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    Catalyst component for the polymerization of olefins
    1.
    发明授权
    Catalyst component for the polymerization of olefins 失效

    公开(公告)号：US5728641A

    公开(公告)日：1998-03-17

    申请号：US464655

    申请日：1995-06-21

    申请人： Fuyuki Aida ,  Yoshio Tajima ,  Kazuo Matsuura

    发明人： Fuyuki Aida ,  Yoshio Tajima ,  Kazuo Matsuura

    IPC分类号： C08F4/60 ,  C08F4/619 ,  C08F4/649 ,  C08F4/658 ,  C08F4/659 ,  C08F4/6592 ,  C08F10/00

    CPC分类号： C08F10/00 ,  C08F4/61904 ,  C08F4/61912 ,  C08F4/61916 ,  C08F4/65904 ,  Y10S526/943

    摘要： According to the present invention there are provided a catalyst component, a catalyst using the catalyst component and a process using the catalyst, for the preparation of olefin polymers high in molecular weight and relatively wide in molecular weight distribution, using an extremely small amount of a modified organoaluminum compound such as methylaluminoxane and in high yield. The catalyst component is prepared by contacting at least the following constituents (1), (2), (3) and (4) with one another: (1) a compound represented by the general formula Me.sup.1 R.sup.1.sub.p (OR.sup.2).sub.q X.sub.4-p-q where R.sup.1 and R.sup.2 are each independently a hydrocarbon group having 1 to 24 carbon atoms, X is a halogen atom, Me is Zr, Ti or Hf, p and q are each an integer in the ranges of 0.ltoreq.p.ltoreq.4 and 0.ltoreq.q.ltoreq.4, provided 0.ltoreq.p+q.ltoreq.4; (2) at least one compound selected from the group consisting of compounds represented by the following general formulas 1 to 4: General formula 1: Me.sup.2 R.sup.3.sub.m (OR.sup.4).sub.n X.sup.2.sub.z-m-n General formul 2: Me.sup.3 H.sub.2 R.sup.5.sub.3-a General formula 3: Me.sup.4 �Me.sup.3 H.sub.b R.sup.6.sub.c (OR.sup.7).sub.4-b-c !.sub.y General formula 4: ##STR1## where R.sup.3,R.sup.4, R.sup.5, R.sup.6, R.sup.7 and R.sup.8, which may be the same or different, are each independently a hydrocarbon group having 1 to 24 carbon atoms, Me.sup.2 is a Group 1, 2, 12 or 13 element in the Periodic Table of Elements, Me.sup.3 is a Group 13 element in the same Table, Me.sup.4 is a Group 1, 2, or 12 element in the same Table, X.sup.2 is a halogen atom, z is the valence of Me.sup.2, y is the valence of Me.sup.4, and m, n, a, b, c and d are each an integer in the ranges of 0.ltoreq.m.ltoreq.z, 0.ltoreq.n.ltoreq.z, provided 0.ltoreq.m+m.ltoreq.z, 0

    Catalyst component for the polymerization of olefins
    2.
    发明授权
    Catalyst component for the polymerization of olefins 失效
    用于烯烃聚合的催化剂组分

    公开(公告)号：US5556821A

    公开(公告)日：1996-09-17

    申请号：US276898

    申请日：1994-07-19

    申请人： Fuyuki Aida ,  Yoshio Tajima ,  Kazuo Matsuura

    发明人： Fuyuki Aida ,  Yoshio Tajima ,  Kazuo Matsuura

    IPC分类号： C08F4/60 ,  C08F4/642 ,  C08F4/659 ,  C08F4/6592 ,  C08F4/74 ,  C08F10/00 ,  B01J31/00

    CPC分类号： C08F10/00 ,  C08F4/65912 ,  C08F4/6592

    摘要： According to the present invention there is provide a catalyst capable of affording an olefin homopolymer or copolymer having a high molecular weight and a relatively wide molecular weight distribution, in high yield, using an extremely small amount of a modified organoaluminum compound (particularly methylaluminoxane).The catalyst comprises the modified organoaluminum compound and a catalyst component comprising the following compounds (1) and (2): (1) a compound represented by the general formula R.sub.p MX.sub.4-p where M is a transition metal of Group IVa in the Periodic Table, R is cyclopentadienyl, substituted cyclopentadienyl, indenyl, substituted indenyl, or an aralkyl group having 7 to 24 carbon atoms, provided Rs may be bonded together through an alkylene groups having 2 to 8 carbon atoms and/or silylene group, X is a halogen atom, a hydrogen atom or a hydrocarbon residue having 1 to 24 carbon atoms, and p is a number satisfying the condition of 1.ltoreq.p.ltoreq.4; and (2) a compound containing carbon-fluorine bond.

    摘要翻译： 根据本发明，提供能够以极少量的改性有机铝化合物（特别是甲基铝氧烷）以高产率提供具有高分子量和相对较宽分子量分布的烯烃均聚物或共聚物的催化剂。 催化剂包含改性的有机铝化合物和包含以下化合物（1）和（2）的催化剂组分：（1）由通式RpMX4-p表示的化合物，其中M是元素周期表中IVa族的过渡金属， R是环戊二烯基，取代的环戊二烯基，茚基，取代的茚基或具有7至24个碳原子的芳烷基，其中R 5可以通过具有2-8个碳原子和/或亚甲硅基的亚烷基键合在一起，X是卤素原子 ，氢原子或碳原子数为1〜24的烃残基，p为满足1≤n≤4的条件的数。 和（2）含有碳 - 氟键的化合物。

    Oligomerization catalysts and process using the same for the production of olefinic oligomers
    3.
    发明授权
    Oligomerization catalysts and process using the same for the production of olefinic oligomers 失效
    低聚催化剂及其制备烯烃低聚物的方法

    公开(公告)号：US5744678A

    公开(公告)日：1998-04-28

    申请号：US737077

    申请日：1996-11-01

    申请人： Fuyuki Aida ,  Takashi Nakano ,  Yoshio Tajima ,  Kazuo Matsuura

    发明人： Fuyuki Aida ,  Takashi Nakano ,  Yoshio Tajima ,  Kazuo Matsuura

    IPC分类号： B01J31/12 ,  B01J31/14 ,  B01J31/24 ,  C07C2/30 ,  C07C2/36 ,  C07C2/18 ,  C07C2/22

    CPC分类号： C07C2/36 ,  B01J31/143 ,  B01J31/24 ,  C07C2/30 ,  B01J2231/20 ,  B01J2531/847 ,  C07C2527/14 ,  C07C2531/02 ,  C07C2531/04 ,  C07C2531/14 ,  C07C2531/16 ,  C07C2531/24

    摘要： An oligomerization catalyst according to the invention comprises a nickel compound (A); an organophosphoric compound (B); an organoaluminum compound (C); and a compound of the group consisting of carbon-halogen bond-containing compounds, oxoacid and salts thereof, sulfonic acid and derivatives thereof, and compounds of any of the formulae QX.sup.4.sub.n, QR.sub.n, QR'.sub.n, QX.sup.4.sub.1 R.sub.m, QX.sup.4.sub.1 R'.sub.m, QR.sub.1 R'.sub.m, Q.sup.1 (BR.sub.4).sub.p and R"(BR.sub.4) wherein Q is an element of the group consisting of Mg, Ti, Zr, B and Sn, Q.sup.1 is an element of the group consisting of Li, Na, K, Ca and Zn, X.sup.4 is a halogen or hydrogen atom, R is a C.sub.1 -C.sub.12 hydrocarbon group, R' is a C.sub.1 -C.sub.12 oxygen-containing hydrocarbon group, R" is a C.sub.1 -C.sub.20 hydrocarbon group or an ammonium group, n is a valence of Q, l, m is a natural member that satisfied n=l+m, and p is a valence of Q.sup.1. This catalyst is useful for the production of alpha-olefinic oligomers.

    摘要翻译： PCT No.PCT / JP96 / 00532 Sec。 371日期：1996年11月1日 102（e）1996年11月1日PCT PCT 1996年3月6日PCT公布。 出版物WO96 / 27440 日本1996年9月12日根据本发明的低聚催化剂包含镍化合物（A）; 有机磷化合物（B）; 有机铝化合物（C）; 和由含碳 - 卤素键的化合物，含氧酸及其盐，磺酸及其衍生物组成的组的化合物，以及式QX4n，QRn，QR'n，QX41Rm，QX41R'm，QR1R' m，Q1（BR4）p和R“（BR4）其中Q是由Mg，Ti，Zr，B和Sn组成的组的元素，Q1是由Li，Na，K，Ca Zn，X4为卤素或氢原子，R为C1-C12烃基，R'为C1-C12含氧烃基，R“为C1-C20烃基或铵基，n为 Q，l，m的化合价是满足n = 1 + m的天然成员，p是Q1的化合价。 该催化剂可用于生产α-烯烃低聚物。

    Catalyst components for polymerization of olefins
    4.
    发明授权
    Catalyst components for polymerization of olefins 失效
    用于烯烃聚合的催化剂组分

    公开(公告)号：US5795839A

    公开(公告)日：1998-08-18

    申请号：US461604

    申请日：1995-06-05

    申请人： Naoki Kataoka ,  Yosuke Numao ,  Takashi Seki ,  Yoshio Tajima ,  Kazuo Matsuura

    发明人： Naoki Kataoka ,  Yosuke Numao ,  Takashi Seki ,  Yoshio Tajima ,  Kazuo Matsuura

    IPC分类号： C08F4/64 ,  C08F4/659 ,  C08F10/00 ,  C08F210/16

    CPC分类号： C08F10/00 ,  C08F210/16 ,  C08F4/65904 ,  C08F4/65912 ,  C08F4/65916 ,  Y10S526/901 ,  Y10S526/943

    摘要： A process for the polymerization of olefinic hydrocarbons is carried out in the presence of a catalyst comprising a catalyst component derived from reacting a compound of the formula Me.sup.1 R.sup.1.sub.n X.sup.1.sub.4-n, a compound of the formula Me.sup.2 R.sup.2.sub.m X.sup.2.sub.z-m, an organocyclic compound having two or more conjugated double bonds and a carrier of inorganic or polymeric material, and a modified organoaluminum compound having Al--O--Al bonds, the resulting polyolefins having a relatively wide molecular weight distribution, a relatively narrow composition distribution and increased bulk density.

    摘要翻译： 烯烃聚合方法是在催化剂存在下进行的，该催化剂包含催化剂组分，催化剂组分衍生自使式Me1R1nX14-n的化合物，式Me2R2mX2z-m的化合物，具有两个或更多个共轭 双键和无机或聚合物材料的载体和具有Al-O-Al键的改性有机铝化合物，所得聚烯烃具有相对较宽的分子量分布，相对窄的组成分布和增加的体积密度。

    Solid catalyst components for olefin polemerization and use thereof
    5.
    发明授权
    Solid catalyst components for olefin polemerization and use thereof 失效
    用于烯烃聚合的固体催化剂组分及其用途

    公开(公告)号：US5604170A

    公开(公告)日：1997-02-18

    申请号：US199561

    申请日：1994-02-22

    申请人： Akira Sano ,  Kunimichi Kubo ,  Kazuo Matsuura ,  Yoshio Tajima

    发明人： Akira Sano ,  Kunimichi Kubo ,  Kazuo Matsuura ,  Yoshio Tajima

    IPC分类号： C08F4/646 ,  C08F4/659 ,  C08F4/6592 ,  C08F10/00 ,  C08F110/06 ,  C08F210/16 ,  C08F4/64

    CPC分类号： C08F10/00 ,  C08F110/06 ,  C08F210/16 ,  C08F4/65904 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/65925

    摘要： An effective catalyst carrier for use in the polymerization of olefins is provided.Said carrier comprises particles of silicon oxide or aluminum oxide satisfying the following characteristics (A) to (E):(A) An average particle diameter as measured by the sieving method is in the range of 20 to 150 .mu.m.(B) A specific surface area as measured by the BET method is in the range of 150 to 600 m.sup.2 /g.(C) The volume of pores ranging in pore radius from 18 to 1,000 Angstroms as measured by the mercury penetration method is in the range of 0.3 to 2.0 cm.sup.3 /g.(D) An apparent specific gravity as measured according to JIS K6220-6.8 is not lower than 0.32.(E) After the particles classified in the range of between 53 .mu.m and 75 .mu.m by the sieving method have been subjected to an ultrasonic disintegration treatment at 40 KHz, 35 W, for 20 minutes, the proportion of 50 .mu.m or smaller particles, i.e., degree of ultrasonic disintegration, is not more than 30%.

    摘要翻译： 提供了一种用于烯烃聚合的有效催化剂载体。 所述载体包含满足以下特征（A）至（E）的氧化硅或氧化铝颗粒：（A）通过筛分方法测量的平均粒径为20-150μm。 （B）通过BET法测定的比表面积为150〜600m 2 / g的范围。 （C）通过水银渗透法测定的孔半径为18〜1000埃的孔的体积在0.3〜2.0cm 3 / g的范围内。 （D）根据JIS K6220-6.8测定的表观比重不低于0.32。 （E）通过筛分方法将分级在53μm至75μm范围内的颗粒在40KHz，35W，20分钟以上进行超声波分解处理，比例为50μm以上 颗粒，即超声崩解度不大于30％。

    Process for preparing polyolefins
    7.
    发明授权
    Process for preparing polyolefins 失效
    聚烯烃的制备方法

    公开(公告)号：US4288579A

    公开(公告)日：1981-09-08

    申请号：US102646

    申请日：1979-12-12

    申请人： Mitsuji Miyoshi ,  Yoshio Tajima ,  Kazuo Matsuura ,  Nobuyuki Kuroda ,  Mitsuo Matsuno

    发明人： Mitsuji Miyoshi ,  Yoshio Tajima ,  Kazuo Matsuura ,  Nobuyuki Kuroda ,  Mitsuo Matsuno

    IPC分类号： C08F4/00 ,  C08F4/60 ,  C08F4/64 ,  C08F10/00 ,  C08F4/02 ,  C08F10/06

    CPC分类号： C08F10/00 ,  Y10S526/906

    摘要： According to this invention there is provided a process for polymerizing or copolymerizing olefins using a catalyst consisting of:[A]a solid component obtained by contacting(1) a reaction product resulting from heat reaction of a magnesium oxide and an aluminum trihalide with(2) a titanium halide and/or an addition product of a titanium halide and an aromatic carboxylic acid ester, and[B]an organometallic compound and/or an addition product of an organometallic compound and an aromatic carboxylic acid ester,or alternatively, using a catalyst consisting of acid components [A] and [B] plus [C] an aromatic carboxylic acid ester.

    摘要翻译： 根据本发明，提供了一种使用由以下组成的催化剂聚合或共聚烯烃的方法：[A]通过使（1）由氧化镁和三卤化铝的热反应得到的反应产物与（2） ）卤化钛和/或卤化钛和芳族羧酸酯的加成产物，和[B]有机金属化合物和/或有机金属化合物和芳族羧酸酯的加成产物，或者使用 由酸组分[A]和[B] + [C]芳族羧酸酯组成的催化剂。

    Olefin polymerization catalyst and process for preparing polyolefins
    8.
    发明授权
    Olefin polymerization catalyst and process for preparing polyolefins 失效
    烯烃聚合催化剂和制备聚烯烃的方法

    公开(公告)号：US6077804A

    公开(公告)日：2000-06-20

    申请号：US858120

    申请日：1997-05-19

    申请人： Yoshio Tajima ,  Naoki Kataoka ,  Akira Sano ,  Kazuo Matsuura

    发明人： Yoshio Tajima ,  Naoki Kataoka ,  Akira Sano ,  Kazuo Matsuura

    IPC分类号： C08F4/642 ,  C08F4/60 ,  C08F4/652 ,  C08F4/658 ,  C08F4/659 ,  C08F4/6592 ,  C08F10/00

    CPC分类号： C08F10/00 ,  C08F4/65904 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/6592

    摘要： According to the present invention, there are provided a catalyst and a process for the preparation of polyolefins having a relatively wide molecular weight distribution, good particle properties, a narrow composition distribution in copolymerization and a high molecular weight and being less sticky. The catalyst is prepared by contacting the following constituents (1) to (4) with one another:(1) a compound represented by the general formula Me.sup.1 R.sup.1.sub.p (OR.sup.2).sub.q X.sub.4-p-q, where Me.sup.1 is Zr, Ti or Hf, R.sup.1 and R.sup.2 are each independently a hydrocarbon group having 1 to 24 carbon atoms, X is a halogen atom, p and q are each an integer in the ranges of 0.ltoreq.p.ltoreq.4 and 0.ltoreq.q.ltoreq.4 , provided 0.ltoreq.p+q.ltoreq.4;(2) a compound represented by the general formula Me.sup.2 R.sup.3.sub.m (OR.sup.4).sub.n X.sup.2.sub.z-m-n, where Me.sup.2 is a Group I-III element in the Periodic Table, R.sup.3 and R.sup.4 are each independently a hydrocarbon group having 1 to 24 carbon atoms, X.sup.2 is a halogen atom or a hydrogen atom, provided when X.sup.2 is a hydrogen atom, Me.sup.2 is a Group III element in the Periodic Table, z is the valence of Me.sup.2, m and n are each an integer in the ranges of 0.ltoreq.m.ltoreq.z, and 0.ltoreq.n.ltoreq.z, provided 0.ltoreq.m+n.ltoreq.z;(3) an organocyclic compound having conjugated double bonds; and(4) a modified organoaluminum compound containing Al--O--Al bond, and thereafter contacting the resulting contact reaction product with the following component (5):(5) an inorganic carrier and/or a particulate polymer carrier.

    摘要翻译： 根据本发明，提供了一种催化剂和制备具有较宽分子量分布，良好的颗粒性能，窄的共聚合成分布和高分子量且不易粘的聚烯烃的方法。 通过使下述成分（1）〜（4）彼此接触来制备催化剂：（1）由通式Me1R1p（OR2）qX4-pq表示的化合物，其中Me1为Zr，Ti或Hf，R1和R2 各自独立地为具有1〜24个碳原子的烃基，X为卤素原子，p和q各自为0≤p≤4且0≤q≤4的整数， 提供0