Sulfated catalyst for skeletal isomerization of olefins
    1.
    发明授权
    Sulfated catalyst for skeletal isomerization of olefins 失效
    用于烯烃骨架异构化的硫酸化催化剂

    公开(公告)号:US5182247A

    公开(公告)日:1993-01-26

    申请号:US653217

    申请日:1991-02-11

    IPC分类号: B01J27/053 C07C5/27

    CPC分类号: B01J27/053 C07C5/2781

    摘要: Normal olefins such as n-butene can be converted to branched species by skeletal isomerization over catalysts containing solid acids prepared by sulfating catalyst precursors containing hydrous metal oxides--e.g., aluminas, silica-aluminas or clays treated with sulfuric acid, metal sulfates, sulfur trioxide or organic sulfates. The catalyst precursors are sulfated sufficiently to produce the desired skeletal isomerization without substantial cracking under suitable isomerization conditions.

    摘要翻译: 通过骨架异构化,可以通过骨架异构化将正链烯烃转化成支链物质,所述催化剂含有通过硫酸化含有水合金属氧化物的催化剂前体制备的固体酸,例如氧化铝,二氧化硅 - 氧化铝或硫酸处理的粘土,金属硫酸盐,三氧化硫 或有机硫酸盐。 催化剂前体被充分硫酸化以在合适的异构化条件下产生所需的骨架异构化而没有实质的裂解。

    Skeletal isomerization of n-pentenes to isopentene on pretreated zeolites
    2.
    发明授权
    Skeletal isomerization of n-pentenes to isopentene on pretreated zeolites 失效
    在预处理的沸石上正己烯对异戊烯的骨架异构化

    公开(公告)号:US5463160A

    公开(公告)日:1995-10-31

    申请号:US112999

    申请日:1993-08-30

    IPC分类号: C07C5/27

    CPC分类号: C07C5/2775 Y02P20/125

    摘要: The selective conversion by skeletal isomerization over steam pretreated ferrierite zeolite-based catalysts having pore sizes of at least about 4.2 Angstroms and a pore structure characterized by intersecting 10-MR and 8-MR channels. The steam pretreated ferrierite zeolite-based catalysts have sufficient acidity to catalyze the skeletal isomerization of normal olefins. The catalysts can be used to produce isoolefins for reaction with alcohols in integrated processes to produce tertiary amyl methyl ethers such as TAME.

    摘要翻译: 通过在具有至少约4.2埃的孔径的蒸汽预处理的镁碱沸石基催化剂上进行骨架异构化的选择性转化和以10-MR和8-MR通道相交为特征的孔结构。 蒸汽预处理的镁碱沸石基催化剂具有足够的酸度来催化正构烯烃的骨架异构化。 催化剂可以用于制备用于与醇在一体化方法中反应的异烯烃,以产生叔戊基甲基醚如TAME。

    Method and apparatus for the production of exhaust gas filters
    3.
    发明授权
    Method and apparatus for the production of exhaust gas filters 失效
    用于生产废气过滤器的方法和设备

    公开(公告)号:US4553499A

    公开(公告)日:1985-11-19

    申请号:US604187

    申请日:1984-04-26

    IPC分类号: B01J37/02 B05C3/04 B05C3/09

    CPC分类号: B01J37/0215

    摘要: Method and apparatus for forming a coating material, and for depositing the material onto the surface of an article or a substrate. The apparatus includes a tank within which the coating composition is formed together with a residual amount of gas. The tank and the internal support members are electrically segregated from a perforated container with reactant material held on the internal support to avoid the formation of gas bubbles on the surfaces of the tank and support which are immersed into the coating composition.

    摘要翻译: 用于形成涂料的方法和设备,以及用于将材料沉积到物品或基底的表面上。 该装置包括一个罐,其中涂料组合物与剩余量的气体一起形成。 罐和内部支撑构件与穿孔容器电隔离,反应物材料保持在内部支撑件上,以避免在浸入涂料组合物中的罐和支撑体的表面上形成气泡。

    Coal liquefaction process
    4.
    发明授权
    Coal liquefaction process 失效
    煤液化过程

    公开(公告)号:US4551224A

    公开(公告)日:1985-11-05

    申请号:US562323

    申请日:1983-12-16

    申请人: Erven J. Kuhlmann

    发明人: Erven J. Kuhlmann

    IPC分类号: C10G1/00 C10G1/06 C10G45/00

    CPC分类号: C10G1/002 C10G1/065 C10G45/00

    摘要: Process for liquefying coal or similar liquefiable carbonaceous solids in which the liquefaction solvent is a hydrotreated solvent mixture that is derived in the process. The solvent mixture comprises at least 78 wt. % decalin, comprising cis and trans decalin. The cis-isomers comprise at least 80 wt. % of the total weight of the decalin. The solvent mixture may also include about 0-2 wt. % of naphthalene, about 0-5 wt. % of a constituent comprising the mono and/or di methyl derivative of at least one of the other constituents in the mixture, and tetralin comprising the remainder, e.g., about 1-22 wt. %.

    摘要翻译: 用于液化煤或类似可液化碳质固体的方法,其中液化溶剂是在该方法中得到的加氢处理的溶剂混合物。 溶剂混合物包含至少78wt。 %十氢化萘,包括顺式和反式十氢化萘。 顺式异构体包含至少80wt。 十氢萘总重量的百分比。 溶剂混合物还可以包括约0-2重量% %的萘,约0-5wt。 包含混合物中至少一种其它组分的单和/或二甲基衍生物的组分的%,以及包含剩余部分例如约1-22重量%的四氢化萘。 %。

    Process for improving the hydrogen donor properties of a coal
liquefaction solvent
    5.
    发明授权
    Process for improving the hydrogen donor properties of a coal liquefaction solvent 失效
    改善煤液化溶剂的氢供体特性的方法

    公开(公告)号:US4476009A

    公开(公告)日:1984-10-09

    申请号:US478196

    申请日:1983-03-24

    CPC分类号: C10G67/16 C10G1/002

    摘要: A process for improving the properties of a hydrogen donor coal liquefaction solvent employed in a coal liquefaction process which comprises separating said coal liquefaction solvent into a first fraction boiling in the range from about 350.degree. to about 675.degree. F., and a second fraction boiling in the range from about 675.degree. F. to about 1000.degree. F., hydrogenating said first fraction at a temperature ranging from about 600.degree. to about 800.degree. F., under a pressure of about 500 to 4000 psig, hydrogenating said second fraction at a temperature ranging from about 600.degree. to 700.degree. F. at a pressure from about 500 to 4000 psig and combining said hydrogenated first and second fractions to provide a coal liquefaction solvent having an increased concentration of hydrogen donor components.

    摘要翻译: 一种用于改善在煤液化过程中使用的氢供体煤液化溶剂的性质的方法,其包括将所述煤液化溶剂分离成沸点在约350至约675°F的沸点的第一馏分和沸腾的第二馏分 在约675°F至约1000°F的范围内,在约600至约800°F的温度下在约500至4000psig的压力下氢化所述第一级分,将所述第二级分在 温度范围为约600至700°F,压力为约500至4000psig,并组合所述氢化的第一和第二级分以提供具有增加的供氢组分浓度的煤液化溶剂。