公开(公告)号：US20210040110A1

公开(公告)日：2021-02-11

申请号：US16989030

申请日：2020-08-10

申请人： Eni S.p.A.

发明人： Riccardo PO ,  Gabriele BIANCHI

IPC分类号： C07D495/04 ,  H01L51/00 ,  C08G61/12

摘要： Polymer comprising an indacen-4-one derivative, said polymer having general formula (IX), (X) or (XI): in which: W and W1, Z and Y, R1 and R2, are as described; D represents an electron-donor group; A represents an electron-acceptor group; n is an integer ranging from 10 to 500.

公开(公告)号：US20240166896A1

公开(公告)日：2024-05-23

申请号：US18547282

申请日：2022-02-23

申请人： ENI S.P.A.

发明人： Giulio ASSANELLI ,  Marcello NOTARI ,  Antonio AMICO ,  Riccardo PO ,  Luca SERBOLISCA

IPC分类号： C09D7/80 ,  C09D5/14 ,  C09D7/61 ,  C09D7/65

CPC分类号： C09D7/80 ,  C09D5/14 ,  C09D7/61 ,  C09D7/65

摘要： A process for preparing an antimicrobial coating composition includes the following steps:



a. providing an aqueous dispersion having graphite, at least one oxidizing agent and optionally at least one antimicrobial agent;
b. subjecting the aqueous dispersion from step a to high shear homogenization mixing the dispersion at a mixing speed equal to or greater than 1000 rpm, to obtain an antibacterial aqueous dispersion having graphene oxide;
and c. mixing the aqueous antimicrobial dispersion with at least one film-forming agent to obtain the antimicrobial coating composition.




The composition obtainable by the above process and use thereof to impart antimicrobial properties to the surface of a substrate are also related.

公开(公告)号：US20230309371A1

公开(公告)日：2023-09-28

申请号：US18020201

申请日：2021-08-06

申请人： ENI S.P.A.

发明人： Riccardo PO ,  Gianni CORSO ,  Riccardo BARBIERI

IPC分类号： H10K85/10 ,  H10K85/20 ,  H10K30/50 ,  H10K30/81

CPC分类号： H10K85/151 ,  H10K85/1135 ,  H10K85/111 ,  H10K85/113 ,  H10K85/215 ,  H10K30/50 ,  H10K30/81

摘要： An inverted polymer photovoltaic cell (or solar cell) includes an anode; a first anodic interlayer (buffer layer) based on PEDOT:PSS [poly(3,4-ethylenedioxythiophene):polystyrene sulfonate]; an active layer having at least one photoactive organic polymer as an electron donor and at least one electron acceptor organic compound; a cathodic interlayer (buffer layer); and a cathode. A second anodic interlayer (buffer layer) includes at least one heteropolyacid and, optionally, at least one amino compound is placed between the first anodic interlayer (buffer layer) and the active layer.
The inverted polymer photovoltaic cell (or solar cell) shows good values of photoelectric conversion efficiency (power conversion efficiency—PCE) (η) and, in particular, a good level of adhesion between the different layers, more specifically between the active layer and the first anodic interlayer (buffer layer).

公开(公告)号：US20180244691A1

公开(公告)日：2018-08-30

申请号：US15573865

申请日：2016-05-16

申请人： Eni S.p.A.

发明人： Riccardo PO ,  Gabriele BIANCHI

IPC分类号： C07D495/04 ,  C08G61/12 ,  H01L51/00

CPC分类号： C07D495/04 ,  C08G61/124 ,  C08G61/126 ,  C08G2261/11 ,  C08G2261/122 ,  C08G2261/1412 ,  C08G2261/1424 ,  C08G2261/3223 ,  C08G2261/3243 ,  C08G2261/3246 ,  C08G2261/514 ,  C08G2261/91 ,  H01L51/0036 ,  H01L51/0047 ,  H01L51/4253 ,  Y02E10/549 ,  Y02P70/521

摘要： Indacen-4-one derivative having general formula (I) in which: —W and W1, which are the same or different, preferably the same, represent an oxygen atom; a sulfur atom; an N—R3 group in which R3 represents a hydrogen atom, or is selected from linear or branched C1-C20, preferably C2-C10, alkyl groups; —Z and Y, which are the same or different, preferably the same, represent a nitrogen atom; or a C—R4 group in which R4 represents a hydrogen atom, or is selected from linear or branched C1-C20, preferably C2-C10, alkyl groups, optionally substituted cycloalkyl groups, optionally substituted aryl groups, optionally substituted heteroaryl groups, linear or branched C1-C20, preferably C2-C10, alkoxyl groups, R5—O—[CH2—CH2—O]n— polyethyleneoxyl groups in which R5 is selected from linear or branched C1-C20, preferably C2-C10, alkyl groups, and n is an integer ranging from 1 to 4; —R6—OR7 groups in which R6 is selected from linear or branched C1-C20, preferably C2-C10, alkylene groups and R7 represents a hydrogen atom or is selected from linear or branched C1-C20, preferably C2-C10, alkyl groups, or is selected from R5—[—OCH2—CH2—]n— polyethyleneoxyl groups in which R5 has the same meanings as above reported and n is an integer ranging from 1 to 4, —COR8 groups in which R8 is selected from linear or branched C1-C20, preferably C2-C10, alkyl groups, —COOR9 groups in which R9 is selected from linear or branched C1-C20, preferably C2-C10, alkyl groups, or represent a —CHO group, or a cyano group (—CN); —R1 and R2, which are the same or different, preferably the same, are selected from linear or branched C1-C10, preferably C2-C10, alkyl groups, optionally substituted cycloalkyl groups, optionally substituted aryl groups, optionally substituted heteroaryl groups, linear or branched C1-C20, preferably C2-C10, alkoxyl groups, R5—O—[CH2—CH2—O]n— polyethyleneoxyl groups in which R5 has the same meanings as above reported and n is an integer ranging from 1 to 4, —R6—OR7 groups in which R6 and R7 have the same meanings as above reported, —COR8 groups in which R8 has the same meanings as above reported, —COOR9 groups in which R9 has the same meanings as above reported, or represent a —CHO group, or a cyano group (—CN). Said indacen-4-one derivative may advantageously be used in the synthesis of electron-donor polymers, said polymers being a further object of the present invention. Said polymers may advantageously be used in the construction of photovoltaic devices (or solar devices) such as, for example, photovoltaic cells (or solar cells), photovoltaic modules (or solar modules), on either a rigid or flexible support.