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公开(公告)号：US20110130531A1
公开(公告)日：2011-06-02
申请号：US12976059
申请日：2010-12-22
申请人： F. David Hussein , Kevin J. Cann , Ann M. Schoeb-Wolters , Phuong A. Cao , Bruce J. Savatsky , Eric J. Markel , Daniel P. Zilker, JR. , Garth R. Giesbrecht
发明人： F. David Hussein , Kevin J. Cann , Ann M. Schoeb-Wolters , Phuong A. Cao , Bruce J. Savatsky , Eric J. Markel , Daniel P. Zilker, JR. , Garth R. Giesbrecht
CPC分类号： C08F10/00 , C08F4/65912 , C08F4/65925 , C08F10/02 , C08F210/16 , C08F4/65916 , C08F2/34 , C08F210/14 , C08F2500/12 , C08F2500/03
摘要： Methods for gas phase olefin polymerization are provided. The method can include combining a spray dried catalyst system with a diluent to produce a catalyst slurry. The catalyst system can include a metallocene compound. Ethylene, a continuity additive, and the catalyst slurry can be introduced to a gas phase fluidized bed reactor. The reactor can be operated at conditions sufficient to produce a polyethylene. The spray dried catalyst system can have a catalyst productivity of at least 12,000 grams polyethylene per gram of the catalyst system.
摘要翻译： 提供了气相烯烃聚合方法。 该方法可以包括将喷雾干燥的催化剂体系与稀释剂组合以产生催化剂浆料。 催化剂体系可以包括金属茂化合物。 可将乙烯，连续性添加剂和催化剂浆料引入气相流化床反应器。 反应器可以在足以产生聚乙烯的条件下操作。 喷雾干燥的催化剂体系可以具有每克催化剂体系至少12,000克聚乙烯的催化剂生产率。
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公开(公告)号：US08497330B2
公开(公告)日：2013-07-30
申请号：US12976059
申请日：2010-12-22
申请人： F. David Hussein , Kevin J. Cann , Ann M. Schoeb-Wolters , Phuong A. Cao , Bruce J. Savatsky , Eric J. Markel , Daniel P. Zilker, Jr. , Garth R. Giesbrecht
发明人： F. David Hussein , Kevin J. Cann , Ann M. Schoeb-Wolters , Phuong A. Cao , Bruce J. Savatsky , Eric J. Markel , Daniel P. Zilker, Jr. , Garth R. Giesbrecht
CPC分类号： C08F10/00 , C08F4/65912 , C08F4/65925 , C08F10/02 , C08F210/16 , C08F4/65916 , C08F2/34 , C08F210/14 , C08F2500/12 , C08F2500/03
摘要： Methods for gas phase olefin polymerization are provided. The method can include combining a spray dried catalyst system with a diluent to produce a catalyst slurry. The catalyst system can include a metallocene compound. Ethylene, a continuity additive, and the catalyst slurry can be introduced to a gas phase fluidized bed reactor. The reactor can be operated at conditions sufficient to produce a polyethylene. The spray dried catalyst system can have a catalyst productivity of at least 12,000 grams polyethylene per gram of the catalyst system.
摘要翻译： 提供了气相烯烃聚合方法。 该方法可以包括将喷雾干燥的催化剂体系与稀释剂组合以产生催化剂浆料。 催化剂体系可以包括金属茂化合物。 可将乙烯，连续性添加剂和催化剂浆料引入气相流化床反应器。 反应器可以在足以产生聚乙烯的条件下操作。 喷雾干燥的催化剂体系可以具有每克催化剂体系至少12,000克聚乙烯的催化剂生产率。
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公开(公告)号：US20110098425A1
公开(公告)日：2011-04-28
申请号：US12908522
申请日：2010-10-20
申请人： Garth R. Giesbrecht , Timothy M. Boller , Alexander Z. Voskoboynikov , Andrey F. Asachenko , Mikhail V. Nikulin , Alexey A. Tsarev
发明人： Garth R. Giesbrecht , Timothy M. Boller , Alexander Z. Voskoboynikov , Andrey F. Asachenko , Mikhail V. Nikulin , Alexey A. Tsarev
CPC分类号： C07F7/00
摘要： This invention relates to Group 4 catalyst compounds containing di-anionic tridentate nitrogen/oxygen based ligands. The catalyst compounds are useful, with or without activators, to polymerize olefins, particularly a-olefins, or other unsaturated monomers. Systems and processes to oligomerize and/or polymerize one or more unsaturated monomers using the catalyst compound, as well as the oligomers and/or polymers produced therefrom are also provided.
摘要翻译： 本发明涉及含有二阴离子三齿氮/氧基配体的第4族催化剂化合物。 催化剂化合物可以有或没有活化剂聚合烯烃，特别是α-烯烃或其它不饱和单体。 还提供了使用催化剂化合物低聚和/或聚合一种或多种不饱和单体的系统和方法，以及由其制备的低聚物和/或聚合物。
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公开(公告)号：US08877881B2
公开(公告)日：2014-11-04
申请号：US13301910
申请日：2011-11-22
申请人： Garth R. Giesbrecht
发明人： Garth R. Giesbrecht
CPC分类号： C08F210/16 , C08F4/659 , C08F4/64055 , C08F4/64048 , C08F210/14 , C08F2500/20
摘要： This invention relates to Group 4 catalyst compounds containing anionic bidentate nitrogen/oxygen based ligands catalyst compounds useful for polymerization and or oligomerization of unsaturated monomers. The catalyst compounds are particularly useful, with or without activators, to polymerize olefins, particularly α-olefins, or other unsaturated monomers.
摘要翻译： 本发明涉及含有阴离子二齿氮/氧基配体的催化剂化合物，其可用于不饱和单体的聚合和/或低聚。 催化剂化合物特别可用于使用或不使用活化剂来聚合烯烃，特别是α-烯烃或其它不饱和单体。
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公开(公告)号：US08541521B2
公开(公告)日：2013-09-24
申请号：US12908257
申请日：2010-10-20
申请人： Garth R. Giesbrecht , Timothy M. Boller , Alexander Z. Voskoboynikov , Andrey F. Asachenko , Mikhail V. Nikulin , Alexey A. Tsarev
发明人： Garth R. Giesbrecht , Timothy M. Boller , Alexander Z. Voskoboynikov , Andrey F. Asachenko , Mikhail V. Nikulin , Alexey A. Tsarev
CPC分类号： C07F7/00
摘要： Group 4 catalyst compounds containing di-anionic tridentate nitrogen/oxygen based ligands are provided. The catalyst compounds are useful, with or without activators, to polymerize olefins, particularly α-olefins, or other unsaturated monomers. Systems and processes to oligomerize and/or polymerize one or more unsaturated monomers using the catalyst compound, as well as the oligomers and/or polymers produced therefrom are also provided.
摘要翻译： 提供了含有二阴离子三齿氮/氧基配体的第4族催化剂化合物。 催化剂化合物可用于或不使用活化剂聚合烯烃，特别是α-烯烃或其它不饱和单体。 还提供了使用催化剂化合物低聚和/或聚合一种或多种不饱和单体的系统和方法，以及由其制备的低聚物和/或聚合物。
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公开(公告)号：US08530593B2
公开(公告)日：2013-09-10
申请号：US12908615
申请日：2010-10-20
申请人： Garth R. Giesbrecht , Timothy M. Boller , Alexander Z. Voskoboynikov , Andrey F. Asachenko , Mikhail V. Nikulin , Alexey A. Tsarev
发明人： Garth R. Giesbrecht , Timothy M. Boller , Alexander Z. Voskoboynikov , Andrey F. Asachenko , Mikhail V. Nikulin , Alexey A. Tsarev
摘要： This invention relates to Group 4 dialkyl compounds supported by a pyridyl-amido-aryl (“PAA”), an anisole-amido-aryl (“AAA”), a phenoxy-amido-pyridyl (“PAPY”), an anisole-amido-phenoxy (“AAP”) or a anisole-amido-phenoxy (“AAP”) tridentate ligand. Such compounds can polymerize olefins, such as ethylene.
摘要翻译： 本发明涉及由吡啶基 - 酰氨基 - 芳基（“PAA”），苯甲醚 - 酰氨基 - 芳基（“AAA”），苯氧基 - 酰胺基 - 吡啶基（“PAPY”），苯甲醚 - 酰氨基 - 苯氧基（“AAP”）或苯甲醚 - 酰氨基 - 苯氧基（“AAP”）三齿配体。 这样的化合物可以聚合烯烃，如乙烯。
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公开(公告)号：US20110213109A1
公开(公告)日：2011-09-01
申请号：US12715068
申请日：2010-03-01
申请人： Alexander Z. Voskoboynikov , Mikhail V. Nikulin , Aleksey A. Tsarev , Andrey F. Asachenko , Alexander V. Babkin , Garth R. Giesbrecht , Jo Ann M. Canich
发明人： Alexander Z. Voskoboynikov , Mikhail V. Nikulin , Aleksey A. Tsarev , Andrey F. Asachenko , Alexander V. Babkin , Garth R. Giesbrecht , Jo Ann M. Canich
CPC分类号： C07F17/00 , Y10S526/943
摘要： This invention relates to transition metal compounds, catalyst systems comprising said compounds and polymerization processes using such catalyst systems, where the transition metal compound is represented by the formula: This invention also relates to process to produce such compounds.
摘要翻译： 本发明涉及过渡金属化合物，包含所述化合物的催化剂体系和使用这种催化剂体系的聚合方法，其中过渡金属化合物由下式表示：本发明还涉及制备这些化合物的方法。
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公开(公告)号：US08541522B2
公开(公告)日：2013-09-24
申请号：US12908268
申请日：2010-10-20
申请人： Garth R. Giesbrecht , Timothy M. Boller , Alexander Z. Voskoboynikov , Andrey F. Asachenko , Mikhail V. Nikulin , Alexey A. Tsarev
发明人： Garth R. Giesbrecht , Timothy M. Boller , Alexander Z. Voskoboynikov , Andrey F. Asachenko , Mikhail V. Nikulin , Alexey A. Tsarev
CPC分类号： C07F7/00
摘要： This invention relates to Group 4 catalyst compounds containing di-anionic tridentate nitrogen/oxygen based ligands. The catalyst compounds are useful, with or without activators, to polymerize olefins, particularly α-olefins, or other unsaturated monomers. Systems and processes to oligomerize and/or polymerize one or more unsaturated monomers using the catalyst compound, as well as the oligomers and/or polymers produced therefrom are also provided.
摘要翻译： 本发明涉及含有二阴离子三齿氮/氧基配体的第4族催化剂化合物。 催化剂化合物可用于或不使用活化剂聚合烯烃，特别是α-烯烃或其它不饱和单体。 还提供了使用催化剂化合物低聚和/或聚合一种或多种不饱和单体的系统和方法，以及由其制备的低聚物和/或聚合物。
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公开(公告)号：US08058461B2
公开(公告)日：2011-11-15
申请号：US12715068
申请日：2010-03-01
申请人： Alexander Z. Voskoboynikov , Mikhail V. Nikulin , Aleksey A. Tsarev , Andrey F. Asachenko , Alexander V. Babkin , Garth R. Giesbrecht , Jo Ann M. Canich
发明人： Alexander Z. Voskoboynikov , Mikhail V. Nikulin , Aleksey A. Tsarev , Andrey F. Asachenko , Alexander V. Babkin , Garth R. Giesbrecht , Jo Ann M. Canich
IPC分类号： C08F4/6592 , B01J31/22 , C07F17/00
CPC分类号： C07F17/00 , Y10S526/943
摘要： This invention relates to transition metal compounds, catalyst systems comprising said compounds and polymerization processes using such catalyst systems, where the transition metal compound is represented by the formula: This invention also relates to process to produce such compounds.
摘要翻译： 本发明涉及过渡金属化合物，包含所述化合物的催化剂体系和使用这种催化剂体系的聚合方法，其中过渡金属化合物由下式表示：本发明还涉及制备这些化合物的方法。
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公开(公告)号：US20110098427A1
公开(公告)日：2011-04-28
申请号：US12908257
申请日：2010-10-20
申请人： Garth R. Giesbrecht , Timothy M. Boller , Alexander Z. Voskoboynikov , Andrey F. Asachenko , Mikhail V. Nikulin , Alexey A. Tsarev
发明人： Garth R. Giesbrecht , Timothy M. Boller , Alexander Z. Voskoboynikov , Andrey F. Asachenko , Mikhail V. Nikulin , Alexey A. Tsarev
IPC分类号： C08F4/60 , C07D213/89 , C07D213/30 , C07D213/38 , C07C43/23 , C07C211/45 , C07F7/28 , C07F7/00 , C07F7/08 , B01J31/22
CPC分类号： C07F7/00
摘要： Group 4 catalyst compounds containing di-anionic tridentate nitrogen/oxygen based ligands are provided. The catalyst compounds are useful, with or without activators, to polymerize olefins, particularly α-olefins, or other unsaturated monomers. Systems and processes to oligomerize and/or polymerize one or more unsaturated monomers using the catalyst compound, as well as the oligomers and/or polymers produced therefrom are also provided.
摘要翻译： 提供了含有二阴离子三齿氮/氧基配体的第4族催化剂化合物。 催化剂化合物在有或没有活化剂的情况下可用于聚合烯烃，特别是α-烯烃或其它不饱和单体。 还提供了使用催化剂化合物低聚和/或聚合一种或多种不饱和单体的系统和方法，以及由其制备的低聚物和/或聚合物。
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