摘要:
In at least one embodiment, a fuel cell is provided comprising a positive electrode including a first gas diffusion layer and a first catalyst layer, a negative electrode including a second gas diffusion layer and a second catalyst layer, a proton exchange membrane (PEM) disposed between the positive and negative electrodes, and a microporous layer of carbon and binder disposed between at least one of the first gas diffusion layer and the first catalyst layer and the second gas diffusion layer and the second catalyst layer. The microporous layer may have defined therein a plurality of pores with a diameter of 0.05 to 2.0 μm and a plurality of bores having a diameter of 1 to 100 μm. The bores may be laser perforated and comprise from 0.1 to 5 percent of a total porosity of the microporous layer.
摘要:
A fuel cell includes a plurality of unit cells disposed in a stack. Each unit cell includes a membrane electrode assembly (MEA) having an anode and a cathode and a bipolar plate having a cathode side defining a recessed pocket in fluid communication with an air port, an anode side, and coolant channels between the cathode and anode sides. The bipolar plate is disposed against the MEA such that the cathode is disposed over the pocket. A flow guide is disposed in the pocket with a front side facing the MEA and a back side facing a bottom of the pocket. The flow guide has a plurality of embossments.
摘要:
A solid polymer electrolyte having a reinforcing substrate, a polymer having ethylene oxide portions and hydrocarbon portions with pendent functional groups having high relative permittivity for an electrochemical cell is provided. The solid polymer electrolyte may provide good ionic conductivity at room temperature and good mechanical strength.
摘要:
A bipolar plate for a fuel cell includes an anode plate and a cathode plate. The anode plate has hydrogen flow channels on a first side of the anode plate and coolant channels on a second side of the anode plate. The cathode plate has a first side disposed against the second side of the anode plate to cover the coolant channels and has a second side defining a recessed pocket configured to receive a stream of air. A flow guide is disposed in the pocket such that an inlet manifold is formed along a first edge of the flow guide and an outlet manifold is formed along a second edge of the flow guide. The flow guide defines channels extending from the inlet manifold to the outlet manifold. A plurality of openings is defined by through the flow guide.
摘要:
Various methods of making low-tortuosity electrodes are disclosed. In some embodiments, the low-tortuosity electrodes have a tortuosity of less than 2.0 or 1.4 and include battery-active material and solid electrolyte with the solid electrolyte having channels therein that are vertically aligned. A solid-state lithium-ion battery electrode is also disclosed.
摘要:
A single-ion polymer electrolyte has formula (I): R—[SO2N(M)SO2—X—]m—SO3Li (I). In formula (I), X may be an electron withdrawing group such as an aromatic group, substituted aromatic group, —(CF2)n—, —(CCl2)n—, —C6H4—, or —C6H3(NO2)—. R may be a fluorinated alkyl, LiSO3(CF2)3—, or an aromatic group, and M may be a metal cation. For the single-ion polymer electrolyte with formula (I), m may be an integer from 2 to 2000, and n may be an integer from 1 to 4.
摘要:
A fuel cell electrode includes a carbon nanofiber substrate and a continuous film of up to 100 atom-thick monolayers forming a network of interconnected electrocatalyst nanoparticles deposited on the carbon nanofiber substrate such that at least some of the nanoparticles are directly adhered to uppermost nanofibers of the substrate to form a layer resistant to electrocatalyst depletion.
摘要:
In at least one embodiment, a microporous layer configured to be disposed between a catalyst layer and a gas diffusion layer of a fuel cell electrode assembly is provided. The microporous layer may have defined therein a plurality of hydrophilic pores, a plurality of hydrophobic pores with a diameter of 0.02 to 0.5 μm, and a plurality of bores with a diameter of 0.5 to 100 μm. The microporous layer structures and gas diffusion layer assemblies disclosed herein may be defined by a number of various designs and arrangements for use in proton exchange membrane fuel cell systems.
摘要:
A bipolar plate for a fuel cell includes an anode plate and a cathode plate. The anode plate has hydrogen flow channels on a first side of the anode plate and coolant channels on a second side of the anode plate. The cathode plate has a first side disposed against the second side of the anode plate to cover the coolant channels and has a second side defining a recessed pocket configured to receive a stream of air. A flow guide is disposed in the pocket such that an inlet manifold is formed along a first edge of the flow guide and an outlet manifold is formed along a second edge of the flow guide. The flow guide defines channels extending from the inlet manifold to the outlet manifold. A plurality of openings is defined by through the flow guide.
摘要:
A fuel cell oxidation reduction reaction catalyst comprising a carbon substrate, an amorphous metal oxide intermediate layer on the substrate, and an intertwined matrix of platinum and elemental niobium arranged to form a surface metal layer covering the intermediate layer such that upon oxidation, the niobium binds with oxygen resulting in strengthened bonds between the platinum and the intermediate layer.