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公开(公告)号:US20180250655A1
公开(公告)日:2018-09-06
申请号:US15910130
申请日:2018-03-02
Inventor: Chuansheng Bai , Majosefina Cunningham , Patrick P. McCall , Hans Thomann , Jeannine Elizabeth Elliott , Vinh Nguyen
CPC classification number: B01J20/08 , B01D53/02 , B01D2253/1124 , B01D2257/504 , B01D2258/0283 , B01J20/041 , B01J20/3007 , B01J20/3078 , B01J20/3204 , B01J20/3236 , Y02C10/08
Abstract: The disclosure generally relates to CCS sorbents, particularly for CO2/H2O displacement desorption process. The sorbents include an aluminum oxide support that includes alkali metal salts within the support, in the form of pseudo alkali aluminate. The sorbents also include alkali metal salt impregnated on the support. The sorbents demonstrate improved CO2 loadings and better H2O/CO2 ratios, as well as improved stability. Compositions and methods of making are disclosed.
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2.
公开(公告)号:US20150007725A1
公开(公告)日:2015-01-08
申请号:US14325579
申请日:2014-07-08
Inventor: Jeannine Elizabeth Elliott , Robert James Copeland , Patrick P. McCall
IPC: B01D53/06
CPC classification number: B01D53/83 , B01D53/06 , B01D53/08 , B01D53/62 , B01D2251/304 , B01D2251/306 , B01D2253/104 , B01D2258/0283 , B01D2259/4009 , Y02C10/04 , Y02C10/08
Abstract: A rotary moving bed and process for separating a carbon dioxide from a gas stream is disclosed. The rotary moving bed can have a rotational assembly rotating on a vertical axis, and a plurality of sorbent cells positioned horizontally to the axis of rotation that fills a vertical space in the moving bed, where the sorbent cells adsorb the carbon dioxide by concentration swing adsorption and adsorptive displacement. The sorbent can be regenerated and the carbon dioxide recaptured by desorbing the carbon dioxide from the sorbent using concentration swing adsorption and desorptive displacement with steam. The gas flows in the system flow in a direction horizontal to the axis of rotation and in a direction opposite the rotational movement of the sorbent cells.
Abstract translation: 公开了一种用于从气流中分离二氧化碳的旋转移动床和方法。 旋转移动床可以具有在垂直轴线上旋转的旋转组件和水平地定位在旋转轴线上的多个吸附单元,其填充移动床中的垂直空间,其中吸附单元通过浓度变化吸附吸附二氧化碳 和吸附位移。 吸附剂可以再生,并且通过使用浓度变化吸附和蒸汽的解吸位移从吸附剂中解吸二氧化碳来重新捕获二氧化碳。 气体在系统流动中沿着与旋转轴线水平的方向和与吸附剂单元的旋转运动相反的方向流动。
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公开(公告)号:US20210268474A1
公开(公告)日:2021-09-02
申请号:US17316713
申请日:2021-05-11
Inventor: Chuansheng Bai , Majosefina Cunningham , Patrick P. McCall , Hans Thomann , Jeannine Elizabeth Elliott , Vinh Nguyen
Abstract: The disclosure generally relates to CCS sorbents, particularly for CO2/H2O displacement desorption process. The sorbents include an aluminum oxide support that includes alkali metal salts within the support, in the form of pseudo alkali aluminate. The sorbents also include alkali metal salt impregnated on the support. The sorbents demonstrate improved CO2 loadings and better H2O/CO2 ratios, as well as improved stability. Compositions and methods of making are disclosed.
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公开(公告)号:US10821393B2
公开(公告)日:2020-11-03
申请号:US15234772
申请日:2016-08-11
Inventor: Jeannine Elizabeth Elliott , Robert James Copeland , Jeff Lind , Daniel P. Leta , Patrick P. McCall
Abstract: A system and method for separating and/or purification of CO2 gas from a CO2 feed stream is described. The system and method include a plurality of fixed sorbent beds, adsorption zones and desorption zones, where the sorbent beds are connected via valve and lines to create a simulated moving bed system, where the sorbent beds move from one adsorption position to another adsorption position, and then into one regeneration position to another regeneration position, and optionally back to an adsorption position. The system and method operate by concentration swing adsorption/desorption and by adsorptive/desorptive displacement.
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5.
公开(公告)号:US20200290013A1
公开(公告)日:2020-09-17
申请号:US16889657
申请日:2020-06-01
Inventor: Jeannine Elizabeth Elliott , Robert James Copeland , Margarita Dubovik , Daniel P. Leta , Patrick P. McCall , Chuansheng Bai , Bruce A. DeRites
Abstract: Compositions and methods of preparing the compositions are disclosed for sorbents and other surfaces that can adsorb and desorb carbon dioxide. A sorbent or surface can include a metal compound such as an alkali or alkaline earth compound and a support. The sorbent can be prepared by several methods, including an incipient wetness technique. The sorbents have a CO2 adsorption and desorption profile. A sorbent having high levels of a metal compound and adsorbed CO2 is disclosed.
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公开(公告)号:US11198109B2
公开(公告)日:2021-12-14
申请号:US15910159
申请日:2018-03-02
Inventor: Chuansheng Bai , Majosefina Cunningham , Patrick P. McCall , Hans Thomann , Jeannine Elizabeth Elliott , Vinh Nguyen
Abstract: The disclosure generally relates to CCS sorbents, particularly for CO2/H2O displacement desorption process. The sorbents include an aluminum oxide support that includes two alkali metal salts impregnated on the support. The two alkali metals include a potassium metal salts and a second alkali metal salt which is not potassium. The second metal salt disrupts poisoning effects that degrade sorbent lifetime. The sorbents demonstrate improved CO2 loadings and better H2O/CO2 ratios, as well as improved stability. Compositions and methods of making are disclosed.
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公开(公告)号:US20180250654A1
公开(公告)日:2018-09-06
申请号:US15910257
申请日:2018-03-02
Inventor: Chuansheng Bai , Majosefina Cunningham , Patrick P. McCall , Hans Thomann , Jeannine Elizabeth Elliott , Vinh Nguyen
CPC classification number: B01J20/041 , B01D53/02 , B01D53/0462 , B01D2253/1124 , B01D2253/25 , B01D2257/504 , B01D2259/40083 , B01D2259/4009 , B01J20/08 , B01J20/3007 , B01J20/3078 , B01J20/3204 , B01J20/3236 , B01J20/3433 , B01J20/3466
Abstract: The disclosure generally relates to CCS sorbents, particularly for CO2/H2O displacement desorption process. The sorbent includes an aluminum oxide support and an alkali metal salt impregnated on the support. The support can be prepared by creating and extruding a dough to create an extrudate, which is then drying and calcined to form the support. Calcination temperatures can be between about 120° C. and 500° C., preferably about 200° C. to about 400° C. The sorbents demonstrate improved CO2 loadings and better H2O/CO2 ratios, as well as improved stability. Compositions and methods of making are disclosed.
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公开(公告)号:US20180250653A1
公开(公告)日:2018-09-06
申请号:US15910212
申请日:2018-03-02
Inventor: Chuansheng Bai , Majosefina Cunningham , Patrick P. McCall , Hans Thomann , Jeannine Elizabeth Elliott , Vinh Nguyen
CPC classification number: B01J20/041 , B01D53/02 , B01D2253/104 , B01D2253/106 , B01D2253/1124 , B01D2253/20 , B01D2253/25 , B01D2257/504 , B01D2258/0283 , B01D2259/40086 , B01J20/08 , B01J20/103 , B01J20/22 , B01J20/3078 , B01J20/3204 , B01J20/3234 , B01J20/3433 , B01J20/3466
Abstract: The disclosure generally relates to CCS sorbents, particularly for CO2/H2O displacement desorption process. The sorbent includes an aluminum oxide support and an alkali metal salt impregnated on the support, and a silicon modification of the sorbent to reduce water uptake by the sorbent and make it more hydrophobic. The silicon modification can be an organosilyl moiety added after the initial sorbent is complete, or a silica source added to the aluminum oxide structure, typically via impregnation. The sorbents demonstrate better H2O/CO2 ratios. Compositions and methods of making are disclosed.
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公开(公告)号:US09539540B2
公开(公告)日:2017-01-10
申请号:US14325579
申请日:2014-07-08
Inventor: Jeannine Elizabeth Elliott , Robert James Copeland , Patrick P. McCall
CPC classification number: B01D53/83 , B01D53/06 , B01D53/08 , B01D53/62 , B01D2251/304 , B01D2251/306 , B01D2253/104 , B01D2258/0283 , B01D2259/4009 , Y02C10/04 , Y02C10/08
Abstract: A rotary moving bed and process for separating a carbon dioxide from a gas stream is disclosed. The rotary moving bed can have a rotational assembly rotating on a vertical axis, and a plurality of sorbent cells positioned horizontally to the axis of rotation that fills a vertical space in the moving bed, where the sorbent cells adsorb the carbon dioxide by concentration swing adsorption and adsorptive displacement. The sorbent can be regenerated and the carbon dioxide recaptured by desorbing the carbon dioxide from the sorbent using concentration swing adsorption and desorptive displacement with steam. The gas flows in the system flow in a direction horizontal to the axis of rotation and in a direction opposite the rotational movement of the sorbent cells.
Abstract translation: 公开了一种用于从气流中分离二氧化碳的旋转移动床和方法。 旋转移动床可以具有在垂直轴线上旋转的旋转组件和水平地定位在旋转轴线上的多个吸附单元,其填充移动床中的垂直空间,其中吸附单元通过浓度变化吸附吸附二氧化碳 和吸附位移。 吸附剂可以再生,并且通过使用浓度变化吸附和蒸汽的解吸位移从吸附剂中解吸二氧化碳来重新捕获二氧化碳。 气体在系统流动中沿着与旋转轴线水平的方向和与吸附剂单元的旋转运动相反的方向流动。
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公开(公告)号:US20160361680A1
公开(公告)日:2016-12-15
申请号:US15234772
申请日:2016-08-11
Inventor: Jeannine Elizabeth Elliott , Robert James Copeland , Jeff Lind , Daniel P. Leta , Patrick P. McCall
IPC: B01D53/04
Abstract: A system and method for separating and/or purification of CO2 gas from a CO2 feed stream is described. The system and method include a plurality of fixed sorbent beds, adsorption zones and desorption zones, where the sorbent beds are connected via valve and lines to create a simulated moving bed system, where the sorbent beds move from one adsorption position to another adsorption position, and then into one regeneration position to another regeneration position, and optionally back to an adsorption position. The system and method operate by concentration swing adsorption/desorption and by adsorptive/desorptive displacement.
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