公开(公告)号：US4849514A

公开(公告)日：1989-07-18

申请号：US164769

申请日：1988-03-07

Applicant: Everett E. Gilbert

Inventor： Everett E. Gilbert

IPC: C06B25/18 ,  C06B43/00 ,  C08B15/06

CPC classification number: C08B15/06 ,  C06B25/18 ,  C06B43/00

Abstract: This invention is an improved process of making azidodeoxycellulose a hig energetic ingredient for use in a propellant. The process is accomplished by nitrating cellulose to nitrocellulose, converting the nitrocellulose in sequence to the iodine derivative, and finally reacting the iodine derivative of cellulose with sodium azide to produce azidodeoxycellulose having up to about 1.5% residual nitrogen as nitrate groups.

Abstract translation: 本发明是制备叠氮基脱氧纤维素是用于推进剂的高能成分的改进方法。 该过程通过将纤维素硝化成硝化纤维素，将硝化纤维素依次转化成碘衍生物，最后使纤维素的碘衍生物与叠氮化钠反应，生成具有高达约1.5％残留氮作为硝酸根的叠氮化物纤维素。

公开(公告)号：USH106H

公开(公告)日：1986-08-05

申请号：US767994

申请日：1985-08-21

Applicant: Everett E. Gilbert

Inventor： Everett E. Gilbert

IPC: C06B25/04 ,  C06B31/38 ,  C07C309/24

CPC classification number: C06B25/04 ,  C06B31/38 ,  C07C309/24

Abstract: Novel energetic sulfate salts which form a eutectic with ammonium nitrate ntaining explosive formulations are disclosed. The eutectic quality of such formulations facilitates melt loading thereof. Two typical novel sulfate salts of the invention are 1-(2-ammonium sulfatoethyl)-2,4,6-trinitrobenzene and 1,3-Bis-2(2-ammonium sulfoethyl)-2,4,6-trinitrobenzene. Also disclosed is a method for the synthesis of such sulfate salts together also with a method for the synthesis of the necessary alkanol substituted trinitrobenzene derivative precursor.

公开(公告)号：US3941812A

公开(公告)日：1976-03-02

申请号：US566848

申请日：1975-04-10

Applicant: Everett E. Gilbert

Inventor： Everett E. Gilbert

IPC: C07D323/00

CPC classification number: C07D323/00

Abstract: Novel compounds are provided having the formula ##SPC1##Wherein R is hydrogen or lower n-alkyl and the ether oxygen atoms are attached in the 1,3 or 1,4 positions to the R substituted benzene rings, R being in the 2 or 5 positions when the ether oxygen atoms are in the 1,3 positions and R is lower n-alkyl.These compounds are useful as explosives characterized by good thermal stability.

Abstract translation: 提供新的化合物，其具有式WHEREIN R是氢或低级正烷基，并且醚氧原子在1,3或1,4位连接到R取代的苯环上，R为2或5位，当 醚氧原子在1,3位，R是低级正烷基。

公开(公告)号：US3939148A

公开(公告)日：1976-02-17

申请号：US445738

申请日：1974-02-25

Applicant: Victor I. Siele ,  Everett E. Gilbert

Inventor： Victor I. Siele ,  Everett E. Gilbert

IPC: C07D257/02

CPC classification number: C07D257/02

Abstract: 1,3,5,7-TETRANITRO-1,3,5,7-TETRAAZACYLOOCTANE IS PREPARED BY NITROLYSIS OF A 1,3,5,7-TETRAACYL-1,3,5,7-TETRAAZACYLOOCTANE OR A 1,5-DIACYL-3,7-DINITRO11,3,5,7-TETRAAZACYCLOOCATNE WITH NITROGEN PENTOXIDE.

Abstract translation: 1,3,5,7-四脱硝基-1,3,5,7-四氢环己烷通过1,3,5,7-四氢-1,3,5,7-四脱氧山梨糖醇或1,5- DIACYL-3,7-DINITRO11,3,5,7-四氮杂环戊二烯与氮氧化物。

公开(公告)号：USH138H

公开(公告)日：1986-10-07

申请号：US655609

申请日：1984-09-28

Applicant: Everett E. Gilbert

Inventor： Everett E. Gilbert

IPC: C06B43/00 ,  C07C247/10

CPC classification number: C07C247/10 ,  C06B43/00

Abstract: Poly(azidomethyl)benzenes having the formulaC.sub.6 H.sub.6-N (CH.sub.2 N.sub.3).sub.Nwherein n represents 3 to 6 inclusive. These compounds are for use as novelxplosives.

公开(公告)号：US4270012A

公开(公告)日：1981-05-26

申请号：US112585

申请日：1980-01-16

Applicant: Everett E. Gilbert

Inventor： Everett E. Gilbert

IPC: C07C205/06 ,  C07C79/10

CPC classification number: C07C201/12

Abstract: A process for preparing 2,2',4,4',6,6'-hexanitrostilbene in high yields byeacting 2,2',4,4',6,6'-hexanitrobibenzyl in a suitable solvent with an oxygen-containing gas in the presence of a catalyst. The catalyst is selected from the group consisting of copper ammino and cobalt ammino compounds, copper and cobalt acetates, copper and cobalt halides, copper sulfate, and ammonium and alkali metal bases.

Abstract translation: 一种通过使2,2'，4,4'，6,6'-六硝基苄基在合适的溶剂中与含氧的反应生成2,2'，4,4'，6,6'-己腈二茋的方法， 气体在催化剂存在下。 催化剂选自氨基磺酸铜和氨基钴化合物，铜和钴酸乙酯，铜和钴卤化物，硫酸铜和铵和碱金属碱。

公开(公告)号：US4245129A

公开(公告)日：1981-01-13

申请号：US66599

申请日：1979-08-14

Applicant: Everett E. Gilbert

Inventor： Everett E. Gilbert

IPC: C07C205/06 ,  C07C79/10

CPC classification number: C07C201/12

Abstract: 2,2',4,4',6,6'-hexanitrobibenzyl, an intermediate compound used for makingexanitrostilbene, is prepared by adding an aqueous alkaline metal hypochlorite solution containing an alkaline metal hydroxide to trinitrotoluene dispersed in a single solvent selected from the group consisting of methanol, ethanol, 2-methoxyethanol, isopropanol, acetone, tetrahydrofuran, N,N-dimethylformamide, N,N-dimethylacetamide, pyridine and N-methyl pyrrolidinone. The compound is then separated from the reaction mixture.

Abstract translation: 2,2'，4,4'，6,6'-六硝基苄基，用于制备己腈二苯乙烯的中间体化合物是通过将含有碱金属氢氧化物的碱金属氢氧化亚铜溶液加入分散于选自以下的一种溶剂的单一溶剂中的三硝基甲苯来制备的： 由甲醇，乙醇，2-甲氧基乙醇，异丙醇，丙酮，四氢呋喃，N，N-二甲基甲酰胺，N，N-二甲基乙酰胺，吡啶和N-甲基吡咯烷酮组成的组。 然后将化合物与反应混合物分离。

公开(公告)号：US4221745A

公开(公告)日：1980-09-09

申请号：US20881

申请日：1979-03-15

Applicant: Everett E. Gilbert

Inventor： Everett E. Gilbert

IPC: C07C201/12 ,  C07C205/06 ,  C07C79/10

CPC classification number: C07C201/12

Abstract: There is disclosed a process for converting 2,2', 4,4', 6,6'-hexanitrobibyl (HNBB) to 2,2', 4,4', 6,6'-hexanitrostilbene (HNS) by reacting HNBB with a copper ammino compound in a solvent. The HNS product can be produced in yields of greater than 65%.

Abstract translation: 公开了将HNBB与HNBB反应的方法，将2,2'，4,4'，6,6'-六硝基苄基（HNBB）转化为2,2'，4,4'，6,6'-己二芪（HNS） 在溶剂中的铜氨基化合物。 HNS产品的产量可以大于65％。

公开(公告)号：US4843121A

公开(公告)日：1989-06-27

申请号：US747744

申请日：1985-06-24

Applicant: Everett E. Gilbert

Inventor： Everett E. Gilbert

IPC: C08F8/30

CPC classification number: C08F8/30

Abstract: Polyvinylazidonitrate and a process of making the same by reacting polyvinitrate with sodium or lithium azide in selected solvents.

Abstract translation: 聚乙烯亚氨基硝酸盐及其制备方法通过使聚乙烯基硝酸盐与选择的溶剂中的叠氮化钠或叠氮化钠反应。

公开(公告)号：US4839420A

公开(公告)日：1989-06-13

申请号：US600869

申请日：1984-04-16

Applicant: Everett E. Gilbert

Inventor： Everett E. Gilbert

IPC: C08F8/30

CPC classification number: C08F8/30

Abstract: Polyvinylazidonitrate and a process of making the same by reacting polyvinitrate with sodium or lithium azide in selected solvents.

Abstract translation: 聚乙烯亚氨基硝酸盐及其制备方法通过使聚乙烯基硝酸盐与选择的溶剂中的叠氮化钠或叠氮化钠反应。