公开(公告)号：US20190241496A1

公开(公告)日：2019-08-08

申请号：US16389424

申请日：2019-04-19

申请人： ECOLAB USA, INC.

发明人： David Youdong Tong

IPC分类号： C07C67/62 ,  C07C7/20 ,  C07C51/50 ,  C07D211/94 ,  C07C45/86 ,  C07C231/22 ,  C07C253/32

摘要： Polymerization inhibitor compositions are provided. The polymerization inhibitor compositions may include at least one hydroxylamine of a nitroxide and at least one phenylenediamine. Methods of inhibiting the unwanted polymerization of monomers are also provided. The methods include adding the presently disclosed polymerization inhibitor compositions to a fluid containing the monomers. The monomers may be ethylenically unsaturated monomers, such as acrylic acid, methacrylic acid, acrylonitrile, methacrylonitrile, acrolein, methacrolein, acrylate, methacrylate, acrylamide, methacrylamide, vinyl acetate, butadiene, ethylene, propylene, and styrene.

公开(公告)号：US10308585B2

公开(公告)日：2019-06-04

申请号：US16143956

申请日：2018-09-27

申请人： ECOLAB USA, INC.

发明人： David Youdong Tong

IPC分类号： C07D211/00 ,  C07D211/30 ,  C07C67/62 ,  C07D211/94 ,  C07C7/20 ,  C07C231/22 ,  C07C45/86 ,  C07C253/32 ,  C07C51/50

摘要： Polymerization inhibitor compositions are provided. The polymerization inhibitor compositions may include at least one hydroxylamine of a nitroxide and at least one phenylenediamine. Methods of inhibiting the unwanted polymerization of monomers are also provided. The methods include adding the presently disclosed polymerization inhibitor compositions to a fluid containing the monomers. The monomers may be ethylenically unsaturated monomers, such as acrylic acid, methacrylic acid, acrylonitrile, methacrylonitrile, acrolein, methacrolein, acrylate, methacrylate, acrylamide, methacrylamide, vinyl acetate, butadiene, ethylene, propylene, and styrene.

公开(公告)号：US20190023642A1

公开(公告)日：2019-01-24

申请号：US16143956

申请日：2018-09-27

申请人： ECOLAB USA, INC.

发明人： David Youdong Tong

IPC分类号： C07C67/62 ,  C07D211/94 ,  C07C231/22 ,  C07C7/20 ,  C07C45/86 ,  C07C253/32 ,  C07C51/50 ,  C07C69/54 ,  C07C57/04 ,  C07C69/15 ,  C07C11/167 ,  C07C11/04 ,  C07C11/06 ,  C07C15/46 ,  C07C47/22 ,  C07C233/09 ,  C07C255/08

摘要： Polymerization inhibitor compositions are provided. The polymerization inhibitor compositions may include at least one hydroxylamine of a nitroxide and at least one phenylenediamine. Methods of inhibiting the unwanted polymerization of monomers are also provided. The methods include adding the presently disclosed polymerization inhibitor compositions to a fluid containing the monomers. The monomers may be ethylenically unsaturated monomers, such as acrylic acid, methacrylic acid, acrylonitrile, methacrylonitrile, acrolein, methacrolein, acrylate, methacrylate, acrylamide, methacrylamide, vinyl acetate, butadiene, ethylene, propylene, and styrene.

公开(公告)号：US10112888B2

公开(公告)日：2018-10-30

申请号：US15147472

申请日：2016-05-05

申请人： ECOLAB USA, INC.

发明人： David Youdong Tong

IPC分类号： C07D211/00 ,  C07D211/30 ,  C07C67/62 ,  C07D211/94 ,  C07C7/20 ,  C07C231/22 ,  C07C45/86 ,  C07C253/32 ,  C07C51/50

摘要： Polymerization inhibitor compositions are provided. The polymerization inhibitor compositions may include at least one hydroxylamine of a nitroxide and at least one phenylenediamine. Methods of inhibiting the unwanted polymerization of monomers are also provided. The methods include adding the presently disclosed polymerization inhibitor compositions to a fluid containing the monomers. The monomers may be ethylenically unsaturated monomers, such as acrylic acid, methacrylic acid, acrylonitrile, methacrylonitrile, acrolein, methacrolein, acrylate, methacrylate, acrylamide, methacrylamide, vinyl acetate, butadiene, ethylene, propylene, and styrene.

公开(公告)号：US09399622B2

公开(公告)日：2016-07-26

申请号：US14095606

申请日：2013-12-03

申请人： Ecolab USA, Inc.

发明人： David Youdong Tong

IPC分类号： C07D211/00 ,  C07D211/30 ,  C07D211/94 ,  C07C67/62

CPC分类号： C07C67/62 ,  C07C7/20 ,  C07C45/86 ,  C07C51/50 ,  C07C231/22 ,  C07C253/32 ,  C07D211/94 ,  C07C69/54 ,  C07C57/04 ,  C07C69/15 ,  C07C11/167 ,  C07C11/04 ,  C07C11/06 ,  C07C15/46 ,  C07C47/22 ,  C07C233/09 ,  C07C255/08

摘要： Polymerization inhibitor compositions are provided. The polymerization inhibitor compositions may include at least one hydroxylamine of a nitroxide and at least one phenylenediamine. Methods of inhibiting the unwanted polymerization of monomers are also provided. The methods include adding the presently disclosed polymerization inhibitor compositions to a fluid containing the monomers. The monomers may be ethylenically unsaturated monomers, such as acrylic acid, methacrylic acid, acrylonitrile, methacrylonitrile, acrolein, methacrolein, acrylate, methacrylate, acrylamide, methacrylamide, vinyl acetate, butadiene, ethylene, propylene, and styrene.

摘要翻译： 提供聚合抑制剂组合物。 聚合抑制剂组合物可包括至少一种氮氧化物的羟胺和至少一种苯二胺。 还提供了抑制单体不期望的聚合的方法。 所述方法包括将目前公开的阻聚剂组合物添加到含有单体的流体中。 单体可以是烯属不饱和单体，例如丙烯酸，甲基丙烯酸，丙烯腈，甲基丙烯腈，丙烯醛，异丁烯醛，丙烯酸酯，甲基丙烯酸酯，丙烯酰胺，甲基丙烯酰胺，乙酸乙烯酯，丁二烯，乙烯，丙烯和苯乙烯。

公开(公告)号：US10370331B2

公开(公告)日：2019-08-06

申请号：US15915201

申请日：2018-03-08

申请人： Ecolab USA Inc.

发明人： Jonathan Masere ,  Javier Florencio ,  Ramon Colorado, Jr. ,  Andrew R. Neilson ,  David Youdong Tong

IPC分类号： C07C7/20 ,  C07D211/94 ,  C07C231/22 ,  C07C67/62 ,  C07C51/50 ,  C08F2/40

摘要： Disclosed herein are compositions including between 20 wt % and 50 wt % of a nitroxyl compound such as 2,2,6,6-tetramethylpiperidinyl-1-oxyl. The compositions are stable under field conditions of transportation and storage. The compositions remain homogeneous and pumpable or pourable at temperatures between −20° C. and 60° C., even when temperatures fluctuate in this range over a period of 10 days to 5 years, and even where the container used to transport and store the composition is made from metal or includes a metal surface contacting the composition.

公开(公告)号：US20180258014A1

公开(公告)日：2018-09-13

申请号：US15915201

申请日：2018-03-08

申请人： Ecolab USA Inc.

发明人： Jonathan Masere ,  Javier Florencio ,  Ramon Colorado, JR. ,  Andrew R. Neilson ,  David Youdong Tong

IPC分类号： C07C7/20 ,  C07C51/50 ,  C07C67/62 ,  C07C231/22

CPC分类号： C07D211/94 ,  C07C7/20 ,  C07C51/50 ,  C07C67/62 ,  C07C231/22 ,  C08F2/40

摘要： Disclosed herein are compositions including between 20 wt % and 50 wt % of a nitroxyl compound such as 2,2,6,6-tetramethylpiperidinyl-1-oxyl. The compositions are stable under field conditions of transportation and storage. The compositions remain homogeneous and pumpable or pourable at temperatures between −20° C. and 60° C., even when temperatures fluctuate in this range over a period of 10 days to 5 years, and even where the container used to transport and store the composition is made from metal or includes a metal surface contacting the composition.

公开(公告)号：US10696618B2

公开(公告)日：2020-06-30

申请号：US16389424

申请日：2019-04-19

申请人： ECOLAB USA, INC.

发明人： David Youdong Tong

IPC分类号： C07C67/62 ,  C07D211/94 ,  C07C231/22 ,  C07C45/86 ,  C07C253/32 ,  C07C51/50 ,  C07C7/20

摘要： Polymerization inhibitor compositions are provided. The polymerization inhibitor compositions may include at least one hydroxylamine of a nitroxide and at least one phenylenediamine. Methods of inhibiting the unwanted polymerization of monomers are also provided. The methods include adding the presently disclosed polymerization inhibitor compositions to a fluid containing the monomers. The monomers may be ethylenically unsaturated monomers, such as acrylic acid, methacrylic acid, acrylonitrile, methacrylonitrile, acrolein, methacrolein, acrylate, methacrylate, acrylamide, methacrylamide, vinyl acetate, butadiene, ethylene, propylene, and styrene.

公开(公告)号：US09884951B2

公开(公告)日：2018-02-06

申请号：US14881880

申请日：2015-10-13

申请人： Ecolab USA Inc.

发明人： David Youdong Tong

IPC分类号： C08K5/12 ,  C08F2/00

CPC分类号： C08K5/12 ,  C08F2/005

摘要： The present invention generally relates to a method for reducing polymer agglomeration or fouling, and its use in processes for the preparation of an acrylate, methacrylic acid, or a methacrylate. According to the present invention, the reagent comprises an alkyl phthalate, an alkaryl phthalate, an aryl phthalate, or a phthalic acid, and applying the reagent to processes for the preparation of an acrylate, methacrylic acid, or a methacrylate to prevent polymeric foulant precursors from agglomerating or to dissolve existing polymeric agglomerates or foulants so as to reduce polymer agglomeration or fouling in the process or storage equipment.

公开(公告)号：US20160244398A1

公开(公告)日：2016-08-25

申请号：US15147472

申请日：2016-05-05

申请人： ECOLAB USA, INC.

发明人： David Youdong Tong

IPC分类号： C07C67/62 ,  C07C7/20

CPC分类号： C07C67/62 ,  C07C7/20 ,  C07C45/86 ,  C07C51/50 ,  C07C231/22 ,  C07C253/32 ,  C07D211/94 ,  C07C69/54 ,  C07C57/04 ,  C07C69/15 ,  C07C11/167 ,  C07C11/04 ,  C07C11/06 ,  C07C15/46 ,  C07C47/22 ,  C07C233/09 ,  C07C255/08

摘要： Polymerization inhibitor compositions are provided. The polymerization inhibitor compositions may include at least one hydroxylamine of a nitroxide and at least one phenylenediamine. Methods of inhibiting the unwanted polymerization of monomers are also provided. The methods include adding the presently disclosed polymerization inhibitor compositions to a fluid containing the monomers. The monomers may be ethylenically unsaturated monomers, such as acrylic acid, methacrylic acid, acrylonitrile, methacrylonitrile, acrolein, methacrolein, acrylate, methacrylate, acrylamide, methacrylamide, vinyl acetate, butadiene, ethylene, propylene, and styrene.