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公开(公告)号：US20240001335A1
公开(公告)日：2024-01-04
申请号：US17855980
申请日：2022-07-01
发明人： Anna C. IVASHKO , Aaron W. PETERS , Preeti KAMAKOTI , Scott J. WEIGEL , Matthew T. KAPELEWSKI , Nicole M. HERB , Roxana PEREZ VELEZ , Marc H. ANTHONIS , Doron LEVIN , Tara L. REDDINGTON
CPC分类号： B01J20/226 , B01J20/28064 , B01J20/28073 , B01J20/28076 , B01J20/3085 , C07F3/02
摘要： Methods are provided for synthesizing metal-organic framework compositions using synthesis mixtures with elevated solids content and/or elevated kinematic viscosity. The methods can allow for formation of MOF-274 metal-organic framework compositions, such as EMM-67 (a mixed-metal MOF-274 metal-organic composition). More generally, the methods can allow for formation of MOF structures that include multi-ring disalicylate organic linkers using synthesis mixtures that contain a reduced or minimized amount of solvent, such as down to having substantially no solvent in the synthesis mixture.
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公开(公告)号：US20240002417A1
公开(公告)日：2024-01-04
申请号：US17856041
申请日：2022-07-01
发明人： Anna C. IVASHKO , Carter W. ABNEY , Nicole M. HERB , Preeti KAMAKOTI , Aaron W. PETERS , Matthew T. KAPELEWSKI , Marc H. ANTHONIS , Roxana PEREZ VELEZ , Nadya A. HRYCENKO , Doron LEVIN , Tara L. REDDINGTON , Scott J. WEIGEL
CPC分类号： C07F13/005 , C07F3/02 , C01B39/00
摘要： Methods are provided for synthesizing metal organic framework compositions in an aqueous environment and/or in a mixed alcohol/water solvent. The methods can allow for formation of MOF-274 metal organic framework compositions, such as EMM-67 (a mixed metal MOF-274 metal organic framework composition). More generally, the methods can allow for formation of MOF structures that include disalicylate linkers in an aqueous environment and/or in a mixed alcohol/water solvent.
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