公开(公告)号：US20120012822A1

公开(公告)日：2012-01-19

申请号：US13145487

申请日：2010-01-22

申请人： Fumitoshi Kakiuchi ,  Hiroki Terai

发明人： Fumitoshi Kakiuchi ,  Hiroki Terai

IPC分类号： H01L51/10 ,  C07F7/08 ,  C07D495/04 ,  C07D493/04 ,  C07C5/00 ,  C07C46/00 ,  C07D401/10 ,  C07D487/04 ,  C07C15/20 ,  C07C50/22 ,  C07D517/04

CPC分类号： H01L51/0558 ,  C07F7/0805 ,  C07F7/081 ,  C07F7/0812 ,  C07F7/1804 ,  H01L51/0055 ,  H01L51/0056 ,  H01L51/0057 ,  H01L51/0068 ,  H01L51/0074 ,  H01L51/0094 ,  H01L51/0541 ,  H01L51/0545 ,  H01L51/0554 ,  H01L51/057 ,  H01L51/102

摘要： An aromatic compound represented by the following formula (1). [In the formula, ring A and ring B each represent a benzene ring, an aromatic fused ring composed of 2-4 rings, a heteroaromatic ring or a heterocyclic aromatic fused ring composed of 2-4 rings, R1a represents a group —CHR2a—CHR2bR2c, and R1b, R1c and R1d each represent hydrogen, aryl or a group —CHR2d—CHR2eR2f. This is with the proviso that at least 2 of R1b, R1c and R1d are not hydrogen. R2a, R2b and R2c each represent hydrogen, alkyl, aryl or a substituted silyl group, and R2a and R2b may be bonded together to form a ring. R2d, R2e and R2f each represent hydrogen, alkyl, aryl or a substituted silyl group, and R2d and R2e may be bonded together to form a ring.]

摘要翻译： 由下式（1）表示的芳香族化合物。 [式中，环A和环B各自表示苯环，由2-4个环组成的芳香稠环，杂环芳环或由2-4个环组成的杂环芳香稠合环，R 1a表示基团-CHR 2a- CHR2bR2c和R1b，R1c和R1d各自表示氢，芳基或基团-CHR2d-CHR2eR2f。 这是条件是R1b，R1c和R1d的至少2个不是氢。 R2a，R2b和R2c各自表示氢，烷基，芳基或取代的甲硅烷基，R2a和R2b可以键合在一起形成环。 R2d，R2e和R2f各自表示氢，烷基，芳基或取代甲硅烷基，R2d和R2e可以键合在一起形成环。]

公开(公告)号：US20090043096A1

公开(公告)日：2009-02-12

申请号：US12162549

申请日：2007-02-02

申请人： Fumitoshi Kakiuchi ,  Yusuke Matsuura ,  Masato Ueda

发明人： Fumitoshi Kakiuchi ,  Yusuke Matsuura ,  Masato Ueda

IPC分类号： C07D239/02 ,  C07D213/06 ,  C07D231/12 ,  C07D263/12 ,  C07D277/20 ,  C07D409/04 ,  C07D221/06

CPC分类号： C07D213/127 ,  C07D213/16 ,  C07D213/26 ,  C07D213/30 ,  C07D213/57 ,  C07D221/10 ,  C07D231/12 ,  C07D239/26 ,  C07D263/12 ,  C07D277/22 ,  C07D401/04 ,  C07D409/04

摘要： A method of producing an aromatic compound of the following formula (3) comprising reacting a compound of the following formula (1) with an olefin compound of the following formula (2) in the presence of a transition metal complex: (wherein, an Ar1 ring represents an aromatic hydrocarbon ring or aromatic heterocyclic ring, an Ar2 ring represents a heterocyclic ring containing X1 and N*, and the X1 represents a nitrogen atom or carbon atom and the N represents a nitrogen atom connecting via a double bond to either one of two adjacent atoms in the Ar2 ring.) (wherein, R1, R2, R3 and R4 represent each independently a hydrogen atom, an alkyl group having 1 to 10 carbon atoms or an aryl group having 6 to 18 carbon atoms.) (wherein, Ar1, Ar2, X1, N*, R1, R2 and R3 represent the same meanings as described above.).

摘要翻译： 一种制备下式（3）的芳族化合物的方法，包括使下式（1）的化合物与下式（2）的烯烃化合物在过渡金属络合物的存在下反应：（其中Ar 1 环表示芳香族烃环或芳香族杂环，Ar 2环表示含有X1和N *的杂环，X1表示氮原子或碳原子，N表示通过双键连接的氮原子与 （其中，R 1，R 2，R 3和R 4各自独立地表示氢原子，碳原子数1〜10的烷基或碳原子数6〜18的芳基）（式中， Ar1，Ar2，X1，N *，R1，R2和R3表示与上述相同的含义。

公开(公告)号：US08212048B2

公开(公告)日：2012-07-03

申请号：US12162549

申请日：2007-02-02

申请人： Fumitoshi Kakiuchi ,  Yusuke Matsuura ,  Masato Ueda

发明人： Fumitoshi Kakiuchi ,  Yusuke Matsuura ,  Masato Ueda

IPC分类号： C07D401/04 ,  C07D403/04 ,  C07D213/02 ,  C07D213/22 ,  C07D213/127 ,  C07D215/00 ,  C07D221/10 ,  C07D237/06 ,  C07D237/30 ,  C07D239/24 ,  C07D239/70 ,  C07D241/10 ,  C07D241/36 ,  C07D251/12 ,  C07D277/20 ,  C07D275/02 ,  C07D261/06 ,  C07D263/30 ,  C07D233/54 ,  C07D231/10 ,  C07D231/12 ,  C07D333/10

CPC分类号： C07D213/127 ,  C07D213/16 ,  C07D213/26 ,  C07D213/30 ,  C07D213/57 ,  C07D221/10 ,  C07D231/12 ,  C07D239/26 ,  C07D263/12 ,  C07D277/22 ,  C07D401/04 ,  C07D409/04

摘要： A method of producing an aromatic compound of the following formula (3) comprising reacting a compound of the following formula (1) with an olefin compound of the following formula (2) in the presence of a transition metal complex: (wherein, an Ar1 ring represents an aromatic hydrocarbon ring or aromatic heterocyclic ring, an Ar2 ring represents a heterocyclic ring containing X1 and N*, and the X1 represents a nitrogen atom or carbon atom and the N represents a nitrogen atom connecting via a double bond to either one of two adjacent atoms in the Ar2 ring.) (wherein, R1, R2, R3 and R4 represent each independently a hydrogen atom, an alkyl group having 1 to 10 carbon atoms or an aryl group having 6 to 18 carbon atoms.) (wherein, Ar1, Ar2, X1, N*, R1, R2 and R3 represent the same meanings as described above.).

摘要翻译： 一种制备下式（3）的芳族化合物的方法，包括使下式（1）的化合物与下式（2）的烯烃化合物在过渡金属络合物的存在下反应：（其中Ar 1 环表示芳香族烃环或芳香族杂环，Ar 2环表示含有X1和N *的杂环，X1表示氮原子或碳原子，N表示通过双键连接的氮原子与 （其中，R 1，R 2，R 3和R 4各自独立地表示氢原子，碳原子数1〜10的烷基或碳原子数6〜18的芳基）（式中， Ar1，Ar2，X1，N *，R1，R2和R3表示与上述相同的含义。

公开(公告)号：US20110028739A1

公开(公告)日：2011-02-03

申请号：US12812575

申请日：2009-01-16

申请人： Fumitoshi Kakiuchi ,  Jun Oguma

发明人： Fumitoshi Kakiuchi ,  Jun Oguma

IPC分类号： C07D409/14

CPC分类号： H01L51/0068 ,  C07D333/18 ,  H01L51/0062 ,  H01L51/0065 ,  H01L51/0067 ,  H01L51/0069 ,  H01L51/0071 ,  H01L51/0072 ,  H01L51/0073 ,  H01L51/0074 ,  H01L51/5048

摘要： A compound represented by the following formula (1): wherein Ar1, Ar2 and Ar3 each independently represent an aryl group or a monovalent heterocyclic group; the aryl group or the monovalent heterocyclic group represented by Ar1 has an aryl group, a monovalent alicyclic hydrocarbon group or a monovalent heterocyclic group at one position adjacent to the atom that forms Ar1 and is bonded to a carbon atom forming the benzene ring Q; the aryl group or the monovalent heterocyclic group represented by Ar2 has an aryl group, a monovalent alicyclic hydrocarbon group or a monovalent heterocyclic group at one position adjacent to the atom that forms Ar2 and is bonded to a carbon atom forming the benzene ring Q; the aryl group or the monovalent heterocyclic group represented by Ar3 has an aryl group, a monovalent alicyclic hydrocarbon group or a monovalent heterocyclic group at one position adjacent to the atom that forms Ar3 and is bonded to a carbon atom forming the benzene ring Q.

摘要翻译： 由下式（1）表示的化合物：其中Ar1，Ar2和Ar3各自独立地表示芳基或1价杂环基; 由Ar 1表示的芳基或1价杂环基在与形成Ar 1的原子相邻的一个位置上具有芳基，一价脂环族烃基或1价杂环基，与形成苯环Q的碳原子键合。 由Ar 2表示的芳基或1价杂环基在与形成Ar 2的原子相邻的一个位置上具有芳基，一价脂环族烃基或1价杂环基，与形成苯环Q的碳原子键合; 由Ar 3表示的芳基或1价杂环基在与形成Ar 3的原子相邻的一个位置上具有芳基，一价脂环族烃基或1价杂环基，与形成苯环Q的碳原子键合。

公开(公告)号：US20110308963A1

公开(公告)日：2011-12-22

申请号：US13203597

申请日：2010-03-08

申请人： Fumitoshi Kakiuchi

发明人： Fumitoshi Kakiuchi

IPC分类号： C25B3/06

CPC分类号： C25B3/06 ,  C25B9/08

摘要： In an electrolytic bath partitioned with an anion exchange membrane, water is supplied to the cathode chamber and an aromatic compound and a polar organic solvent, and depending on the case also a transition metal catalyst, are supplied to the anode chamber, and then electrolysis is carried out in the presence of a halogenating agent, to introduce a halogen onto the aromatic ring of the aromatic compound.

摘要翻译： 在用阴离子交换膜分隔的电解槽中，向阳极室供给水，向阳极室供给芳香族化合物和极性有机溶剂，并且根据情况也提供过渡金属催化剂，然后电解为 在卤化剂的存在下进行，以在芳香族化合物的芳环上引入卤素。