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公开(公告)号:US20240392197A1
公开(公告)日:2024-11-28
申请号:US18691105
申请日:2022-10-03
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: Mark A. Nierode , Rodney S. Smith , Michael A. Radzicki , Donald J. Norris , Kapil Kandel , Tania M. Almazan
Abstract: Processes for upgrading a hydrocarbon for a predetermined period of time. The process can include determining an amount of one or more contaminant-containing compositions that will be present in a pyrolysis effluent based, at least in part, on a composition of a hydrocarbon feed to be steam cracked, a. temperature the hydrocarbon feed will be heated at during steam cracking, a residence time the hydrocarbon feed will be heated at the temperature during steam cracking, or a combination thereof. In some examples, the process can also include taking one or more steps to allow the hydrocarbon feed to be steam cracked for at least as long as a predetermined, period of time, such as controlling process conditions within one or more separation stages to favor certain product compositions and/or introducing a predetermined amount of one or more materials into various locations of the process, or any combination thereof.
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公开(公告)号:US11926605B2
公开(公告)日:2024-03-12
申请号:US16978496
申请日:2019-02-11
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: Kapil Kandel , Stephen T. Cohn , Michael Salciccioli , Crisita Carmen H. Atienza , Alan A. Galuska
IPC: C07D307/36 , C07D307/54 , C08G63/185
CPC classification number: C07D307/36 , C07D307/54 , C08G63/185
Abstract: A 5,5′-Di-(protected)-2,2′-bifuran:
wherein each R1 is independently an unsubstituted or substituted 5- or 6-member 1,3-dioxo-2-yl ring radical. Processes for making the bifuran include coupling 2-(protected)-furfural. Processes for using the bifuran include deprotection, functionalization, and/or polymerization to form a polyester. The polyester can be a renewable, high-performing polyester offering a combination of low cost of production, high sustainability, and excellent performance.-
公开(公告)号:US20220033720A1
公开(公告)日:2022-02-03
申请号:US17298972
申请日:2019-12-11
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: John S. Coleman , Kapil Kandel , Michael J. Clemmons , Teng Xu , Giovanni S. Contello
Abstract: Processes for preparing a low particulate liquid hydrocarbon product are provided and includes blending a tar stream containing particles with a fluid to produce a fluid-feed mixture containing tar, the particles, and the fluid, and centrifuging the fluid-feed mixture at a temperature of greater than 60° C. to produce a higher density portion and a lower density portion, where the lower density portion contains no more than 25 wt % of the particles in the fluid-feed mixture.
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公开(公告)号:US11162037B2
公开(公告)日:2021-11-02
申请号:US16467790
申请日:2017-12-01
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: Krystle J. Emanuele , Kapil Kandel , Glenn A. Heeter , Jeffrey C. Yeh , Teng Xu
Abstract: This invention relates to a process for determining the suitability of pyrolysis tar, such as steam cracker tar, for upgrading using hydroprocessing without excessive fouling of the hydroprocessing reactor. The invention includes establishing a reference activity for the thermally treating the pyrolysis tar to produce a treated tar having a lesser reactivity.
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公开(公告)号:US10159959B2
公开(公告)日:2018-12-25
申请号:US15905282
申请日:2018-02-26
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: Kapil Kandel , Paul F. Keusenkothen , Jeevan S. Abichandani
IPC: C07C29/50 , C07C29/153 , C10G2/00 , B01J23/745 , B01J23/72 , B01J37/02 , B01J37/00 , B01J37/06 , B01J23/89 , B01J23/80 , B01J23/00 , B01J23/889 , B01J37/08 , B01J35/10 , B01J37/16 , B01J29/03 , B01J21/08
Abstract: The invention relates to templated active material, including those deriving order from organic and/or inorganic templating agents. The invention also relates to methods for producing templated active material, and to active material produced by such methods, and the use of such templated active material for producing oxygenate.
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公开(公告)号:US20180334622A1
公开(公告)日:2018-11-22
申请号:US15971590
申请日:2018-05-04
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: Gaurav Agrawal , Stephen T. Cohn , Kapil Kandel , Subramanya V. Nayak , Teng Xu
IPC: C10G47/04
CPC classification number: C10G47/04 , C10G9/36 , C10G45/38 , C10G47/00 , C10G65/04 , C10G65/12 , C10G2300/301 , C10G2400/04
Abstract: A hydrocarbon conversion process comprises providing a hydrocarbon feedstock comprising an effluent fraction from a pyrolysis process, wherein the effluent fraction has an initial boiling point at atmospheric pressure of at least 177° C. and a final boiling point at atmospheric pressure of no more than 343° C. and comprises at least 0.5 wt. % of olefinic hydrogen atoms based on the total weight of hydrogen atoms in the effluent fraction. The hydrocarbon feedstock is hydroprocessed in at least one hydroprocessing zone in the presence of treatment gas comprising molecular hydrogen under catalytic hydroprocessing conditions to produce a hydroprocessed product comprising less than 0.5 wt. % of olefinic hydrogen atoms based on the total weight of hydrogen atoms in the hydroprocessed product. The hydroprocessing conditions comprise a temperature from 150 to 350° C. and a pressure from 500 to 1500 psig (3550 to 10445 kPa-a).
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公开(公告)号:US11970573B2
公开(公告)日:2024-04-30
申请号:US17227662
申请日:2019-11-13
Inventor: Monica Lotz , S. Richard Turner , Hans Eliot Edling , Kapil Kandel , Michael Salciccioli , Stephen Cohn , Alan A. Galuska , Javier Guzman , Edward E. Paschke
IPC: C08G63/193 , C08G63/80 , C08G63/85
CPC classification number: C08G63/193 , C08G63/80 , C08G63/85 , C08G2120/00
Abstract: Bifuran-modified polyester, polyethylene-terephthalate-co (2,2′-bifuran-5,5′-dicarboxylate), prepared by esterifying or transesterifying a diacid component comprising from 2 to 10 mole percent 2,2′-bifuran-5,5′-dicarboxylate and a diol component with a catalyst compound comprising metal present in an amount of from about 10 to about 450 ppm and polycondensation to form the polyester wherein the polyester has an inherent viscosity of at least 0.5 g/dL, a glass transition temperature (Tg) of 82° C. or more, a semicrystalline melting peak (Tm) with ΔHf equal to or greater than 5 J/g on the second heating ramp, and melting temperature (Tm) between 229° C. and 246° C. Reinforced compositions and shaped articles comprising bifuran-modified polyethylene terephthalate and methods of their production are also disclosed.
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公开(公告)号:US11530361B2
公开(公告)日:2022-12-20
申请号:US17495948
申请日:2021-10-07
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: Kapil Kandel , Glenn A. Heeter , Teng Xu , Giovanni S. Contello , Krystle J. Emanuele
Abstract: This invention relates to a process for determining the suitability of pyrolysis tar, such as steam cracker tar, for upgrading using hydroprocessing without excessive fouling of the hydroprocessing reactor. A pyrolysis tar is sampled, the sample is analyzed to determine one or more characteristics of the tar related to tar reactivity, and the analysis is used to determine conditions under which the tar can be blended, pre-treated, and/or hydroprocessed.
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公开(公告)号:US20220204866A1
公开(公告)日:2022-06-30
申请号:US17610615
申请日:2020-05-15
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: John J. Monson , Kendele S. Galvan , Kapil Kandel
Abstract: Processes and apparatus for preparing a liquid hydrocarbon product are provided. In one embodiment, a process for prepreparing a liquid hydrocarbon product includes thermally-treating a tar to produce a first tar composition and blending the tar composition with a utility fluid to form a tar-fluid mixture. The process includes separating the tar-fluid mixture to form a first lower-density portion and a first higher-density portion containing solids. The process further includes thermally-treating the first higher-density portion to form a thermally-treated first higher-density portion to convert at least a portion of the solids to liquid.
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公开(公告)号:US11286428B2
公开(公告)日:2022-03-29
申请号:US17278547
申请日:2019-10-18
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: Kapil Kandel , Teng Xu , John S. Coleman , Krystle J. Emanuele , Frank Cheng-Yu Wang , Anthony S. Mennito
Abstract: Processes for preparing a low particulate liquid hydrocarbon product are provided and include blending a tar stream containing particles with a fluid and heating to a temperature of 250° C. or greater to produce a fluid-feed mixture that contains tar, the particles, and the fluid. The fluid-feed mixture contains about 20 wt % or greater of the fluid, based on a combined weight of the tar stream and the fluid. Also, about 25 wt % to about 99 wt % of the particles in the tar stream are dissolved or decomposed when producing the fluid-feed mixture.
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