公开(公告)号：US6090356A

公开(公告)日：2000-07-18

申请号：US150846

申请日：1998-09-10

申请人： Frederick C. Jahnke ,  William P. Volk

发明人： Frederick C. Jahnke ,  William P. Volk

IPC分类号： C01B3/36 ,  C01B3/50 ,  C01B3/52 ,  C01B32/50 ,  C10K1/08 ,  C10K1/18 ,  C10L3/00 ,  C01B3/00

CPC分类号： C01B3/52 ,  C10K1/08 ,  C10L3/00 ,  C01B2203/0415 ,  C01B2203/047 ,  C01B2203/0475 ,  C01B2203/0485 ,  Y02E20/18 ,  Y02P20/125

摘要： This invention is an integrated process which removes acidic gases such as H.sub.2 S, COS and CO.sub.2 from raw synthesis gas. The H.sub.2 S and COS is concentrated and separately recovered. The separately recovered CO.sub.2 is used as a moderator with the purified syngas in a combustion turbine. The process comprises separating H.sub.2 S and COS from a raw synthesis gas by absorption with a liquid solvent, removing coabsorbed CO.sub.2 by stripping the solvent with nitrogen, separating the H.sub.2 S and COS from the solvent and recovering sulfur from the H.sub.2 S and COS. The energy value of the CO.sub.2 and its value as a diluent in reducing NO.sub.x is recovered by using the CO.sub.2 as a moderator during combustion of the purified synthesis gas in a gas turbine.

摘要翻译： 本发明是从原料合成气中除去H 2 S，COS和CO 2等酸性气体的综合工艺。 H2S和COS浓缩并分离回收。 单独回收的二氧化碳用作在燃气轮机中具有纯化合成气的缓和剂。 该方法包括通过用液体溶剂吸收从原料合成气中分离H 2 S和COS，通过用氮气汽提溶剂除去共吸附的CO 2，从溶剂中分离H 2 S和COS，并从H 2 S和COS中回收硫，其能量值 在燃气轮机中净化的合成气的燃烧期间，通过使用CO 2作为调节剂来回收CO 2及其作为还原NOx中的稀释剂的值。

公开(公告)号：US06596780B2

公开(公告)日：2003-07-22

申请号：US10001783

申请日：2001-10-23

申请人： Fred C. Jahnke ,  Dipak C. Kothari ,  Lalit S. Shah ,  William P. Volk ,  Kamlesh B. Vakil ,  Rui Song ,  Gayla D. Hamby

发明人： Fred C. Jahnke ,  Dipak C. Kothari ,  Lalit S. Shah ,  William P. Volk ,  Kamlesh B. Vakil ,  Rui Song ,  Gayla D. Hamby

IPC分类号： C07C2700

CPC分类号： C10G2/32 ,  F02B43/00 ,  F02G3/00 ,  Y02T10/32

摘要： Hydrocarbonaceous fuel, such as coal, oil or gas, is gasified to produce syngas comprising H2 and CO, scrubbed free of particles, and saturated with water. The syngas is then treated in an acid gas removal unit as desired to remove any impurities in the syngas. After processing the syngas in the AGR, it is routed to a hydrocarbon synthesis reactor. In the hydrocarbon synthesis reactor, the bulk of the H2 and CO in the syngas is converted to synthetic hydrocarbons, the makeup of which is generally dependent on the type catalyst used in the reactor. The unreacted gas, or tailgas, exiting the reactor, is sent to the gas turbine as fuel. Optionally, N2 or natural gas can be added to the tailgas prior to the combustion turbine. N2 may also optionally be mixed with the hydrocarbon synthesis reactor feed to help control the reaction temperature. After being combusted in the combustor of a gas turbine, the combustion products are expanded to produce power. The expanded combustion products are then sent to a heat recovery steam generator (HRSG) to produce steam that can also be expanded to produce power.

摘要翻译： 将碳氢化合物燃料（例如煤，油或气体）气化以产生包含H 2和CO的合成气，除去颗粒并用水饱和。 然后根据需要在酸性气体去除单元中处理合成气以除去合成气中的任何杂质。 在处理AGR中的合成气后，将其送入烃合成反应器。 在烃合成反应器中，合成气中的大部分H 2和CO转化为合成烃，其组成通常取决于反应器中使用的催化剂类型。 离开反应器的未反应气体或尾气作为燃料送到燃气轮机。 任选地，可以在燃气轮机之前将氮气或天然气加入到尾气中。 N2也可以任选地与烃合成反应器进料混合以帮助控制反应温度。 在燃气轮机的燃烧器中燃烧之后，燃烧产物被膨胀以产生动力。 然后将膨胀的燃烧产物送到热回收蒸汽发生器（HRSG），以产生也可以膨胀以产生电力的蒸汽。