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公开(公告)号：US20210032217A1
公开(公告)日：2021-02-04
申请号：US16965756
申请日：2019-01-31
Applicant: Furanix Technologies B.V.
Inventor： Robert-Jan van Putten , Benjamin McKay , Gerardus Johannes Maria Gruter , Jan Cornelis van der Waal
IPC: C07D307/50 , C07B63/00
Abstract: A process includes the following steps: a) converting a solid material containing hemicellulose, cellulose and lignin, by: (i) hydrolyzing at least part of the hemicellulose of the solid material with a first aqueous hydrochloric acid solution, yielding a remaining solid material and a hydrochloric acid- containing, aqueous, first hydrolysate product solution; (ii) hydrolyzing at least part of the cellulose of the remaining solid material with a second aqueous hydrochloric acid solution, yielding a residue and a hydrochloric acid-containing, aqueous, second hydrolysate product solution; (b) forwarding to step (c) a, hydrochloric acid-containing, aqueous intermediate product solution comprising: a part of or the whole of the hydrochloric acid-containing, aqueous first and/or second hydrolysate product solution of step (a); and (c) heating at least part of the hydrochloric acid-containing, aqueous intermediate product solution to yield a product solution containing 5-(chloromethyl)furfural, and extracting the 5-(chloromethyl)furfural from the product solution into an extraction solvent.
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公开(公告)号：US09902750B2
公开(公告)日：2018-02-27
申请号：US14895027
申请日：2014-06-06
Applicant: Furanix Technologies B.V.
Inventor： Benjamin McKay , Ana Sofia Vagueiro De Sousa Dias , Sarwat Iqbal , Gerardus Johannes Maria Gruter , Robert-Jan Van Putten
Abstract: A fructoside-containing product is manufactured from a glucose-rich feedstock, in a process where glucose to fructose is isomerized by contacting the glucose-rich feedstock with a basic isomerization catalyst in an alcoholic medium at a temperature of at least 75° C., to yield a fructose-containing product; and where at least part of the fructose-containing product obtained therefrom is reacted with an alcohol in the presence of an acid catalyst to yield a fructoside-containing product.
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公开(公告)号：US20210032216A1
公开(公告)日：2021-02-04
申请号：US16965746
申请日：2019-01-31
Applicant: Furanix Technologies B.V.
Inventor： Robert-Jan van Putten , Benjamin McKay , Gerardus Johannes Maria Gruter , Jan Cornelis van der Waal
IPC: C07D307/50 , B01D11/02
Abstract: A process for the conversion of solid lignocellulosic material containing hemicellulose, cellulose and lignin, includes (a) hydrolyzing, at a temperature equal to or less than 40° C. at least part of the hemicellulose and at least part of the cellulose of the solid lignocellulosic material with an aqueous hydrochloric acid solution, containing in the range from equal to or more than 40.0 wt. % to equal to or less than 51.0 wt. % hydrochloric acid, based on the combined weight amount of water and hydrochloric acid in the aqueous hydrochloric acid solution; yielding a hydrochloric acid-containing, aqueous hydrolysate solution; (b) separating the hydrochloric acid-containing, aqueous hydrolysate solution from the lignin; and (c) heating at least part of the hydrochloric acid-containing, aqueous hydrolysate solution to a temperature equal to or more than 60° C., yielding a product solution containing 5-(chloromethyl)furfural, and extracting the 5-(chloromethyl)furfural from the product solution into an extraction solvent.
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公开(公告)号：US09896425B2
公开(公告)日：2018-02-20
申请号：US14914972
申请日：2014-08-29
Applicant: FURANIX TECHNOLOGIES B.V.
Inventor： Jagdeep Singh , Benjamin McKay , Bing Wang , Matheus Adrianus Dam , Gerardus Johannes Maria Gruter , Ana Sofia Vagueiro De Sousa Dias
IPC: C07D307/68 , C07B63/02
CPC classification number: C07D307/68 , C07B63/02
Abstract: An acid composition comprising 2-formyl-furan-5-carboxylic acid and 2,5-furandicarboxylic acid is purified in a process which comprises; contacting the acid composition with an alcohol to obtain an esterified composition; and separating the ester of 2-formyl-furan-5-carboxylic acid from the esterified composition to obtain a purified esterified product; and contacting the purified esterified composition with water for saponification or hydrolysis, to obtain a product composition, comprising 2,5-furandicarboxylic acid and a reduced amount of 2-formyl-furan-5-carboxylic acid.
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Patent Agency Ranking
公开(公告)号：US09643945B2
公开(公告)日：2017-05-09
申请号：US14781993
申请日：2014-04-04
Applicant: Furanix Technologies B.V.
Inventor： Etienne Mazoyer , Ana Sofia Vagueiro De Sousa Dias , Benjamin McKay , Hendrikus Jacob Baars , Victor Peter Charles Vreeken , Gerardus Johannes Maria Gruter , David Lee Sikkenga
IPC: C07D307/68
CPC classification number: C07D307/68 , Y02P20/582
Abstract: 2,5-Furandicarboxylic acid and methyl acetate are prepared in a continuous process by introducing a 5-methoxymethylfurfural-containing feedstock, an oxygen-containing gas, an oxidation catalyst and an acetic acid-containing solvent into a reactor; allowing 5-methoxymethylfurfural to react with oxygen and acetic acid in the presence of the oxidation catalyst to yield 2,5-furandicarboxylic acid as main product and methyl acetate; withdrawing 2,5-furandicarboxylic acid-containing product from the reactor and recovering 2,5-furandicarboxylic acid product; and withdrawing a vaporous stream containing methyl acetate from the reactor.
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公开(公告)号：US20160024039A1
公开(公告)日：2016-01-28
申请号：US14781993
申请日：2014-04-04
Applicant: FURANIX TECHNOLOGIES B.V.
Inventor： Etienne Mazoyer , Ana Sofia Vagueiro De Sousa Dias , Benjamin McKay , Hendrikus Jacob Baars , Victor Peter Charles Vreeken , Gerardus Johannes Maria Gruter , David Lee Sikkenga
IPC: C07D307/68
CPC classification number: C07D307/68 , Y02P20/582
Abstract: 2,5-Furandicarboxylic acid and methyl acetate are prepared in a continuous process by introducing a 5-methoxymethylfurfural-containing feedstock, an oxygen-containing gas, an oxidation catalyst and an acetic acid-containing solvent into a reactor; allowing 5-methoxymethylfurfural to react with oxygen and acetic acid in the presence of the oxidation catalyst to yield 2,5-furandicarboxylic acid as main product and methyl acetate; withdrawing 2,5-furandicarboxylic acid-containing product from the reactor and recovering 2,5-furandicarboxylic acid product; and withdrawing a vaporous stream containing methyl acetate from the reactor.
Abstract translation: 通过将5-甲氧基甲基糠醛的原料，含氧气体，氧化催化剂和含乙酸的溶剂引入反应器，在连续方法中制备2,5-呋喃二甲酸和乙酸甲酯。 在氧化催化剂存在下，使5-甲氧基甲基糠醛与氧和乙酸反应，得到2,5-呋喃二羧酸为主要产物和乙酸甲酯; 从反应器中取出2,5-呋喃二羧酸的产物并回收2,5-呋喃二羧酸产物; 并从反应器中取出含有乙酸甲酯的蒸气流。
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公开(公告)号：US11332454B2
公开(公告)日：2022-05-17
申请号：US16965746
申请日：2019-01-31
Applicant: Furanix Technologies B.V.
Inventor： Robert-Jan van Putten , Benjamin McKay , Gerardus Johannes Maria Gruter , Jan Cornelis van der Waal
IPC: C07D307/50 , B01D11/02
Abstract: A process for the conversion of solid lignocellulosic material containing hemicellulose, cellulose and lignin, includes (a) hydrolyzing, at a temperature equal to or less than 40° C. at least part of the hemicellulose and at least part of the cellulose of the solid lignocellulosic material with an aqueous hydrochloric acid solution, containing in the range from equal to or more than 40.0 wt. % to equal to or less than 51.0 wt. % hydrochloric acid, based on the combined weight amount of water and hydrochloric acid in the aqueous hydrochloric acid solution; yielding a hydrochloric acid-containing, aqueous hydrolysate solution; (b) separating the hydrochloric acid-containing, aqueous hydrolysate solution from the lignin; and (c) heating at least part of the hydrochloric acid-containing, aqueous hydrolysate solution to a temperature equal to or more than 60° C., yielding a product solution containing 5-(chloromethyl)furfural, and extracting the 5-(chloromethyl)furfural from the product solution into an extraction solvent.
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公开(公告)号：US11578046B2
公开(公告)日：2023-02-14
申请号：US16965756
申请日：2019-01-31
Applicant: Furanix Technologies B.V.
Inventor： Robert-Jan van Putten , Benjamin McKay , Gerardus Johannes Maria Gruter , Jan Cornelis van der Waal
IPC: C07D307/50 , C07B63/00
Abstract: A process includes the following steps: a) converting a solid material containing hemicellulose, cellulose and lignin, by: (i) hydrolyzing at least part of the hemicellulose of the solid material with a first aqueous hydrochloric acid solution, yielding a remaining solid material and a hydrochloric acid-containing, aqueous, first hydrolysate product solution; (ii) hydrolyzing at least part of the cellulose of the remaining solid material with a second aqueous hydrochloric acid solution, yielding a residue and a hydrochloric acid-containing, aqueous, second hydrolysate product solution; (b) forwarding to step (c) a, hydrochloric acid-containing, aqueous intermediate product solution comprising: a part of or the whole of the hydrochloric acid-containing, aqueous first and/or second hydrolysate product solution of step (a); and (c) heating at least part of the hydrochloric acid-containing, aqueous intermediate product solution to yield a product solution containing 5-(chloromethyl)furfural, and extracting the 5-(chloromethyl)furfural from the product solution into an extraction solvent.
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公开(公告)号：US20160130292A1
公开(公告)日：2016-05-12
申请号：US14895027
申请日：2014-06-06
Applicant: FURANIX TECHNOLOGIES B.V.
Inventor： Benjamin McKay , Ana Sofia Vagueiro De Sousa Dias , Sarwat Iqbal , Gerardus Johannes Maria Gruter , Robert-Jan Van Putten
IPC: C07H3/02
Abstract: A fructoside-containing product is manufactured from a glucose-rich feedstock, in a process where glucose to fructose is isomerized by contacting the glucose-rich feedstock with a basic isomerization catalyst in an alcoholic medium at a temperature of at least 75° C., to yield a fructose-containing product; and where at least part of the fructose-containing product obtained therefrom is reacted with an alcohol in the presence of an acid catalyst to yield a fructoside-containing product.
Abstract translation: 在富含葡萄糖的原料中制备含果糖糖苷的产物，其中葡萄糖至果糖通过在至少75℃的温度下在醇介质中使富含葡萄糖的原料与碱性异构化催化剂接触来异构化， 产生含果糖的产品; 并且其中由酸得到的含果糖糖的产物的至少一部分与醇在酸催化剂的存在下反应，得到含果糖糖苷的产物。
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