翻译： 聚合物和任选的分散体稳定剂在聚环氧化物树脂连续相中的分散体的特征在于，分散体在60℃以上保持稳定。组合物是可固化的，并且可用作制备层压板和增强塑料以及作为粘合剂的涂料。 该组合物显示出优于含有反应性液体聚合物的组合物的性能。
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公开(公告)号：US4431754A
公开(公告)日：1984-02-14
申请号：US353709
申请日：1982-03-01
申请人： Dwight K. Hoffman
发明人： Dwight K. Hoffman
IPC分类号： C08F283/00 , C08G18/63 , C08G18/14
CPC分类号： C08G18/635 , C08F283/00 , C08G18/63 , C08G2105/02
摘要： A low viscosity copolymer polyahl dispersion is prepared by polymerizing polymer particles in a polyahl medium, to a first solids concentration and thereafter diluting the dispersion to a second lower solids concentration. The resulting diluted dispersion has a lower viscosity than if the dispersion were prepared directly at the lower solids level. The invention has particular advantage when used with "all acrylonitrile" dispersions. The copolymer polyahl dispersions are useful in the manufacture of urethane and isocyanurate foams.
摘要翻译： 通过将多聚烯烃介质中的聚合物颗粒聚合至第一固体浓度，然后将分散体稀释至第二较低固体浓度来制备低粘度共聚物聚烯烃分散体。 所得到的稀释分散体的粘度低于直接在较低固体含量下制备分散体的粘度。 当与“所有丙烯腈”分散体一起使用时，本发明具有特别的优点。 共聚物聚乙烯分散体可用于制备聚氨酯和异氰脲酸酯泡沫。
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