公开(公告)号：US20230312774A1

公开(公告)日：2023-10-05

申请号：US18209054

申请日：2023-06-13

Applicant: ExxonMobil Technology and Engineering Company

Inventor： Aaron Sattler ,  Suzzy C.H. Ho ,  Michele L. Paccagnini ,  Christian E. Padilla

IPC: C08F4/70 ,  C08F10/14 ,  C07C2/08 ,  C07C2/32

CPC classification number: C08F4/7098 ,  C08F10/14 ,  C07C2/08 ,  C07C2/32

Abstract: The present disclosure provides base stocks and or diesel fuel, and processes for producing such base stocks and or diesel fuel by polymerizing alpha-olefins and internal olefins. The present disclosure further provides polyolefin products useful as base stocks and or diesel fuel. In at least one embodiment, a process includes: i) introducing, neat or in the presence of a solvent, a feed comprising a branched C5-C30 internal olefin, with a catalyst compound comprising a group 8, 9, 10, or 11 transition metal and at least one heteroatom; and ii) obtaining a C6-C100 polyolefin product having one olefin, a methylene content of from about 1 wt. % to about 98 wt. %, and or a methyl content of from about 1 wt. % to about 75 wt. %. The feed may further include a linear C4-C30 internal olefin, a C2-C30 alpha-olefin, or a mixture thereof.

公开(公告)号：US11713364B2

公开(公告)日：2023-08-01

申请号：US16833992

申请日：2020-03-30

Applicant: ExxonMobil Technology and Engineering Company

Inventor： Aaron Sattler ,  Suzzy C. H. Ho ,  Michele L. Paccagnini ,  Christian E. Padilla

IPC: C07C2/08 ,  C07C2/32 ,  C08F4/70 ,  C08F10/14

CPC classification number: C08F4/7098 ,  C07C2/08 ,  C07C2/32 ,  C08F10/14

Abstract: The present disclosure provides base stocks and or diesel fuel, and processes for producing such base stocks and or diesel fuel by polymerizing alpha-olefins and internal olefins. The present disclosure further provides polyolefin products useful as base stocks and or diesel fuel. In at least one embodiment, a process includes: i) introducing, neat or in the presence of a solvent, a feed comprising a branched C5-C30 internal olefin, with a catalyst compound comprising a group 8, 9, 10, or 11 transition metal and at least one heteroatom and ii) obtaining a C6-C100 polyolefin product having one olefin, a methylene content of from about 1 wt % to about 98 wt %, and or a methyl content of from about 1 wt % to about 75 wt %. The feed may further include a linear C4-C30 internal olefin, a C2-C30 alpha-olefin, or a mixture thereof.

公开(公告)号：US11591419B2

公开(公告)日：2023-02-28

申请号：US16705319

申请日：2019-12-06

Applicant: ExxonMobil Technology and Engineering Company

Inventor： Suzzy C. H. Ho ,  Christian E. Padilla ,  Aaron Sattler ,  Michele Paccagnini

IPC: C08F4/70 ,  C08F4/80 ,  C08F10/14 ,  C10M107/10 ,  C08F4/06 ,  C10M107/42 ,  C08F10/08

Abstract: The present disclosure provides base stocks and processes for producing such basestocks by polymerizing internal olefins. The present disclosure further provides base stocks, comprising low molecular weight polyolefin products, having one or more of improved flow, low temperature properties, and thickening efficiency. The present disclosure further provides polyolefin products useful as base stocks and or diesel fuel. In at least one embodiment, a process includes introducing a feedstream comprising C4-C30 internal-olefins with a catalyst system comprising a nickel diimine catalyst optionally in the presence of a solvent. The method includes obtaining a C6-C100 polyolefin product having one or more of a carbon fraction of epsilon-carbons of from about 0.08 to about 0.3, as determined by 13C NMR spectroscopy, based on the total carbon content of the polyolefin product.