公开(公告)号：US10023681B2

公开(公告)日：2018-07-17

申请号：US13951958

申请日：2013-07-26

申请人： EVONIK DEGUSSA GMBH

发明人： Juan Jesus Burdeniuc ,  Jean Louise Vincent ,  Tadao Yasue ,  Timothy J. Miller ,  Renee Jo Keller

IPC分类号： C08G18/18 ,  C08G18/50 ,  C08G18/54 ,  C08J9/14 ,  C08G18/09 ,  C08G18/22 ,  C08G18/40 ,  C08J9/02 ,  C08G18/20 ,  C08G18/34 ,  C08G101/00

摘要： Catalyst compositions useful in the production of insulating polyurethane or polyisocyanurate foam are disclosed. The catalyst compositions impart increased stability of a mixture of the catalyst, a halogen-containing blowing agent, and a polyol. These catalyst compositions include amine/acid salts with a pH of

公开(公告)号：US10196476B2

公开(公告)日：2019-02-05

申请号：US14437070

申请日：2013-10-24

申请人： EVONIK DEGUSSA GMBH

发明人： Juan Jesus Burdeniuc ,  Jean Louise Vincent ,  Timothy J. Miller

IPC分类号： C08G18/18 ,  C08G18/50 ,  C08G18/54 ,  C08J9/14 ,  C08G18/09 ,  C08G18/22 ,  C08G18/40 ,  C08J9/02 ,  C08G18/20 ,  C08G18/34 ,  C08G101/00

摘要： Catalyst compositions useful in the production of insulating polyurethane or polyisocyanurate foam are disclosed. The catalyst compositions impart increased stability of a mixture of the catalyst, a halogen-containing blowing agent, and a polyol. These catalyst compositions comprise of at least 10% of a tetraalkylguanidine and at least 10% of a tertiary amine catalyst with an isocyanate reactive group. These improved catalysts can be used with any halogenated blowing agent, and provide substantial stability benefits with the use of hydrofluoroolefins and hydrofluorochloroolefins. In an exemplary embodiment, a process includes providing a pre-mix comprising a hydrohaloolefin blowing agent, at least one polyol, water, and a catalyst comprising 10-50% tetramethylguanidine and 10-90% of one or more of an amine catalyst containing an isocyanate reactive group.

公开(公告)号：US10125234B2

公开(公告)日：2018-11-13

申请号：US14632037

申请日：2015-02-26

申请人： EVONIK DEGUSSA GMBH

发明人： Robert Francis Hoffman ,  James Douglas Tobias ,  Jean Louise Vincent ,  Timothy J. Miller

IPC分类号： C08G18/16 ,  C08J9/14 ,  C08G18/79 ,  C08G18/09 ,  C08G18/22 ,  C08G18/42 ,  C08J9/00 ,  C08J9/12 ,  C08G101/00

摘要： A composition and process to make polyisocyanurate or polyurethane foam using a catalyst composition comprising at least one bismuth carboxylate catalyst and one or more co-catalysts selected from the group of alkali metal carboxylates and quaternary ammonium carboxylate salts, such that the resultant foam has improved insulation properties. The polyisocyanurate or polyurethane foams produced by this catalyst composition and method are useful for laminated boardstock, construction panels, appliance insulation, and spray-applied insulation.