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公开(公告)号：US20210108141A1
公开(公告)日：2021-04-15
申请号：US17067164
申请日：2020-10-09
Applicant: Ecolab USA Inc.
Inventor： Jonathan Masere
Abstract: Described are compositions and methods for inhibiting polymerization of a monomer (e.g., styrene) composition a quinone methide polymerization retarder and an ammonium salt. In a mixture, the ammonium salt improves the efficacy of the quinone methide polymerization retarder and provides greater antipolymerant activity. In turn, the mixture reduces or prevents apparatus fouling and improves the purity of monomer streams.
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公开(公告)号：US10155705B2
公开(公告)日：2018-12-18
申请号：US15132844
申请日：2016-04-19
Applicant: Ecolab USA Inc.
Inventor： Jonathan Masere , Ramon Colorado, Jr.
IPC: C07C7/20
Abstract: The present invention generally relates to compounds and methods for preventing fouling caused by the radical polymerization of unsaturated compounds, particularly vinyl monomers. More particularly, it relates to the use of hindered hydroquinones to inhibit the polymerization, which result in the fouling of process equipment, and prematurely consume the vinylic monomer products.
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公开(公告)号：US20190202962A1
公开(公告)日：2019-07-04
申请号：US16228260
申请日：2018-12-20
Applicant: Ecolab USA Inc.
Inventor： Michael L. Braden , Ashish Dhawan , Jonathan Masere
Abstract: The present disclosure generally relates to nonylphenol-free alkoxylated 4-(alkyloxy)phenol/aldehyde resins and processes for making alkoxylated 4-(alkyloxy)phenol/aldehyde resins. The disclosure also relates to methods of breaking emulsions of oil and water comprising the dosing of an effective amount of an emulsion breaker composition into a stable emulsion to destabilize the emulsion, wherein the emulsion breaker composition comprises an alkoxylated 4-(alkyloxy)phenol/aldehyde resin.
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公开(公告)号：US20160289147A1
公开(公告)日：2016-10-06
申请号：US15085523
申请日：2016-03-30
Applicant: Ecolab USA Inc.
Inventor： Jonathan Masere , Ramon Colorado, JR.
IPC: C07C7/20
Abstract: The present invention generally relates to compounds and methods for inhibiting the radical polymerization of unsaturated compounds, particularly vinyl monomers. More particularly, it relates to the use of cinnamyl quinone methides to inhibit the polymerization of unsaturated hydrocarbon compounds (e.g., vinyl monomers) soluble in organic solvents, particularly hydrocarbon streams.
Abstract translation: 本发明一般涉及抑制不饱和化合物，特别是乙烯基单体的自由基聚合的化合物和方法。 更具体地说，本发明涉及肉桂基醌甲基化物抑制可溶于有机溶剂，特别是烃流中的不饱和烃化合物（例如乙烯基单体）聚合的用途。
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5.发明申请USE OF STABLE LIPOPHILIC HYDROXYLAMINE COMPOUNDS FOR INHIBITING POLYMERIZATION OF VINYL MONOMERS 有权使用稳定的二氯羟胺化合物抑制乙烯基单体的聚合公开(公告)号：US20160272586A1
公开(公告)日：2016-09-22
申请号：US15072780
申请日：2016-03-17
Applicant: Ecolab USA Inc.
Inventor： Jonathan Masere , Andrew R. Neilson , Russell P. Watson
IPC: C07D211/94 , C07C7/20
CPC classification number: C07D211/94 , C07C7/20 , C07C67/62 , C07C11/167 , C07C15/46 , C07C69/54 , C07C11/18
Abstract: The present invention generally relates to compounds and methods for inhibiting the radical polymerization of unsaturated compounds, particularly vinyl monomers. More particularly, it relates to the use of stable hydroxyl amines to inhibit the polymerization of unsaturated compounds (e.g., vinyl monomers) wherein said stable hydroxylamine is soluble in organic solvents, particularly hydrocarbon solvents consisting of unsaturated and, therefore, polymerizable constituents.
Abstract translation: 本发明一般涉及抑制不饱和化合物，特别是乙烯基单体的自由基聚合的化合物和方法。 更具体地说，本发明涉及使用稳定的羟基胺来抑制不饱和化合物（例如乙烯基单体）的聚合，其中所述稳定的羟胺可溶于有机溶剂，特别是由不饱和烃和因此可聚合成分组成的烃溶剂。
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Patent Agency Ranking
公开(公告)号：US11104626B2
公开(公告)日：2021-08-31
申请号：US16721297
申请日：2019-12-19
Applicant: Ecolab USA Inc.
Inventor： Jonathan Masere , Russell P. Watson , Ashish Dhawan
Abstract: Described are methods and compositions for inhibiting polymerization of a monomer (e.g., styrene) composition using a hydroxylated quinone antipolymerant. The hydroxylated quinone antipolymerant can be used with little or no nitroxyl group containing antipolymerant yet still provide excellent antipolymerant activity in a monomer-containing composition.
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公开(公告)号：US20200339880A1
公开(公告)日：2020-10-29
申请号：US16860954
申请日：2020-04-28
Applicant: Ecolab USA Inc.
Inventor： Jonathan Masere , Ashish Dhawan
IPC: C09K15/24 , C08F2/40 , C07C215/76
Abstract: Described are compounds, compositions, and methods that include a nitrogen- and oxygen-containing aromatic compound, such as an aminophenol-based compound, which can be used for inhibiting polymerization of a monomer (e.g., styrene) composition. The compound includes a tertiary amine group wherein the nitrogen is attached to carbon-containing groups, and at least one of oxygen atom separated from the nitrogen by one or more carbon atoms. The antipolymerant can provide excellent antipolymerant activity in a monomer-containing composition.
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公开(公告)号：US20200017610A1
公开(公告)日：2020-01-16
申请号：US16510053
申请日：2019-07-12
Applicant: Ecolab USA Inc.
Inventor： Jonathan Masere , Andrew R. Neilson , Bassam Alnasleh , Ramon Colorado, JR.
IPC: C08F2/40 , C08K5/08 , C08K5/00 , C08K5/17 , C08K5/3435 , C08F12/30 , C08F20/06 , C08F20/18 , C08F20/44 , C08F12/36 , C08F26/06
Abstract: Described are compositions and methods for inhibiting polymerization of a monomer (e.g., styrene) composition, which use an N—O polymerization inhibitor, a quinone methide polymerization retarder, and an amine stabilizer having a primary and/or secondary amine group. In a mixture, the amine-based stabilizer can prevent antagonistic effects and can provide greater antipolymerant activity. In turn, the mixture inhibits apparatus fouling and improves the purity of monomer streams.
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9.发明公开公开(公告)号：US20240141131A1
公开(公告)日：2024-05-02
申请号：US18379592
申请日：2023-10-12
Applicant: Ecolab USA Inc.
Inventor： Jonathan Masere , Ashish Dhawan , Carter M. Silvernail , Pedro Carvalho Campos
CPC classification number: C08J11/22 , C08J11/28 , C08J2379/02
Abstract: Described are compositions and methods for inhibiting and retarding polymerization of a monomer composition, which use a naphthoquinone and a hydroxylamine. When present in a monomer-containing composition, the combination of the naphthoquinone and hydroxylamine provides an unexpected beneficial antipolymerant effect inhibiting unwanted formation of fouling polymer. The antipolymerant combination can be added to a hydrocarbon composition, such as a petroleum, that can include a polymerizable components, such as styrene, where the hydrocarbon composition is purified or processed, such as in the case of distillation.
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公开(公告)号：US11312793B2
公开(公告)日：2022-04-26
申请号：US16580653
申请日：2019-09-24
Applicant: Ecolab USA Inc.
Inventor： Jonathan Masere
Abstract: Described are methods and composition for inhibiting polymerization of a monomer (e.g., styrene) composition using an aminated quinone antipolymerant, such as an aminated benzoquinone or aminated naphthoquinone antipolymerant having one or more secondary or tertiary amine group(s). The aminated quinone antipolymerant can be used with little or no nitroxyl group containing antipolymerant yet still provide excellent antipolymerant activity in a monomer-containing composition.
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