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1.发明授权公开(公告)号：US12227526B2
公开(公告)日：2025-02-18
申请号：US17310622
申请日：2020-03-30
Inventor： Joseph M. Falkowski , Carter W. Abney , Mary S. Abdulkarim , Aaron Sattler , Michele Paccagnini , Simon C. Weston
Abstract: Metal-organic framework materials (MOFs) are highly porous entities comprising a multidentate organic ligand coordinated to multiple metal centers, typically as a coordination polymer. Crystallization may be problematic in some instances when secondary binding sites are present in the multidentate organic ligand. Multidentate organic ligands comprising first and second binding sites bridged together with a third binding site comprising a diimine moiety may alleviate these issues, particularly when using a preformed metal cluster as a metal source to form a MOF. Such MOFs may comprise a plurality of metal centers, and a multidentate organic ligand coordinated to the plurality of metal centers to define an at least partially crystalline network structure having a plurality of internal pores, and in which the multidentate organic ligand comprises first and second binding sites bridged together with a third binding site comprising a diimine moiety. Particular MOFs may comprise N,N′-di(1H-pyrazol-4-yl)ethane-1,2-diimine as a multidentate organic ligand.
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公开(公告)号：US20230257664A1
公开(公告)日：2023-08-17
申请号：US18166852
申请日：2023-02-09
Inventor： Aaron Sattler , Hyung Rae KIM , Theodore W. WALKER , Ethan G. DACOSTA , Xiaochun XU
IPC: C10G11/18
CPC classification number: C10G11/182 , C10G2300/1003 , C10G2300/1007 , C10G2300/1011 , C10G2300/1074
Abstract: The present disclosure provides methods and systems for co-processing a hydrocarbon feed in an FCC system with a second feed of a biomass-derived pyrolysis oil and a third feed of a plastic-derived pyrolysis oil and/or lubricant. A method of co-processing fluid catalytic cracking feeds, includes: introducing a hydrocarbon feed to a fluid catalytic cracking reactor, wherein the hydrocarbon feed comprises hydrocarbons; introducing a biomass feed to the fluid catalytic cracking reactor wherein the biomass feed comprises a biomass-derived pyrolysis oil; introducing a waste feed to the fluid catalytic cracking reactor, wherein the waste feed comprises a plastic, a plastic-derived pyrolysis oil, a lubricant, or a combination thereof; and reacting at least the hydrocarbon feed, the biomass feed, and the waste feed in the presence of one or more fluid catalytic cracking catalysts in the fluid catalytic cracking reactor to produce cracked products.
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Patent Agency Ranking
公开(公告)号：US20230312774A1
公开(公告)日：2023-10-05
申请号：US18209054
申请日：2023-06-13
Inventor： Aaron Sattler , Suzzy C.H. Ho , Michele L. Paccagnini , Christian E. Padilla
CPC classification number: C08F4/7098 , C08F10/14 , C07C2/08 , C07C2/32
Abstract: The present disclosure provides base stocks and or diesel fuel, and processes for producing such base stocks and or diesel fuel by polymerizing alpha-olefins and internal olefins. The present disclosure further provides polyolefin products useful as base stocks and or diesel fuel. In at least one embodiment, a process includes: i) introducing, neat or in the presence of a solvent, a feed comprising a branched C5-C30 internal olefin, with a catalyst compound comprising a group 8, 9, 10, or 11 transition metal and at least one heteroatom; and ii) obtaining a C6-C100 polyolefin product having one olefin, a methylene content of from about 1 wt. % to about 98 wt. %, and or a methyl content of from about 1 wt. % to about 75 wt. %. The feed may further include a linear C4-C30 internal olefin, a C2-C30 alpha-olefin, or a mixture thereof.
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公开(公告)号：US12060527B2
公开(公告)日：2024-08-13
申请号：US18166852
申请日：2023-02-09
Inventor： Aaron Sattler , Hyung Rae Kim , Theodore W. Walker , Ethan G. Dacosta , Xiaochun Xu
CPC classification number: C10G11/182 , C10G2300/1003 , C10G2300/1007 , C10G2300/1011 , C10G2300/1074
Abstract: The present disclosure provides methods and systems for co-processing a hydrocarbon feed in an FCC system with a second feed of a biomass-derived pyrolysis oil and a third feed of a plastic-derived pyrolysis oil and/or lubricant. A method of co-processing fluid catalytic cracking feeds, includes: introducing a hydrocarbon feed to a fluid catalytic cracking reactor, wherein the hydrocarbon feed comprises hydrocarbons; introducing a biomass feed to the fluid catalytic cracking reactor wherein the biomass feed comprises a biomass-derived pyrolysis oil; introducing a waste feed to the fluid catalytic cracking reactor, wherein the waste feed comprises a plastic, a plastic-derived pyrolysis oil, a lubricant, or a combination thereof; and reacting at least the hydrocarbon feed, the biomass feed, and the waste feed in the presence of one or more fluid catalytic cracking catalysts in the fluid catalytic cracking reactor to produce cracked products.
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公开(公告)号：US11713364B2
公开(公告)日：2023-08-01
申请号：US16833992
申请日：2020-03-30
Inventor： Aaron Sattler , Suzzy C. H. Ho , Michele L. Paccagnini , Christian E. Padilla
CPC classification number: C08F4/7098 , C07C2/08 , C07C2/32 , C08F10/14
Abstract: The present disclosure provides base stocks and or diesel fuel, and processes for producing such base stocks and or diesel fuel by polymerizing alpha-olefins and internal olefins. The present disclosure further provides polyolefin products useful as base stocks and or diesel fuel. In at least one embodiment, a process includes: i) introducing, neat or in the presence of a solvent, a feed comprising a branched C5-C30 internal olefin, with a catalyst compound comprising a group 8, 9, 10, or 11 transition metal and at least one heteroatom and ii) obtaining a C6-C100 polyolefin product having one olefin, a methylene content of from about 1 wt % to about 98 wt %, and or a methyl content of from about 1 wt % to about 75 wt %. The feed may further include a linear C4-C30 internal olefin, a C2-C30 alpha-olefin, or a mixture thereof.
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公开(公告)号：US11591419B2
公开(公告)日：2023-02-28
申请号：US16705319
申请日：2019-12-06
Inventor： Suzzy C. H. Ho , Christian E. Padilla , Aaron Sattler , Michele Paccagnini
IPC: C08F4/70 , C08F4/80 , C08F10/14 , C10M107/10 , C08F4/06 , C10M107/42 , C08F10/08
Abstract: The present disclosure provides base stocks and processes for producing such basestocks by polymerizing internal olefins. The present disclosure further provides base stocks, comprising low molecular weight polyolefin products, having one or more of improved flow, low temperature properties, and thickening efficiency. The present disclosure further provides polyolefin products useful as base stocks and or diesel fuel. In at least one embodiment, a process includes introducing a feedstream comprising C4-C30 internal-olefins with a catalyst system comprising a nickel diimine catalyst optionally in the presence of a solvent. The method includes obtaining a C6-C100 polyolefin product having one or more of a carbon fraction of epsilon-carbons of from about 0.08 to about 0.3, as determined by 13C NMR spectroscopy, based on the total carbon content of the polyolefin product.
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公开(公告)号：US11377397B2
公开(公告)日：2022-07-05
申请号：US17077327
申请日：2020-10-22
Inventor： Kun Wang , Aaron Sattler , Jihad M. Dakka
Abstract: The application relates to processes and systems that use a furfural compound for producing five-membered carbocyclic rings that are unsaturated, such as cyclopentene and cyclopentadiene. Examples methods for conversion of furfural compounds may include converting a furfural compound to at least a five-membered, saturated carbocyclic ring, and converting the five-membered, saturated carbocyclic ring in a presence of a catalyst to at least a five-membered, unsaturated carbocyclic ring.
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