公开(公告)号：US20190233445A1

公开(公告)日：2019-08-01

申请号：US16381091

申请日：2019-04-11

申请人： Evonik Degussa GmbH

发明人： Philipp Albert ,  Eckhard Just

IPC分类号： C07F7/18 ,  B01J31/22

摘要： A process can prepare an isocyanurate compound by hydrosilylation. The compound is a tris[3-(trialkoxysilyl)propyl] isocyanurate, a tris[3-(alkyldialkoxysilyl)propyl] isocyanurate, and/or a tris[3-(dialkylalkoxysilyl)propyl] isocyanurate, The process includes (A) preparing a mixture of at least one carboxylic acid, a platinum catalyst, and 1,3,5-triallyl-1,3,5-triazine-2,4,6(1H,3H,5H)-trione; (B) heating the mixture to a temperature in the range of 40 to 140° C.; (C) adding at least one H-silane among a hydrotrialkoxysilane, a hydroalkyldialkoxysilane, and a hydrodialkylalkoxysilane to the mixture; (D) adding at least one alcohol to the mixture prepared in step (C); and (E) isolating the isocyanurate compound.

公开(公告)号：US20190153238A1

公开(公告)日：2019-05-23

申请号：US16251303

申请日：2019-01-18

申请人： Evonik Degussa GmbH

发明人： Philipp Albert ,  Eckhard Just

IPC分类号： C09D5/08 ,  C23C18/12 ,  C23C22/68 ,  C09D4/00 ,  C23C22/50 ,  C23C22/48 ,  C09D5/10

摘要： The present invention relates to a composition comprising—a specific binder containing at least one cocondensate based on at least one ω-glycidyloxyalkylalkoxysilane and a bis(alkoxyalkylsilyl)amine, —water, —alcohol in an amount of less than 3% by weight, based on the composition, —at least one addition selected from the group consisting of particulate metals, metal alloys and metal compounds and —optionally at least one additive, where the pH of the composition is from 1 to 14 and the dry residue of the binder is from 1 to 50% by weight, based on the binder used, a process for the production thereof and also the use thereof for coatings, in particular for the protection of metals against corrosion.

公开(公告)号：US20200010491A1

公开(公告)日：2020-01-09

申请号：US16458632

申请日：2019-07-01

申请人： Evonik Degussa GmbH

发明人： Philipp Albert ,  Eckhard Just

IPC分类号： C07F7/18 ,  B01J31/28

摘要： A process produces a C3- to C20-alkyltrialkoxysilane by hydrosilylation, wherein alkoxy represents methoxy, ethoxy or propoxy. Initially, a mixture is charged of at least one hydroalkoxysilane from the group of hydrotrialkoxysilane, hydroalkyldialkoxysilane, and hydrodialkylalkoxysilane, and a Pt catalyst. The mixture is then heated to a temperature of 30° C. to 60° C. Subsequently, with mixing, an omega-unsaturated or mono-unsaturated C3- to C20-hydrocarbon, at least one carboxylic acid and at least one alcohol as cocatalysts are added to the mixture. The mixture is then reacted and subsequently worked up to obtain the product.

公开(公告)号：US10125156B2

公开(公告)日：2018-11-13

申请号：US15915126

申请日：2018-03-08

申请人： Evonik Degussa GmbH

发明人： Philipp Albert ,  Eckhard Just

IPC分类号： C07D251/30 ,  C07F7/18

摘要： The present invention relates to a process for preparing a tris[3-(alkoxysilyl)propyl] isocyanurate from the group of tris[3-(trialkoxysilyl)propyl] isocyanurate, tris[3-(alkyldialkoxysilyl)propyl] isocyanurate and tris[3-(dialkylalkoxysilyl)propyl] isocyanurate by hydrosilylation,by in step A initially charging a mixture comprising 1,3,5-triallyl-1,3,5-triazine-2,4,6(1H,3H,5H)-trione as olefin component, at least one carboxylic acid and a Pt catalyst, heating the mixture to a temperature of 50 to 140° C., in step B adding at least one hydroalkoxysilane from the group of hydrotrialkoxysilane, hydroalkyldialkoxysilane, hydrodialkylalkoxysilane [called H-silane(s) for short] to the mixture from step A while mixing, in step C leaving the mixture from step B to react while mixing, with addition of at least a defined amount of alcohol to the mixture as further cocatalyst, and in step D working up the product mixture thus obtained.

公开(公告)号：US10377776B2

公开(公告)日：2019-08-13

申请号：US16159763

申请日：2018-10-15

申请人： Evonik Degussa GmbH

发明人： Philipp Albert ,  Eckhard Just

IPC分类号： C07D251/30 ,  C07F7/18 ,  B01J31/22

摘要： A process can prepare an isocyanurate compound by hydrosilylation. The compound is a tris[3-(trialkoxysilyl)propyl] isocyanurate, a tris[3-(alkyldialkoxysilyl)propyl] isocyanurate, and/or a tris[3-(dialkylalkoxysilyl)propyl] isocyanurate. The process includes (A) preparing a mixture of at least one carboxylic acid, a platinum catalyst, and 1,3,5-triallyl-1,3,5-triazine-2,4,6(1H,3H,5H)-trione; (B) heating the mixture to a temperature in the range of 40 to 140° C.; (C) adding at least one H-silane among a hydrotrialkoxysilane, a hydroalkyldialkoxysilane, and a hydrodialkylalkoxysilane to the mixture; (D) adding at least one alcohol to the mixture prepared in step (C); and (E) isolating the isocyanurate compound.

公开(公告)号：US10364260B2

公开(公告)日：2019-07-30

申请号：US15915138

申请日：2018-03-08

申请人： Evonik Degussa GmbH

发明人： Philipp Albert ,  Eckhard Just

IPC分类号： C07D251/34 ,  C07F7/18

摘要： The present invention relates to a process for preparing a tris[3-(alkoxysilyl)propyl] isocyanurate from the group of tris-[3-(trialkoxysilyl)propyl] isocyanurate, tris[3-(alkyldialkoxysilyl)propyl] isocyanurate and tris[3-(dialkylalkoxysilyl)propyl] isocyanurate by hydrosilylation, by in step A initially charging a mixture comprising at least one hydroalkoxysilane from the group of hydrotrialkoxysilane, hydroalkyldialkoxysilane, hydrodialkylalkoxysilane [called H-silane(s) for short], at least one carboxylic acid and a Pt catalyst, heating the mixture to a temperature of 50 to 140° C., in step B adding a mixture of 1,3,5-triallyl-1,3,5-triazine-2,4,6(1H,3H,5H)-trione and at least one alcohol to the mixture from step A while mixing, in step C leaving the mixture from step B to react while mixing and in step D working up the product mixture thus obtained.

公开(公告)号：US10266655B2

公开(公告)日：2019-04-23

申请号：US15530148

申请日：2016-12-08

申请人： Evonik Degussa GmbH

发明人： Philipp Albert ,  Julia Kirberg ,  Jennifer Schrantz ,  Eckhard Just

IPC分类号： C08G77/18 ,  C09D163/00 ,  C08L83/04 ,  C08L83/06 ,  C08L63/00 ,  C08G77/04 ,  C08G77/14 ,  C08G77/16 ,  C09D7/65

摘要： The present invention relates to a composition comprising water and a mixture of [3-(2,3-dihydroxyprop-1-oxy)propyl]silanol oligomers and ethers thereof, wherein the proportion of epoxy groups bound within Si compounds which may be present in the composition is not more than 0.05 mol of epoxy groups per mole of Si in the composition.The invention further relates to a particular process for preparing a composition according to the invention and to the use thereof.

公开(公告)号：US20180258110A1

公开(公告)日：2018-09-13

申请号：US15915138

申请日：2018-03-08

申请人： Evonik Degussa GmbH

发明人： Philipp Albert ,  Eckhard Just

IPC分类号： C07F7/18

CPC分类号： C07F7/1804 ,  C07F7/18 ,  C07F7/1876 ,  Y02P20/588

摘要： The present invention relates to a process for preparing a tris[3-(alkoxysilyl)propyl] isocyanurate from the group of tris-[3-(trialkoxysilyl)propyl] isocyanurate, tris[3-(alkyldialkoxysilyl)propyl] isocyanurate and tris[3-(dialkylalkoxysilyl)propyl] isocyanurate by hydrosilylation, by in step A initially charging a mixture comprising at least one hydroalkoxysilane from the group of hydrotrialkoxysilane, hydroalkyldialkoxysilane, hydrodialkylalkoxysilane [called H-silane(s) for short], at least one carboxylic acid and a Pt catalyst, heating the mixture to a temperature of 50 to 140° C., in step B adding a mixture of 1,3,5-triallyl-1,3,5-triazine-2,4,6(1H,3H,5H)-trione and at least one alcohol to the mixture from step A while mixing, in step C leaving the mixture from step B to react while mixing and in step D working up the product mixture thus obtained.

公开(公告)号：US20180258109A1

公开(公告)日：2018-09-13

申请号：US15915126

申请日：2018-03-08

申请人： Evonik Degussa GmbH

发明人： Philipp Albert ,  Eckhard Just

IPC分类号： C07F7/18

CPC分类号： C07F7/1804 ,  C07F7/18 ,  C07F7/1876

摘要： The present invention relates to a process for preparing a tris[3-(alkoxysilyl)propyl] isocyanurate from the group of tris[3-(trialkoxysilyl)propyl] isocyanurate, tris[3-(alkyldialkoxysilyl)propyl] isocyanurate and tris[3-(dialkylalkoxysilyl)propyl] isocyanurate by hydrosilylation,by in step A initially charging a mixture comprising 1,3,5-triallyl-1,3,5-triazine-2,4,6(1H,3H,5H)-trione as olefin component, at least one carboxylic acid and a Pt catalyst, heating the mixture to a temperature of 50 to 140° C., in step B adding at least one hydroalkoxysilane from the group of hydrotrialkoxysilane, hydroalkyldialkoxysilane, hydrodialkylalkoxysilane [called H-silane(s) for short] to the mixture from step A while mixing, in step C leaving the mixture from step B to react while mixing, with addition of at least a defined amount of alcohol to the mixture as further cocatalyst, and in step D working up the product mixture thus obtained.

公开(公告)号：US09951091B2

公开(公告)日：2018-04-24

申请号：US15658074

申请日：2017-07-24

申请人： Evonik Degussa GmbH

发明人： Philipp Albert ,  Eckhard Just

IPC分类号： C07D251/34 ,  C07F7/18

CPC分类号： C07F7/1876 ,  C07D251/34 ,  C07F7/1804

摘要： A tris[3-(alkoxysilyl)propyl] isocyanurate from the group of tris[3-(trialkoxysilyl)propyl] isocyanurate, tris[3-(alkyldialkoxysilyl)propyl] isocyanurate and tris[3-(dialkylalkoxysilyl)propyl] isocyanurate is prepared by hydrosilylation, by a) initially charging a mixture of at least one hydroalkoxysilane from the group of hydrotrialkoxysilane, hydroalkyldialkoxysilane, hydrodialkylalkoxysilane [called H-silane(s) for short] and a Pt catalyst, b) heating the mixture to a temperature of 40 to 170° C., c) then adding or metering in 1,3,5-triallyl-1,3,5-triazine-2,4,6(1H,3H,5H)-trione, at least one carboxylic acid and at least one alcohol as cocatalyst while mixing, and d) leaving the mixture to react and then working up the product mixture thus obtained.