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    Alkali-and acid-resistant glass composition for the manufacture of glass strands
    1.
    发明授权
    Alkali-and acid-resistant glass composition for the manufacture of glass strands 有权

    公开(公告)号：US09790122B2

    公开(公告)日：2017-10-17

    申请号：US12091615

    申请日：2006-10-23

    申请人： Emmanuel Lecomte ,  Eric Dallies ,  Anne Berthereau

    发明人： Emmanuel Lecomte ,  Eric Dallies ,  Anne Berthereau

    IPC分类号： B32B17/06 ,  C03C13/02 ,  C03C3/087 ,  C03C13/00

    CPC分类号： C03C3/087 ,  C03C13/002

    摘要： The present invention relates to a glass composition which is resistant to alkalis and to acids, in particular for the preparation of reinforcing glass strands, which comprises the following constituents within the limits defined below, as percentages by weight: SiO2≧58%, preferably ≦65% ZrO215-20% R2O (R = Na, K or Li)≧14% K2O≦0.1%, preferably ≦0.05%, RO (R = Mg, Ca or Sr)2.5-6% MgO≦4% TiO2>1 and ≦4% the composition additionally being devoid of F, comprising less than 1% of impurities (Al2O3, Fe2O3 and Cr2O3) and satisfying the following relationships: ZrO2+TiO2≧17% ZrO2/TiO2≧6 It also relates to the use of the glass strands obtained in the reinforcing of inorganic materials, for example cementitious materials, or organic materials, for example plastics, and to the composites including such strands.

    Alkali-And Acid-Resistant Glass Composition For The Manufacture Of Glass Strands
    2.
    发明申请
    Alkali-And Acid-Resistant Glass Composition For The Manufacture Of Glass Strands 有权
    用于制造玻璃丝的耐碱耐酸玻璃组合物

    公开(公告)号：US20090305053A1

    公开(公告)日：2009-12-10

    申请号：US12091615

    申请日：2006-10-23

    申请人： Emmanuel Lecomte ,  Eric Dallies ,  Anne Berthereau

    发明人： Emmanuel Lecomte ,  Eric Dallies ,  Anne Berthereau

    IPC分类号： B32B17/06 ,  C03C13/02

    CPC分类号： C03C3/087 ,  C03C13/002

    摘要： The present invention relates to a glass composition which is resistant to alkalis and to acids, in particular for the preparation of reinforcing glass strands, which comprises the following constituents within the limits defined below, as percentages by weight: SiO2≧58%, preferably ≦65% ZrO215-20% R2O (R = Na, K or Li)≧14% K2O≦0.1%, preferably ≦0.05% RO (R = Mg, Ca or Sr)2.5-6% MgO≦4% TiO2>1 and ≦4% the composition additionally being devoid of F, comprising less than 1% of impurities (Al2O3, Fe2O3 and Cr2O3) and satisfying the following relationships: ZrO2+TiO2≧17% ZrO2/TiO2≧6 It also relates to the use of the glass strands obtained in the reinforcing of inorganic materials, for example cementitious materials, or organic materials, for example plastics, and to the composites including such strands.

    摘要翻译： 本发明涉及耐碱和酸的玻璃组合物，特别是用于制备增强玻璃丝束的玻璃组合物，其包含下列限定的以下组分，重量百分比：SiO 2 = 58％，优选 ZrO2 15-20％R2O（R = Na，K或Li）> = 14％K2O RO（R = Mg，Ca或Sr）2.5-6％MgO TiO2> 1，组合物另外不含F， 1％的杂质（Al 2 O 3，Fe 2 O 3和Cr 2 O 3），并且满足以下关系：ZrO 2 + TiO 2 = 17％ZrO 2 / TiO 2> = 6还涉及在无机材料的增强中获得的玻璃丝的用途，例如 水泥质材料或有机材料，例如塑料，以及包括这种链的复合材料。

    Corrosion-Resistant Fiberglass-Reinforced Plastic Material
    3.
    发明申请
    Corrosion-Resistant Fiberglass-Reinforced Plastic Material 审中-公开
    耐腐蚀玻璃纤维增​​强塑料材料

    公开(公告)号：US20070243995A1

    公开(公告)日：2007-10-18

    申请号：US11630400

    申请日：2005-06-24

    申请人： Eric Dallies ,  Anne Berthereau

    发明人： Eric Dallies ,  Anne Berthereau

    IPC分类号： C04B35/14

    CPC分类号： C03C13/002

    摘要： The present invention relates to the use of glass reinforcing yarns of given composition for obtaining plastics with improved resistance to corrosive, especially basic and acid, substances. It also relates to the composites comprising a plastic reinforced by such glass yarns.

    摘要翻译： 本发明涉及给定组合物的玻璃增强纱线用于获得对腐蚀性，特别是碱性和酸性物质具有改善的耐腐蚀性的塑料的用途。 它还涉及包括由这种玻璃纱线增强的塑料的复合材料。

    Reinforcing threads and composites resistant to corrosive media
    5.
    发明申请
    Reinforcing threads and composites resistant to corrosive media 失效
    加强螺纹和耐腐蚀介质的复合材料

    公开(公告)号：US20050147816A1

    公开(公告)日：2005-07-07

    申请号：US10506674

    申请日：2003-03-26

    申请人： Eric Dallies ,  Patrick Moireau

    发明人： Eric Dallies ,  Patrick Moireau

    IPC分类号： B29B15/14 ,  B29K105/08 ,  B29K309/08 ,  C03C25/10 ,  C03C25/40 ,  D06M13/513 ,  D06M101/00 ,  D02G3/00

    CPC分类号： C03C25/40 ,  Y10T428/2933 ,  Y10T428/2938 ,  Y10T428/2962 ,  Y10T428/2964

    摘要： The present invention relates to reinforcement yarns coated with a sizing composition comprising at least one silane satisfying the formula: Si(R1) (R2) (R3) (R4) in which: R1, R2 and R3 are chosen from the following atoms or groups: —H (except in the case of R3), —Cl, —O—R5, —O—R6—O—R5, —O—(C═O)—R5, —O—R6—(C═O)—R5, R5 and R6 being chosen from hydrocarbon radicals whose main chain has from 1 to 4 carbon atoms; R4═—R7—NHR8 R7 being chosen from branched hydrocarbon radicals whose main chain has from 2 to 6 carbon atoms, R8 being chosen from the following groups: —H, —R9—NH2, —R10—NH—R9—NH2, R9 being chosen from hydrocarbon radicals containing 1 to 12 carbon atoms or from carbonyls, and R10 being chosen from hydrocarbon radicals whose main chain has from 1 to 6 carbon atoms. The glass yarns according to the invention are particularly suitable for reinforcing organic materials, the yarns and composites obtained resisting in a corrosive medium.

    摘要翻译： 本发明涉及涂覆有包含至少一种满足以下公式的硅烷的施胶组合物的增强纱线：<？in-line-formula description =“In-line Formulas”end =“lead”？> Si（R 1 （R 2）（R 3）（R 4）在线式描述=“In- 其中：R 1，R 2和R 3选自以下原子或基团，其中R 1，R 2，R 3，R 3， ：-H（除了R 3的情况除外），-Cl，-OR 5，-OR 6，-OR 5 -O-（CO）-R 5，-OR 6 - （CO）-R 5，R SUP > 5和R 6选自主链具有1至4个碳原子的烃基; R 4选自支链烃基，其主链具有以下基团：支链烃基，其主链具有 2至6个碳原子，R 8选自以下基团：-H，-R 9 -NH 2，-R SUP > 10个-NH-R 9 -NH 2，R 9选自含有1至12个碳原子的烃基或 来自羰基，R 10选自主链具有1至6个碳原子的烃基。 根据本发明的玻璃纱线特别适用于增强有机材料，在腐蚀性介质中获得的纱线和复合材料。

    Reinforcing threads and composites resistant to corrosive media
    7.
    发明授权
    Reinforcing threads and composites resistant to corrosive media 失效
    加强螺纹和耐腐蚀介质的复合材料

    公开(公告)号：US07276282B2

    公开(公告)日：2007-10-02

    申请号：US10506674

    申请日：2003-03-26

    申请人： Eric Dallies ,  Patrick Moireau

    发明人： Eric Dallies ,  Patrick Moireau

    IPC分类号： B32B9/00 ,  C08K9/06

    CPC分类号： C03C25/40 ,  Y10T428/2933 ,  Y10T428/2938 ,  Y10T428/2962 ,  Y10T428/2964

    摘要： The present invention relates to reinforcement yarns coated with a sizing composition comprising at least one silane satisfying the formula: Si(R1)(R2)(R3)(R4) in which: R1, R2 and R3 are chosen from the following atoms or groups: —H (except in the case of R3), —Cl, —O—R5, —O—R6—O—R5, —O—(C═O)—R5, —O—R6—(C═O)—R5, R5 and R6 being chosen from hydrocarbon radicals whose main chain has from 1 to 4 carbon atoms; R4═—R7—NHR8 R7 being chosen from branched hydrocarbon radicals whose main chain has from 2 to 6 carbon atoms, R8 being chosen from the following groups: —H, —R9—NH2, —R10—NH—R9—NH2, R9 being chosen from hydrocarbon radicals containing 1 to 12 carbon atoms or from carbonyls, and R10 being chosen from hydrocarbon radicals whose main chain has from 1 to 6 carbon atoms. The glass yarns according to the invention are particularly suitable for reinforcing organic materials, the yarns and composites obtained resisting in a corrosive medium.

    摘要翻译： 本发明涉及涂覆有包含至少一种满足以下公式的硅烷的施胶组合物的增强纱线：<？in-line-formula description =“In-line Formulas”end =“lead”？> Si（R 1 （R 2）（R 3）（R 4）在线式描述=“In- 其中：R 1，R 2和R 3选自以下原子或基团，其中R 1，R 2，R 3，R 3， ：-H（除了R 3的情况除外），-Cl，-OR 5，-OR 6，-OR 5 -O-（CO）-R 5，-OR 6 - （CO）-R 5，R SUP > 5和R 6选自主链具有1至4个碳原子的烃基; R 4选自支链烃基，其主链具有以下基团：支链烃基，其主链具有 2至6个碳原子，R 8选自以下基团：-H，-R 9 -NH 2，-R SUP > 10个-NH-R 9 -NH 2，R 9选自含有1至12个碳原子的烃基或 来自羰基，R 10选自主链具有1至6个碳原子的烃基。 根据本发明的玻璃纱线特别适用于增强有机材料，在腐蚀性介质中获得的纱线和复合材料。