-
公开(公告)号:US11142591B2
公开(公告)日:2021-10-12
申请号:US16471272
申请日:2017-09-07
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: John R. Hagadorn , Charles J. Harlan , Richard B. Pannell , Chi-I Kuo
IPC: C08F210/16 , C08F2/34 , C08F2/38
Abstract: A process including contacting one or more monomers, at least one catalyst system, and a condensing agent including ≥10 mol % tetramethylsilane under polymerizable conditions to produce a polyolefin polymer is provided.
-
公开(公告)号:US20210179743A1
公开(公告)日:2021-06-17
申请号:US17088286
申请日:2020-11-03
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: Brian R. Berg , Chelsey M. Broussard , Chi-I Kuo , Porter C. Shannon
IPC: C08F4/659 , C08F10/02 , C08F2/34 , C08F4/6592
Abstract: The present disclosure relates to processes for producing a catalyst composition. A process may include mixing a catalyst compound having a transition metal atom, an activator, and a support to form a supported catalyst mixture. A process may also include drying the supported catalyst mixture at a pressure of about 10 kPa or less and a temperature of about 60° C. or greater for a period of about 6 h or less. The present disclosure also relates to processes for producing polyolefins. A process may include introducing a catalyst composition and at least one olefin to a polymerization reactor, where the catalyst composition has about 0.5 wt % to about 1.5 wt % aromatic hydrocarbon content, and less than 1 wt % of aliphatic hydrocarbon content. A process may also include obtaining a polyolefin having about 300 ppb or less aromatic hydrocarbon.
-
公开(公告)号:US20180273655A1
公开(公告)日:2018-09-27
申请号:US15907767
申请日:2018-02-28
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: Chi-I Kuo
CPC classification number: C08F10/14 , C08F4/65912 , C08F4/65925 , C08F4/65927 , C08F10/00 , C08F10/02 , C08F10/06 , C08F10/08 , C08F2410/01 , C08F2420/02 , C08F4/65916
Abstract: Methods for preparing a catalyst system that includes contacting at least one aromatic hydrocarbon, at least one activator, at least one catalyst having a Group 3 through Group 12 metal atom or lanthanide metal atom, and at least one catalyst support to form a first mixture, are provided. Methods include reducing the amount of the aromatic hydrocarbon in the first mixture to form a second mixture having 1.5 wt % or less of the aromatic hydrocarbon based on the total weight of the second mixture. Methods may further include adding a saturated hydrocarbon to the second mixture to form a third mixture.
-
4.
公开(公告)号:US11591417B2
公开(公告)日:2023-02-28
申请号:US16761559
申请日:2018-10-26
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: Chi-I Kuo , Bruce J. Savatsky , Micah A. McClure , Kevin M. Ferreira , Charles J. Harlan , Valerie H. Markham
Abstract: Provided herein are methods and systems for at least partially deactivating at least one component of a reactor effluent from gas phase polyolefin polymerization processes utilizing at least one glycol.
-
公开(公告)号:US20210155723A1
公开(公告)日:2021-05-27
申请号:US17078691
申请日:2020-10-23
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: Brian R. Berg , Handel D. Bennett , Chi-I Kuo , Robert L. Griffin , Chelsey M. Broussard , Bruce J. Savatsky
Abstract: A method of producing a supported catalyst includes introducing a dissolved catalyst solution into a catalyst mix vessel, and after introducing the dissolved catalyst solution into the catalyst mix vessel, introducing a porous support material into the catalyst mix vessel. The catalyst mix vessel is then operated to contact the dissolved catalyst solution on the porous support material and thereby generate the supported catalyst, and the supported catalyst is discharged from the catalyst mix vessel.
-
公开(公告)号:US20180334517A1
公开(公告)日:2018-11-22
申请号:US15950543
申请日:2018-04-11
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: Xuan Ye , Lubin Luo , Charles J. Harlan , Chi-I Kuo , Richard B. Pannell , William A. Lamberti
IPC: C08F210/16
CPC classification number: C08F210/16 , C08F4/65912 , C08F4/65916 , C08F210/14 , C08F2500/18 , C08F2500/24 , C08F4/65927
Abstract: Catalyst systems including a catalyst compound having a Group 3 through Group 12 metal atom or lanthanide metal atom, an activator, and a support material composition, are provided. The support material composition may have a volume percent of pores with a pore size of from 300 angstroms to 1500 angstroms of 10 vol % to 80 vol %. Processes for producing a polyolefin composition utilizing such catalyst systems are also provided.
-
公开(公告)号:US11618791B2
公开(公告)日:2023-04-04
申请号:US17078691
申请日:2020-10-23
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: Brian R. Berg , Handel D. Bennett , Chi-I Kuo , Robert L. Griffin , Chelsey M. Broussard , Bruce J. Savatsky
Abstract: A method of producing a supported catalyst includes introducing a dissolved catalyst solution into a catalyst mix vessel, and after introducing the dissolved catalyst solution into the catalyst mix vessel, introducing a porous support material into the catalyst mix vessel. The catalyst mix vessel is then operated to contact the dissolved catalyst solution on the porous support material and thereby generate the supported catalyst, and the supported catalyst is discharged from the catalyst mix vessel.
-
公开(公告)号:US11492428B2
公开(公告)日:2022-11-08
申请号:US16449257
申请日:2019-06-21
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: Xuan Ye , Jonathan J. Schaefer , Timothy M. Boller , Christopher S. Breiner , Chi-I Kuo , Kevin A. Stevens , Logan E. Shephard , Eyerusalem H. Mamo , Evan J. Morris , Shamah Lloyd
IPC: C08F210/16 , C08F4/659 , C08L23/06 , C08F2/34 , C08F4/6192 , C08F4/622 , C08K3/36
Abstract: Methods to produce heterogeneous polyethylene granules, the method including: contacting first olefin monomers and second olefin monomers with a catalyst system in a single reaction zone to produce heterogeneous polyethylene granules and recovering the heterogeneous polyethylene granules; wherein the catalyst system includes a product of a combination including: one or more catalysts having a Group 3 through Group 12 metal atom or lanthanide metal atom; at least one activator; and optionally, one or more support material compositions; and wherein the heterogeneous polyethylene granules include a product of a combination of: a first portion comprising a first polyethylene including the first olefin monomers and the second olefin monomers; a second portion including a second polyethylene including the first monomers and the second monomers; and wherein the first polyethylene has a higher second monomer weight percent than the second polyethylene, are provided.
-
公开(公告)号:US20200071438A1
公开(公告)日:2020-03-05
申请号:US16492996
申请日:2018-02-28
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: Corrine L. Brandl , Fred D. Ehrman , Edward F. Smith , Chi-I Kuo
IPC: C08F210/16
Abstract: A process for preparing a catalyst system including contacting one or more catalysts having a Group 3 through Group 12 metal atom or lanthanide metal atom with a methylalumoxane and one or more support material compositions to a concentration of methylalumoxane of about 4 mmol to about 15 mmol aluminum per gram of support material is provided. The support material composition may have a macroporosity of from about 0.18 cc/g to about 0.50 cc/g. In other embodiments, a process for polymerizing at least one olefin to produce a polyolefin composition including contacting one or more olefins with the aforementioned catalyst system is also provide.
-
公开(公告)号:US11015001B2
公开(公告)日:2021-05-25
申请号:US15950543
申请日:2018-04-11
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: Xuan Ye , Lubin Luo , Charles J. Harlan , Chi-I Kuo , Richard B. Pannell , William A. Lamberti
IPC: C08F210/16 , C08F4/659
Abstract: Catalyst systems including a catalyst compound having a Group 3 through Group 12 metal atom or lanthanide metal atom, an activator, and a support material composition, are provided. The support material composition may have a volume percent of pores with a pore size of from 300 angstroms to 1500 angstroms of 10 vol % to 80 vol %. Processes for producing a polyolefin composition utilizing such catalyst systems are also provided.
-
-
-
-
-
-
-
-
-