公开(公告)号：US08399558B2

公开(公告)日：2013-03-19

申请号：US12305543

申请日：2007-06-19

申请人： Eui-chul Kang ,  Atsuhiko Ogura ,  Shingo Kataoka ,  Kenji Ito

发明人： Eui-chul Kang ,  Atsuhiko Ogura ,  Shingo Kataoka ,  Kenji Ito

IPC分类号： C08F136/00 ,  C08F8/42 ,  C08F8/40

CPC分类号： C09D4/00 ,  C08F220/36 ,  C08G18/3203 ,  C08G18/8116 ,  C08K3/013 ,  C09D1/00 ,  C09D5/08 ,  C09D5/24 ,  C09D175/16

摘要： The present disclosure provides an inorganic-organic hybrid film which is excellent in transparency, adhesion, heat resistance, weatherability, and anti-rust property, whose refractive index may be controlled easily, and which is also excellent in hardness. Also provided are an inorganic-organic hybrid composition as a starting material for the film, and a hard coating material, an optical material, an anti-rust coating material, and a conductive coating material, all utilizing the composition. The composition is characterized by containing organic component (A) composed of monomer component (a1) containing a particular diol (meth)acrylate compound (U) having a urethane bond, or polymer component (a2) containing polymer (P) obtained by polymerization of monomer component (a1), and inorganic component (B), wherein the ratio of the organic component (A) to the inorganic component (B) is 1:99 to 99:1 by mass.

摘要翻译： 本公开内容提供了透明性，粘合性，耐热性，耐候性和防锈性优异的无机 - 有机杂化膜，其折射率可以容易地控制，并且硬度也是优异的。 还提供了作为膜的起始材料的无机 - 有机杂化组合物，以及全部利用组合物的硬涂层材料，光学材料，防锈涂层材料和导电涂层材料。 该组合物的特征在于含有由含有具有氨基甲酸酯键的特定二醇（甲基）丙烯酸酯化合物（U）的单体成分（a1）构成的有机成分（A），或含有聚合物（P）的聚合物成分（a2） 单体成分（a1）和无机成分（B），其中有机成分（A）与无机成分（B）的比例为1:99〜99:1质量％。

公开(公告)号：US20090208719A1

公开(公告)日：2009-08-20

申请号：US12305543

申请日：2007-06-19

申请人： Eui-chul Kang ,  Atsuhiko Ogura ,  Shingo Kataoka ,  Kenji Ito

发明人： Eui-chul Kang ,  Atsuhiko Ogura ,  Shingo Kataoka ,  Kenji Ito

IPC分类号： B32B27/30 ,  C08F8/00 ,  C08F8/42 ,  C08F8/40 ,  C09D4/00

CPC分类号： C09D4/00 ,  C08F220/36 ,  C08G18/3203 ,  C08G18/8116 ,  C08K3/013 ,  C09D1/00 ,  C09D5/08 ,  C09D5/24 ,  C09D175/16

摘要： The present disclosure provides an inorganic-organic hybrid film which is excellent in transparency, adhesion, heat resistance, weatherability, and anti-rust property, whose refractive index may be controlled easily, and which is also excellent in hardness. Also provided are an inorganic-organic hybrid composition as a starting material for the film, and a hard coating material, an optical material, an anti-rust coating material, and a conductive coating material, all utilizing the composition. The composition is characterized by containing organic component (A) composed of monomer component (a1) containing a particular diol (meth)acrylate compound (U) having a urethane bond, or polymer component (a2) containing polymer (P) obtained by polymerization of monomer component (a1), and inorganic component (B), wherein the ratio of the organic component (A) to the inorganic component (B) is 1:99 to 99:1 by mass.

摘要翻译： 本公开内容提供了透明性，粘合性，耐热性，耐候性和防锈性优异的无机 - 有机杂化膜，其折射率可以容易地控制，并且硬度也是优异的。 还提供了作为膜的起始材料的无机 - 有机杂化组合物，以及全部利用组合物的硬涂层材料，光学材料，防锈涂层材料和导电涂层材料。 该组合物的特征在于含有由含有具有氨基甲酸酯键的特定二醇（甲基）丙烯酸酯化合物（U）的单体成分（a1）构成的有机成分（A），或含有聚合物（P）的聚合物成分（a2） 单体成分（a1）和无机成分（B），其中有机成分（A）与无机成分（B）的比例为1:99〜99:1质量％。

公开(公告)号：US07649105B2

公开(公告)日：2010-01-19

申请号：US12478189

申请日：2009-06-04

申请人： Eui-chul Kang ,  Atsuhiko Ogura ,  Shingo Kataoka ,  Takashi Iwata

发明人： Eui-chul Kang ,  Atsuhiko Ogura ,  Shingo Kataoka ,  Takashi Iwata

IPC分类号： C07C69/74

CPC分类号： C07C271/16 ,  C07D317/22 ,  C08G18/283 ,  C08G18/678 ,  C08G18/8116

摘要： The present invention provides compounds having in their molecule a structure contributing to high hydrophilicity, and having high photopolymerizability, as well as polymers of such compounds, and a method for producing the compound. The compounds are diol (meth)acrylate having a urethane bond represented by the formula (1), and cyclic ketal (meth)acrylate having a urethane bond represented by the formula (2): (R1: H, —CH3; R2: —(CH2)n-; R3: —(CH2)m-; n: 1-4; m: 1-8; (AO): C2-C4 oxyalkylene group; x: 0-1000; R4, R5: H, —CH3, —C2H5).

公开(公告)号：US07763694B2

公开(公告)日：2010-07-27

申请号：US12631049

申请日：2009-12-04

申请人： Eui-chul Kang ,  Atsuhiko Ogura ,  Shingo Kataoka ,  Takashi Iwata

发明人： Eui-chul Kang ,  Atsuhiko Ogura ,  Shingo Kataoka ,  Takashi Iwata

IPC分类号： C08F20/26 ,  C08F34/02 ,  C08F20/58

CPC分类号： C07C271/16 ,  C07D317/22 ,  C08G18/283 ,  C08G18/678 ,  C08G18/8116

摘要： The present invention provides compounds having in their molecule a structure contributing to high hydrophilicity, and having high photopolymerizability, as well as polymers of such compounds, and a method for producing the compound. The compounds are diol (meth)acrylate having a urethane bond represented by the formula (1), and cyclic ketal (meth)acrylate having a urethane bond represented by the formula (2): (R1: H, —CH3; R2: —(CH2)n-; R3: —(CH2)m-; n: 1-4; m: 1-8; (AO): C2-C4 oxyalkylene group; x: 0-1000; R4, R5: H, —CH3, —C2H5).

摘要翻译： 本发明提供了在其分子中具有有助于高亲水性和高光聚合性的结构的化合物，以及这些化合物的聚合物，以及该化合物的制备方法。 化合物是具有由式（1）表示的氨基甲酸酯键的二醇（甲基）丙烯酸酯和具有由式（2）表示的氨基甲酸酯键的环状缩酮（甲基）丙烯酸酯：（R1：H，-CH3; R2： - （CH2）n-; R3： - （CH2）m-; n：1-4; m：1-8;（AO）：C2-C4氧化烯基; x：0-1000; R4，R5：H， CH3，-C2H5）。

公开(公告)号：US20100081780A1

公开(公告)日：2010-04-01

申请号：US12631097

申请日：2009-12-04

申请人： Eui-chul Kang ,  Atsuhiko Ogura ,  Shingo Kataoka ,  Takashi Iwata

发明人： Eui-chul Kang ,  Atsuhiko Ogura ,  Shingo Kataoka ,  Takashi Iwata

IPC分类号： C08F30/02 ,  C08F220/00 ,  C08F28/02

CPC分类号： C07C271/16 ,  C07D317/22 ,  C08G18/283 ,  C08G18/678 ,  C08G18/8116

摘要： The present invention provides compounds having in their molecule a structure contributing to high hydrophilicity, and having high photopolymerizability, as well as polymers of such compounds, and a method for producing the compound. The compounds are diol (meth)acrylate having a urethane bond represented by the formula (1), and cyclic ketal (meth)acrylate having a urethane bond represented by the formula (2): (R1: H, —CH3; R2: —(CH2)n-; R3: —(CH2)m-; n: 1-4; m: 1-8; (AO): C2-C4 oxyalkylene group; x: 0-1000; R4, R5: H, —CH3, —C2H5).

摘要翻译： 本发明提供了在其分子中具有有助于高亲水性和高光聚合性的结构的化合物，以及这些化合物的聚合物，以及该化合物的制备方法。 化合物是具有由式（1）表示的氨基甲酸酯键的二醇（甲基）丙烯酸酯和具有由式（2）表示的氨基甲酸酯键的环状缩酮（甲基）丙烯酸酯：（R1：H，-CH3; R2： - （CH2）n-; R3： - （CH2）m-; n：1-4; m：1-8;（AO）：C2-C4氧化烯基; x：0-1000; R4，R5：H， CH3，-C2H5）。

公开(公告)号：US07557239B2

公开(公告)日：2009-07-07

申请号：US11259543

申请日：2005-10-25

申请人： Eui-chul Kang ,  Atsuhiko Ogura ,  Shingo Kataoka ,  Takashi Iwata

发明人： Eui-chul Kang ,  Atsuhiko Ogura ,  Shingo Kataoka ,  Takashi Iwata

IPC分类号： C07C69/00

CPC分类号： C07C271/16 ,  C07D317/22 ,  C08G18/283 ,  C08G18/678 ,  C08G18/8116

摘要： The present invention provides compounds having in their molecule a structure contributing to high hydrophilicity, and having high photopolymerizability, as well as polymers of such compounds, and a method for producing the compound. The compounds are diol (meth)acrylate having a urethane bond represented by the formula (1), and cyclic ketal (meth)acrylate having a urethane bond represented by the formula (2): (R1: H, —CH3; R2: —(CH2)n-; R3: —(CH2)m-; n: 1-4; m: 1-8; (AO): C2-C4 oxyalkylene group; x: 0-1000; R4, R5: H, —CH3, —C2H5).

摘要翻译： 本发明提供了在其分子中具有有助于高亲水性和高光聚合性的结构的化合物，以及这些化合物的聚合物，以及该化合物的制备方法。 化合物是具有由式（1）表示的氨基甲酸酯键的二醇（甲基）丙烯酸酯和具有由式（2）表示的氨基甲酸酯键的环状缩酮（甲基）丙烯酸酯：（R1：H，-CH3; R2： - （CH2）n-; R3： - （CH2）m-; n：1-4; m：1-8;（AO）：C2-C4氧化烯基; x：0-1000; R4，R5：H， CH3，-C2H5）。

公开(公告)号：US20060089473A1

公开(公告)日：2006-04-27

申请号：US11259543

申请日：2005-10-25

申请人： Eui-chul Kang ,  Atsuhiko Ogura ,  Shingo Kataoka ,  Takashi Iwata

发明人： Eui-chul Kang ,  Atsuhiko Ogura ,  Shingo Kataoka ,  Takashi Iwata

IPC分类号： C08F226/02 ,  C07C271/18

CPC分类号： C07C271/16 ,  C07D317/22 ,  C08G18/283 ,  C08G18/678 ,  C08G18/8116

摘要： The present invention provides compounds having in their molecule a structure contributing to high hydrophilicity, and having high photopolymerizability, as well as polymers of such compounds, and a method for producing the compound. The compounds are diol (meth)acrylate having a urethane bond represented by the formula (1), and cyclic ketal (meth)acrylate having a urethane bond represented by the formula (2): (R1: H, —CH3; R2: —(CH2)n-; R3: —(CH2)m-; n: 1-4; m: 1-8; (AO) : C2-C4 oxyalkylene group; x: 0-1000; R4, R5: H, —CH3, —C2H5).

摘要翻译： 本发明提供了在其分子中具有有助于高亲水性和高光聚合性的结构的化合物，以及这些化合物的聚合物，以及该化合物的制备方法。 化合物是具有由式（1）表示的氨基甲酸酯键的二醇（甲基）丙烯酸酯和具有由式（2）表示的氨基甲酸酯键的环状缩酮（甲基）丙烯酸酯：（R 1） H，-CH 3; R 2： - （CH 2）n - ; R 3： - （ CH 2）m-; n：1-4; m：1-8;（AO）：C 2 -C 4亚氧烷基; x：0-1000; R 4 < H 5，-CH 3，-C 2 H 5）。

公开(公告)号：US07763695B2

公开(公告)日：2010-07-27

申请号：US12631097

申请日：2009-12-04

申请人： Eui-chul Kang ,  Atsuhiko Ogura ,  Shingo Kataoka ,  Takashi Iwata

发明人： Eui-chul Kang ,  Atsuhiko Ogura ,  Shingo Kataoka ,  Takashi Iwata

IPC分类号： C08F20/26 ,  C08F34/02 ,  C08F20/58

CPC分类号： C07C271/16 ,  C07D317/22 ,  C08G18/283 ,  C08G18/678 ,  C08G18/8116

摘要： The present invention provides compounds having in their molecule a structure contributing to high hydrophilicity, and having high photopolymerizability, as well as polymers of such compounds, and a method for producing the compound. The compounds are diol (meth)acrylate having a urethane bond represented by the formula (1), and cyclic ketal (meth)acrylate having a urethane bond represented by the formula (2): (R1: H, —CH3; R2: —(CH2)n-; R3: —(CH2)m-; n: 1-4; m: 1-8; (AO): C2-C4 oxyalkylene group; x: 0-1000; R4, R5: H, —CH3, —C2H5).

公开(公告)号：US20090240015A1

公开(公告)日：2009-09-24

申请号：US12478189

申请日：2009-06-04

申请人： Eui-chul Kang ,  Atsuhiko Ogura ,  Shingo Kataoka ,  Takashi Iwata

发明人： Eui-chul Kang ,  Atsuhiko Ogura ,  Shingo Kataoka ,  Takashi Iwata

IPC分类号： C08F24/00 ,  C07D317/24

CPC分类号： C07C271/16 ,  C07D317/22 ,  C08G18/283 ,  C08G18/678 ,  C08G18/8116

摘要： The present invention provides compounds having in their molecule a structure contributing to high hydrophilicity, and having high photopolymerizability, as well as polymers of such compounds, and a method for producing the compound. The compounds are diol (meth)acrylate having a urethane bond represented by the formula (1), and cyclic ketal (meth)acrylate having a urethane bond represented by the formula (2): (R1: H, —CH3; R2: —(CH2)n-; R3: —(CH2)m-; n: 1-4; m: 1-8; (AO): C2-C4 oxyalkylene group; x: 0-1000; R4, R5: H, —CH3, —C2H5).

公开(公告)号：US20100081779A1

公开(公告)日：2010-04-01

申请号：US12631049

申请日：2009-12-04

申请人： Eui-chul Kang ,  Atsuhiko Ogura ,  Shingo Kataoka ,  Takashi Iwata

发明人： Eui-chul Kang ,  Atsuhiko Ogura ,  Shingo Kataoka ,  Takashi Iwata

IPC分类号： C08F24/00

CPC分类号： C07C271/16 ,  C07D317/22 ,  C08G18/283 ,  C08G18/678 ,  C08G18/8116

摘要： The present invention provides compounds having in their molecule a structure contributing to high hydrophilicity, and having high photopolymerizability, as well as polymers of such compounds, and a method for producing the compound. The compounds are diol (meth)acrylate having a urethane bond represented by the formula (1), and cyclic ketal (meth)acrylate having a urethane bond represented by the formula (2): (R1: H, —CH3; R2: —(CH2)n—; R3: —(CH2)m—; n: 1-4; m: 1-8; (AO): C2-C4 oxyalkylene group; x: 0-1000; R4, R5: H, —CH3, —C2H5).

摘要翻译： 本发明提供了在其分子中具有有助于高亲水性和高光聚合性的结构的化合物，以及这些化合物的聚合物，以及该化合物的制备方法。 化合物是具有由式（1）表示的氨基甲酸酯键的二醇（甲基）丙烯酸酯和具有由式（2）表示的氨基甲酸酯键的环状缩酮（甲基）丙烯酸酯：（R1：H，-CH3; R2： - （CH2）n-; R3： - （CH2）m-; n：1-4; m：1-8;（AO）：C2-C4氧化烯基; x：0-1000; R4，R5：H， CH3，-C2H5）。