公开(公告)号：US20160115113A1

公开(公告)日：2016-04-28

申请号：US14877545

申请日：2015-10-07

Applicant: ExxonMobil Chemical Patents Inc.

Inventor： Mika Shiramizu ,  James R. Lattner ,  Kapil Kandel

IPC: C07C67/03 ,  C07C37/52

CPC classification number: C07C29/46 ,  C07C45/69 ,  C07C67/39 ,  C07C67/40 ,  C07C69/82 ,  C07C47/56 ,  C07C33/26

Abstract: This invention relates to a dimethylterephthalate production process comprising reacting substituted furan with ethylene under cycloaddition reaction conditions and in the presence of a cycloaddition catalyst to produce a bicyclic ether, dehydrating the bicyclic ether to produce a substituted phenyl, dissolving said substituted phenyl in methanol, and oxidizing and esterifying the substituted phenyl in the presence of an oxidative esterification catalyst to form dimethylterephthalate. Importantly, the process does not include oxidizing the substituted phenyl to form terephthalic acid.

Abstract translation: 本发明涉及对苯二甲酸二甲酯生产方法，其包括在环加成反应条件下和在环加成催化剂存在下使取代的呋喃与乙烯反应以产生双环醚，使双环醚脱水以产生取代的苯基，将所述取代的苯基溶解在甲醇中， 在氧化酯化催化剂的存在下氧化和酯化取代的苯基以形成对苯二甲酸二甲酯。 重要的是，该方法不包括氧化取代的苯基以形成对苯二甲酸。