公开(公告)号：US5599782A

公开(公告)日：1997-02-04

申请号：US576263

申请日：1995-12-21

申请人： Robert Y. L. Pan ,  Eugene P. Gosselink ,  Eugene J. Pancheri ,  Stephen W. Morrall

发明人： Robert Y. L. Pan ,  Eugene P. Gosselink ,  Eugene J. Pancheri ,  Stephen W. Morrall

IPC分类号： C08G63/688 ,  C11D3/00 ,  C11D3/37 ,  C11D17/06 ,  C11D1/02

CPC分类号： C08G63/6884 ,  C11D3/0036 ,  C11D3/3715

摘要： Improved soil release agents for granular laundry detergents, typically used at levels as low as about 1% of a fully-formulated anionic surfactant-containing granular detergent, are reaction products of transesterifying and oligomerizing mixtures of monomers having the functions MO.sub.3 SC.sub.6 H.sub.4 C(O)--, M'O.sub.3 SC.sub.6 H.sub.3 {C(O)O--}.sub.2, --(O)CC.sub.6 H.sub.4 C(O)-- and --OCH.sub.2 CH.sub.2 O-- wherein M and M' are independently selected from lithium, potassium and sodium, more preferably sodium; said mixtures having mole ratio of MO.sub.3 SC.sub.6 H.sub.4 C(O)-- to --(O)CC.sub.6 H.sub.4 C(O)-- of from about 0.2:1 to about 1.4:1, mole ratio of MO.sub.3 SC.sub.6 H.sub.4 C(O)-- to M'O.sub.3 SC.sub.6 H.sub.3 {C(O)O--}.sub.2 of from about 0.67:1 to about 20:1 and mole ratio of MO.sub.3 SC.sub.6 H.sub.4 C(O)-- to --OCH.sub.2 CH.sub.2 O-- of from about 0.007:1 to about 0.51:1 and being substantially free from monomers of formula HOROH wherein R is propylene or higher alkyl.

摘要翻译： 用于粒状衣物洗涤剂的改进的去污剂通常以低至约1％的完全配制的含阴离子表面活性剂的颗粒洗涤剂的水平使用，是具有MO3SC6H4C（O） - ， M'O3SC6H3 {C（O）O-} 2， - （O）C16H4C（O） - 和-OCH2CH2O-，其中M和M'独立地选自锂，钾和钠，更优选钠; 所述混合物的MO 3 SC 6 H 4 C（O） - （O）C 6 H 4 C（O）的摩尔比为约0.2:1至约1.4:1摩尔比的MO 3 SC 6 H 4 C（O） - 与M'O 3 SC 6 H 3 {C（O） 约为0.67:1至约20:1的摩尔比和MO 3 SC 6 H 4 C（O） - 至-OCH 2 CH 2 O的摩尔比为约0.007:1至约0.51:1，并且基本上不含式HOROH的单体，其中R 是丙烯或高级烷基。

公开(公告)号：US5560862A

公开(公告)日：1996-10-01

申请号：US486905

申请日：1995-06-07

申请人： Eugene P. Gosselink ,  Gregory S. Miracle ,  Alan D. Willey ,  Michael E. Burns ,  Kevin L. Kott ,  Mark R. Sivik ,  Lucille F. Taylor

发明人： Eugene P. Gosselink ,  Gregory S. Miracle ,  Alan D. Willey ,  Michael E. Burns ,  Kevin L. Kott ,  Mark R. Sivik ,  Lucille F. Taylor

IPC分类号： B01J31/16 ,  C11D3/39 ,  C11D3/395 ,  C11D7/54 ,  C11D7/38 ,  C07D233/00

CPC分类号： C11D3/3927

摘要： Bleaching compositions, laundry and automatic dishwashing detergent compositions comprising multiple-substituted bleach activators which have at least one quaternary nitrogen atom, are provided. More specifically, the invention relates to compositions which provide enhanced cleaning/bleaching benefits though the selection of multiple-substituted quaternary bleach activators having specific leaving groups with a conjugate acid aqueous pK.sub.a above 13 and with advantageous ratios of rate of perhydrolysis to rate of hydrolysis and of rate of perhydrolysis to rate of diacylperoxide production. Included are preferred activator compounds and methods for washing fabrics, hard surfaces, and tableware using the activators.

公开(公告)号：US5188769A

公开(公告)日：1993-02-23

申请号：US857853

申请日：1992-03-26

申请人： Daniel S. Connor ,  Jeffrey J. Scheibel ,  Bruce P. Murch ,  Mark H. Mao ,  Eugene P. Gosselink ,  Roland G. Severson, Jr.

发明人： Daniel S. Connor ,  Jeffrey J. Scheibel ,  Bruce P. Murch ,  Mark H. Mao ,  Eugene P. Gosselink ,  Roland G. Severson, Jr.

IPC分类号： C07C231/02 ,  C11D1/52

CPC分类号： C11D1/525 ,  C07C231/02 ,  Y10S516/07

摘要： The synthesis of polyhydroxy fatty acid amide surfactants exemplified by the compound C.sub.11 H.sub.23 C(O)N(CH.sub.3)CH.sub.2 [CHOH].sub.4 CH.sub.2 OH by reacting a fatty acid ester with an N-alkyl sugar amine can result in contamination of the product surfactant by residual sources of fatty acids. These residual fatty acids may be unacceptable in high sudsing detergent compositions, such as dishwashing liquids, especially with Ca or Mg cations. The process of this invention reacts such contaminants with alkyl amines or, especially, ethanolamine, to convert them into fatty alkyl- or alkanolamides, which are quite acceptable in fully-formulated detergent compositions for home or industrial use.

摘要翻译： 通过使脂肪酸酯与N-烷基糖胺反应，由化合物C11H23C（O）N（CH3）CH2 [CHOH] 4CH2OH表示的多羟基脂肪酸酰胺表面活性剂的合成可导致产物表面活性剂被残留的来源污染 脂肪酸。 这些残留脂肪酸在高泡沫洗涤剂组合物中是不可接受的，例如餐具洗涤液，特别是与Ca或Mg阳离子。 本发明的方法使这些污染物与烷基胺或特别是乙醇胺反应，将它们转化成脂肪烷基 - 或链烷醇酰胺，其在用于家庭或工业用途的完全配制的洗涤剂组合物中是完全可接受的。

公开(公告)号：US4877896A

公开(公告)日：1989-10-31

申请号：US105421

申请日：1987-10-05

申请人： Rene Maldonado ,  Toan Trinh ,  Eugene P. Gosselink

发明人： Rene Maldonado ,  Toan Trinh ,  Eugene P. Gosselink

IPC分类号： C11D3/00 ,  C11D3/37

CPC分类号： C11D3/0036 ,  C11D3/3715

摘要： Anionic, especially sulfoaroyl, NaO.sub.3 S(C.sub.6 H.sub.4)C(O)- preferred, end-capped esters useful as soil release agents in detergent compositions and fabric-conditioner articles. The terephthalate esters contain unsymmetrically substituted oxy-1,2-alkyleneoxy units (oxy-1,2-propyleneoxy units preferred).

公开(公告)号：US4664848A

公开(公告)日：1987-05-12

申请号：US553550

申请日：1983-11-22

申请人： Young S. Oh ,  Eugene P. Gosselink

发明人： Young S. Oh ,  Eugene P. Gosselink

IPC分类号： C08G65/26 ,  C11D1/40 ,  C11D1/62 ,  C11D3/37

CPC分类号： C08G65/2624 ,  C11D1/40 ,  C11D1/62 ,  C11D3/3723

摘要： Detergent compositions which comprise from about 0.05 to about 95% by weight of a water-soluble cationic compound having clay soil removal/anti-redeposition properties. These compounds are selected from ethoxylated cationic monoamines, ethoxylated cationic diamines, ethoxylated cationic polyamines, ethoxylated cationic polymers, and mixtures thereof. In addition to the cationic compounds, the detergent compositions further comprise from about 1 to about 75% by weight of a nonionic, anionic, ampholytic, zwitterionic, or cationic detergent surfactant or mixture thereof. In addition to these detergent surfactants, the detergent composition can optionally comprise from 0 to about 80% by weight of a detergent builder.

摘要翻译： 洗涤剂组合物，其包含约0.05至约95重量％的具有粘土去除/抗再沉积性质的水溶性阳离子化合物。 这些化合物选自乙氧基化阳离子单胺，乙氧基化阳离子二胺，乙氧基化阳离子多胺，乙氧基化阳离子聚合物及其混合物。 除了阳离子化合物之外，洗涤剂组合物还包含约1至约75重量％的非离子，阴离子，两性，两性离子或阳离子洗涤剂表面活性剂或其混合物。 除了这些洗涤剂表面活性剂之外，洗涤剂组合物可以任选地包含0至约80重量％的洗涤剂助洗剂。

公开(公告)号：US4551506A

公开(公告)日：1985-11-05

申请号：US452655

申请日：1982-12-23

申请人： Eugene P. Gosselink

发明人： Eugene P. Gosselink

IPC分类号： C08G65/26 ,  C08G73/04 ,  C11D1/40 ,  C11D1/62 ,  C11D3/37 ,  C11D3/48

CPC分类号： C11D3/3723 ,  C08G65/2624 ,  C11D1/40 ,  C11D1/62

摘要： Water-soluble cationic polymers having clay soil removal/anti-redeposition properties, which comprise a polymer backbone, at least two M groups and at least one L-X group, wherein M is a cationic group attached to or integral with the backbone and contains an N+ positively charged center; X is a nonionic group selected from the group consisting of H, C.sub.1 -C.sub.4 alkyl or hydroxyalkyl ester or ether groups, or mixtures thereof; and L is a hydrophilic chain connecting groups M and X or connecting X to the polymer backbone. L also contains the polyoxyalkylene moiety --[(R'O).sub.m (CH.sub.2 CH.sub.2 O).sub.n ]--, wherein R' is C.sub.3 -C.sub.4 alkylene or hydroxyalkylene, m and n are numbers such that the moiety --(CH.sub.2 CH.sub.2 O).sub.n -- is at least about 50% by weight of said polyoxyalkylene moiety, and n is at least about 3. These cationic polymers are useful in detergent compositions.

摘要翻译： 具有粘土去除/抗再沉积性质的水溶性阳离子聚合物，其包含聚合物主链，至少两个M基团和至少一个LX基团，其中M是与骨架连接或与骨架一体并含有N + 带正电的中心; X是选自H，C 1 -C 4烷基或羟烷基酯或醚基的非离子基团，或其混合物; L是连接基团M和X或将X连接到聚合物骨架的亲水链。 L还含有聚氧化烯部分 - [（R'O）m（CH 2 CH 2 O）n] - ，其中R'是C 3 -C 4亚烷基或羟基亚烷基，m和n是数个这样的数字，使得部分 - （CH 2 CH 2 O）n-至少 约50重量％的所述聚氧化烯部分，n为至少约3.这些阳离子聚合物可用于洗涤剂组合物中。

公开(公告)号：US4861512A

公开(公告)日：1989-08-29

申请号：US228814

申请日：1988-08-02

申请人： Eugene P. Gosselink

发明人： Eugene P. Gosselink

IPC分类号： C08G63/66 ,  C08G63/688 ,  C11D3/37

CPC分类号： C11D3/0036 ,  C08G63/66 ,  C08G63/688 ,  C11D3/3715

摘要： Block polyesters useful as soil release agents in detergent compositions are disclosed. Preferred polyesters have the formula: ##STR1## wherein each R.sup.1 is a 1,4-phenylene moiety; the R.sup.2 consist essentially of ethylene moieties, 1,2-propylene moieties or a mixture thereof; each X is ethyl or preferably methyl; each n is from about 12 to about 43; u is from about 3 to about 10.

摘要翻译： 公开了用作洗涤剂组合物中的污垢释放剂的嵌段聚酯。 优选的聚酯具有下式：其中每个R 1是1,4-亚苯基部分; R2基本上由亚乙基部分，1,2-亚丙基部分或其混合物组成; 每个X是乙基或优选甲基; 每个n为约12至约43; u为约3至约10。

公开(公告)号：US4713194A

公开(公告)日：1987-12-15

申请号：US852258

申请日：1986-04-15

申请人： Eugene P. Gosselink

发明人： Eugene P. Gosselink

IPC分类号： C07C69/82 ,  C08G63/672 ,  C08G63/688 ,  C08G69/44 ,  C08L67/00 ,  C08L67/02 ,  C11D3/37 ,  C11D17/00

CPC分类号： C11D3/0036 ,  C08G63/672 ,  C08G63/6886 ,  C11D3/3715

摘要： Block polyesters having branched hydrophilic capping groups which are useful as soil release agents in detergent compositions are disclosed. Preferred polyesters have the formula; ##STR1## wherein each R.sup.1 is a 1,4-phenylene moiety; the R.sup.2 are essentially ethylene moieties, 1,2-propylene moieties or a mixture thereof; each X is ethyl or preferably methyl; each n.sub.1 is from 1 to about 5; the sum of each n.sub.1 +n.sub.2 is from about 12 to about 43; u is from about 3 to about 10.

摘要翻译： 公开了具有支链亲水性封端基的嵌段聚酯，其可用作洗涤剂组合物中的去污剂。 优选的聚酯具有下式： ＆lt; IMAGE＆gt; + TR＆lt; IMAGE＆gt;其中每个R 1是1,4-亚苯基部分; R2基本上是亚乙基部分，1,2-亚丙基部分或其混合物; 每个X是乙基或优选甲基; 每个n1为1至约5; 每个n1 + n2的和为约12至约43; u为约3至约10。

公开(公告)号：US4659802A

公开(公告)日：1987-04-21

申请号：US553551

申请日：1983-11-22

申请人： Donn N. Rubingh ,  Eugene P. Gosselink

发明人： Donn N. Rubingh ,  Eugene P. Gosselink

IPC分类号： C08G65/26 ,  C11D1/40 ,  C11D1/62 ,  C11D3/37

CPC分类号： C11D3/3723 ,  C08G65/2624 ,  C11D1/40 ,  C11D1/62

摘要： Water-soluble cationic compounds having clay soil removal/anti-redeposition properties. The cationic compounds are selected from ethoxylated cationic diamines, ethoxylated cationic polyamines, ethoxylated cationic polymers and mixtures thereof. These cationic compounds are useful in detergent compositions.

摘要翻译： 具有粘土去除/抗再沉积性能的水溶性阳离子化合物。 阳离子化合物选自乙氧基化阳离子二胺，乙氧基化阳离子多胺，乙氧基化阳离子聚合物及其混合物。 这些阳离子化合物可用于洗涤剂组合物。

公开(公告)号：US4622378A

公开(公告)日：1986-11-11

申请号：US701883

申请日：1985-02-15

申请人： Eugene P. Gosselink

发明人： Eugene P. Gosselink

IPC分类号： C08G65/04 ,  C08G65/26 ,  C08G65/334 ,  C11D3/00 ,  C11D3/37 ,  C08G18/12 ,  C08G18/06

CPC分类号： C08G65/04 ,  C08G65/2624 ,  C08G65/3344 ,  C11D3/0036 ,  C11D3/3703 ,  C11D3/3707 ,  C11D3/3715 ,  C11D3/3719 ,  C11D3/3726 ,  C11D3/3796

摘要： Water-soluble zwitterionic polymers having clay soil removal/anti-redeposition properties, which comprise a polymer backbone, at least 2 M groups and at least one L-X group, wherein M is a cationic group attached to or integral with the backbone and contains an N+ positively charged center; X is an anionic group or a mixture of anionic and nonionic groups; and L is a hydrophilic chain connecting groups M and X or connecting X to the polymer backbone. L also contains the polyoxyalkylene moiety --[(R'O).sub.m (CH.sub.2 CH.sub.2 O).sub.n ]--, wherein R' is C.sub.3 -C.sub.4 alkylene or hydroxyalkylene, m and n are numbers such that the moiety --(CH.sub.2 CH.sub.2 O).sub.n -- comprises at least about 50% by weight of said polyoxyalkylene moiety, and n is at least about 3. These zwitterionic polymers are useful in detergent compositions at from about 0.05 to about 95% by weight. In addition to the polymer, the detergent compositions further comprise from about 1 to about 75% by weight of a nonionic, anionic, ampholytic, zwitterionic, or cationic detergent surfactant or mixture thereof.

摘要翻译： 具有粘土去除/抗再沉积性质的水溶性两性离子聚合物，其包含聚合物主链，至少2M个基团和至少一个LX基团，其中M是与骨架连接或与骨架整体并含有N + 带正电的中心; X是阴离子基团或阴离子和非离子基团的混合物; L是连接基团M和X或将X连接到聚合物骨架的亲水链。 L还含有聚氧化烯部分 - [（R'O）m（CH 2 CH 2 O）n] - ，其中R'是C 3 -C 4亚烷基或羟基亚烷基，m和n是这样的数字，使得 - （CH 2 CH 2 O）n-部分至少包含 约50重量％的所述聚氧化烯部分，n为至少约3.这些两性离子聚合物在洗涤剂组合物中的用量为约0.05至约95重量％。 除了聚合物之外，洗涤剂组合物还包含约1至约75重量％的非离子，阴离子，两性，两性离子或阳离子洗涤剂表面活性剂或其混合物。