公开(公告)号：US3896047A

公开(公告)日：1975-07-22

申请号：US36755373

申请日：1973-06-06

Applicant: GEN ELECTRIC

Inventor： AYCOCK DAVID F ,  SLIVA DANIEL E

IPC: C07C27/22 ,  B01J23/00 ,  B01J31/20 ,  B01J31/40 ,  C07B61/00 ,  C07C27/00 ,  C07C29/156 ,  C07C45/50 ,  C07C67/00 ,  B01J11/02

CPC classification number: B01J31/1895 ,  B01J31/20 ,  B01J31/24 ,  B01J31/403 ,  B01J2231/321 ,  B01J2531/0211 ,  B01J2531/845 ,  C07C67/293 ,  Y02P20/584 ,  C07C69/14

Abstract: An improved process for recycling a cobalt hydroformylation catalyst from a hydroformylation reaction which comprises feeding a hydroformylation product into a mixing zone, adding water thereto, feeding the mixture of water and hydroformylation product into a settling zone where two phases are formed, the phase containing the cobalt hydroformylation catalyst is recycled into the hydroformylation reaction.

Abstract translation: 一种用于从加氢甲酰化反应中回收钴羰基化催化剂的改进方法，其包括将加氢甲酰化产物加入到混合区中，向其中加入水，将水和加氢甲酰化产物的混合物进料到形成两相的沉降区中， 钴氢甲酰胺

公开(公告)号：US3899574A

公开(公告)日：1975-08-12

申请号：US35292273

申请日：1973-04-20

Applicant: GEN ELECTRIC

Inventor： SLIVA DANIEL E ,  KRUTCHEN CHARLES M ,  SHADE RAY W

IPC: D01F9/21 ,  C01B31/02 ,  C01B31/04 ,  C01B31/07

CPC classification number: D01F9/21

Abstract: High strength graphite fiber or ribbon and a method for making them are provided involving the extrusion of a mixture of polyacetylene and an organic solvent, subjecting the extrudate to a preliminary heat treatment, and thereafter exposing the heat stabilized extrudate to temperatures up to about 3300*C while in an inert atmosphere and under tension.

Abstract translation: 提供高强度石墨纤维或带及其制备方法涉及挤出聚乙炔和有机溶剂的混合物，对挤出物进行预热处理，然后将热稳定的挤出物暴露于高达约3300℃的温度 而在惰性气氛和张力下。

公开(公告)号：US3928516A

公开(公告)日：1975-12-23

申请号：US31098972

申请日：1972-11-30

Applicant: GEN ELECTRIC

Inventor： SLIVA DANIEL E ,  SELLEY WILLIAM G

IPC: D01F6/02 ,  D01F9/21 ,  D01D5/04 ,  B05B3/00

CPC classification number: D01F9/21 ,  D01F6/02 ,  Y10S264/19

Abstract: A continuous method is provided for making polyacetylene fiber convertible to high strength carbonaceous products. A thin film evaporator is employed to devolatilize the reaction mixture at the termination of the oxidative coupling of diethynyl organo compounds. The concentrated reaction mixture can be spun into polyacetylene fibers in a continuous manner. The spun concentrate can be collected and employed to make graphite fibers useful in making composites.

Abstract translation: 提供了一种使聚乙炔纤维可转化成高强度碳质产品的连续方法。 在二乙炔基有机化合物的氧化偶联终止时，使用薄膜蒸发器使反应混合物脱挥发分。 浓缩的反应混合物可以连续纺成聚乙炔纤维。 可以收集纺丝浓缩物并用于制备用于制备复合材料的石墨纤维。

公开(公告)号：US3904547A

公开(公告)日：1975-09-09

申请号：US36755173

申请日：1973-06-06

Applicant: GEN ELECTRIC

Inventor： AYCOCK DAVID F ,  SLIVA DANIEL E

IPC: C07C27/22 ,  B01J23/00 ,  B01J31/20 ,  B01J31/40 ,  C07B61/00 ,  C07C27/00 ,  C07C29/156 ,  C07C45/50 ,  C07C67/00 ,  B01D15/06 ,  B01J37/00

CPC classification number: B01J31/1895 ,  B01J31/20 ,  B01J31/24 ,  B01J31/403 ,  B01J2231/321 ,  B01J2531/0211 ,  B01J2531/845 ,  C07C67/293 ,  Y02P20/584 ,  C07C69/14

Abstract: An improved process for recycling a cobalt hydroformylation catalyst from a hydroformylation reaction which comprises feeding a hydroformylation product into a separation zone wherein two phases are formed, a solvent phase containing the cobalt hydroformylation catalyst and another phase containing the catalyst and a hydroformylation compound; separating the catalyst from the hydroformylation compound in a countercurrent extractor; concentrating the catalyst in an evaporation zone and recycling it into the hydroformylation reaction.

Abstract translation: 一种用于从加氢甲酰化反应再循环钴加氢甲酰基化催化剂的改进方法，其包括将加氢甲酰化产物加入分离区，其中形成两相，含有羰基羰基化催化剂的溶剂相和含有催化剂的另一相和加氢甲酰化化合物; 在逆流萃取器中将催化剂与加氢甲酰化化合物分离; 将催化剂浓缩在蒸发区中并将其再循环到加氢甲酰化反应中。