公开(公告)号：US20150361187A1

公开(公告)日：2015-12-17

申请号：US14304328

申请日：2014-06-13

Applicant: FINA TECHNOLOGY, INC.

Inventor： Lei Zhang ,  David J. Rauscher

IPC: C08F4/655

CPC classification number: C08F4/6555 ,  C08F10/00 ,  C08F4/6557

Abstract: The process includes reacting a reaction mixture comprising magnesium ethoxide (Mg(OEt)2), triethylaluminum (TEAl), and 2-ethylhexanol (2-EHOH) to form magnesium 2-ethyl hexyl alkoxide (Mg(2-EHO)2) and contacting Mg(2-EHO)2 in hexane with a first agent to form a reaction product “A.” The process further includes contacting the reaction product “A” with a second agent to form a reaction product “B”, wherein the second agent includes a transition metal and a halogen. The process further includes contacting the reaction product “B” with a third agent to form a reaction product “C”, wherein the third agent includes a first metal halide. In addition, the process includes contacting the reaction product “C” with a fourth agent to form a reaction product “D”, wherein the fourth agent includes a second metal halide. The process also includes contacting the reaction product “D” with a fifth agent to form a Ziegler-Natta catalyst, wherein the fifth agent includes an organoaluminum compound.

Abstract translation: 该方法包括使包含乙醇镁（Mg（OEt）2），三乙基铝（TEAl）和2-乙基己醇（2-EHOH））的反应混合物反应形成2-乙基己基醇盐（Mg（2-EHO）2）和 使己烷中的Mg（2-EHO）2与第一试剂接触以形成反应产物“A.”该方法还包括使反应产物“A”与第二试剂接触以形成反应产物“B”，其中第二 试剂包括过渡金属和卤素。 该方法还包括使反应产物“B”与第三试剂接触以形成反应产物“C”，其中第三试剂包括第一金属卤化物。 此外，该方法包括使反应产物“C”与第四试剂接触以形成反应产物“D”，其中第四试剂包括第二金属卤化物。 该方法还包括使反应产物“D”与第五试剂接触以形成齐格勒 - 纳塔催化剂，其中第五试剂包括有机铝化合物。

公开(公告)号：US09650448B2

公开(公告)日：2017-05-16

申请号：US14304328

申请日：2014-06-13

Applicant: FINA TECHNOLOGY, INC.

Inventor： Lei Zhang ,  David J. Rauscher

IPC: C08F10/02 ,  C08F4/655 ,  C08F10/00

CPC classification number: C08F4/6555 ,  C08F10/00 ,  C08F4/6557

Abstract: The process includes reacting a reaction mixture comprising magnesium ethoxide (Mg(OEt)2), triethylaluminum (TEAl), and 2-ethylhexanol (2-EHOH) to form magnesium 2-ethyl hexyl alkoxide (Mg(2-EHO)2) and contacting Mg(2-EHO)2 in hexane with a first agent to form a reaction product “A.” The process further includes contacting the reaction product “A” with a second agent to form a reaction product “B”, wherein the second agent includes a transition metal and a halogen. The process further includes contacting the reaction product “B” with a third agent to form a reaction product “C”, wherein the third agent includes a first metal halide. In addition, the process includes contacting the reaction product “C” with a fourth agent to form a reaction product “D”, wherein the fourth agent includes a second metal halide. The process also includes contacting the reaction product “D” with a fifth agent to form a Ziegler-Natta catalyst, wherein the fifth agent includes an organoaluminum compound.

公开(公告)号：US09624321B2

公开(公告)日：2017-04-18

申请号：US14304358

申请日：2014-06-13

Applicant: FINA TECHNOLOGY, INC.

Inventor： Lei Zhang ,  David J. Rauscher

IPC: C08F10/02 ,  C08F110/02

CPC classification number: C08F110/02 ,  C08F4/6555 ,  C08F2500/07 ,  C08F2500/12 ,  C08F2500/18 ,  C08F2500/24

Abstract: A process of forming a Ziegler-Natta catalyst component is disclosed. The process includes contacting an alkyl magnesium compound with an alcohol and a first organoaluminum compound to form a magnesium dialkoxide compound and contacting the magnesium dialkoxide compound with a titanating agent to form reaction product “A.” The process further includes reacting reaction product “A” with a halogenating agent to form reaction product “B” and reacting reaction product “B” with a second organoaluminum compound to form a single halogenated catalyst component.

公开(公告)号：US20150361188A1

公开(公告)日：2015-12-17

申请号：US14304358

申请日：2014-06-13

Applicant: FINA TECHNOLOGY, INC.

Inventor： Lei Zhang ,  David J. Rauscher

IPC: C08F10/02

CPC classification number: C08F110/02 ,  C08F4/6555 ,  C08F2500/07 ,  C08F2500/12 ,  C08F2500/18 ,  C08F2500/24

Abstract: A process of forming a Ziegler-Natta catalyst component is disclosed. The process includes contacting an alkyl magnesium compound with an alcohol and a first organoaluminum compound to form a magnesium dialkoxide compound and contacting the magnesium dialkoxide compound with a titanating agent to form reaction product “A.” The process further includes reacting reaction product “A” with a halogenating agent to form reaction product “B” and reacting reaction product “B” with a second organoaluminum compound to form a single halogenated catalyst component.

Abstract translation: 公开了一种形成齐格勒 - 纳塔催化剂组分的方法。 该方法包括使烷基镁化合物与醇和第一有机铝化合物接触以形成二烷氧基化镁化合物，并使二烷氧基镁化合物与钛酸化剂接触以形成反应产物“A”。该方法还包括使反应产物“A” 与卤化剂反应形成反应产物“B”并使反应产物“B”与第二有机铝化合物反应形成单一的卤化催化剂组分。