摘要:
UNCURED, CURABLE, UNSATURATED POLYESTER RESIN COMPOSITIONS CONSISTING ESSENTIALLY OF AN UNSATURATED POLYESTER, AN ETHYLENICALLY UNSATURATED MONOMER SUCH AS STYREME OR A SIMILAR MONOMER, AND ABOUT 0.1-1.5 MOLE PERCENT OF AN INHIBITOR SELECTED FROM A GROUP CONSISTING OF TETRACH''OROCATECHOL, TETRACHIOROHYDROQUINONE, TETRABROMOCATECHOL, AND TETRABROMOOHYDROQUINONE HAVE SHELF LIVES IN EXCESS OF ABOUT 100 DAYS OF ABOUT 70*C.
摘要:
INHIBITORS, SUCH AS, 2-(2-AMINOETHYLAMINO)-5-NITROPYRIDINE, ARE ADDED TO UNCURED POLYESTER RESIN SYSTEMS TO PREVENT GELATION OF THOSE SYSTEMS WHEN THEY ARE STORED AT ROOM TEMPERATURE OR AT ELEVATED TEMPERATURES FOR PERIODS OF TIME IN EXCESS OF THREE YEARS. BETWEEN 0.5 AND 1.0 MOLE PERCENT INHIBITOR IS ADDED TO THE UNCURED POLYESTER SYSTEMS.
摘要:
Solid burn-resistant polymeric compositions are formed by reacting substances such as Cl(PNCl2)9PCl4 and (PNCl2)3 4 with epoxy resins to form PNCl2-epoxy pre polymers. These prepolymers are blended with orgainc liquid prepolymers such as phenolics, epoxies, polyurethanes and polyesters and the blends are cured to form fire resistant plastics, wherein initial P,N, and Cl contents are wholly retained. Those two components, i.e., PNCl2 component and epoxy resin are admixed with liquid organic prepolymers (and polymerization catalysts therefor) and the system is then cured, usually by heating, whereby the PNCl2-epoxy polymer is formed in situ along with the matrix polymer, or in some cases chemically bonded to the organic polymeric crosslinked plastic.
摘要:
INHIBITORS, SUCH AS, PHENAZINE ARE ADDED TO UNCURED POLYESTER RESIN SYSTEMS TO PREVENT GELATION OF THOSE SYSTEMS WHEN THEY ARE STORED AT ROOM TEMPERATURE OR A ELEVATED TEMPERATURE FOR PERIODS OF TIME IN EXCESS OF THREE YEARS. BETWEEN 0.5 AND 1.0 MOLE PERCENT INHIBITOR IS ADDED TO THE UNCURED POLYESTER SYSTEMS.
AND N IS ESSENTIALLY 0 OR GREATER (E.G., 0-20); AND (B) A POLYTHIOL, THE EQUIVALENT RATIO OF THE POLYENE TO POLYTHIOL BEING ABOUT 1:0.5-1.5; AND (C) A MEMBER SELECTED FROM A GROUP CONSISTING OF A MONOMERIC ACID HAVING THE FORMULA
H2C=C(-R)-COOH
WHERE R IS H, CH3 OR C2H5 OR A HOMOPOLYMER OR COPOLYMER OF SUCH MONOMERIC ACID HAVING AN AVERAGE MOLECULAR WEIGHT OF ABOUT 140-1000, THE GROUP MEMBER CONSTITUTING ABOUT 2-10% BY WEIGHT OF THE COMPOSITION. THE ABOVE COMPOSITION CAN CONTAIN AN EFFECTIVE AMOUNT OF A PHOTOCURING RATE ACCELERATOR.
摘要:
SOLID BURN-RESISTANT POLYMERIC COMPOSITIONS ARE FORMED BY REACTING SUBSTANCES SUCH AS C1(PNCL2)9PCL4 AND (PNCL2)3-4 WITH EPOXY RESINS TO FORM PNCL2-EPOXY PREPOLYMERS. THESE PREPOLYMERS ARE BLENDED WITH ORGANIC LIQUID PREPOLYMERS SUCH AS PHENOLICS, EPOXIES, POLYURETHANES AND POLYESTERS AND THE BLENDS ARE CURED TO FORM FIRE RESISTANT PLASTICS, WHEREIN INITIAL P, N, AND CL CONTENTS ARE WHOLLY RETAINED. THOSE TWO COMPONENTS, I.E., PNCL2 COMPONENT AND EPOXY RESIN ARE ADMIXED WITH LIQUID ORGANIC PREPOLYMERS (AND POLYMERIZATION CATALYSTS THEREFOR) AND THE SYSTEM IS THEN CURED, USUALLY BY HEATING, WHEREBY THE PNCL2-EPOXY POLYMER IS FORMED IN SITU ALONG WITH THE MATRIX POLYMER, OR IN SOME CASES CHEMICALLY BONDED TO THE ORGANIC POLYMERIC CROSS-LINKED PLASTIC.
摘要:
DIHYDROXYNAPHTHALENES ARE ADDED TO UNCURED POLYESTER RESIN SYSTEMS TO PREVENT GELATING OF THOSE SYSTEMS WHEN THEY ARE STORED AT ROOM TEMPERATURE OR AT ELEVATED TEMPERATURES FOR PERIODS OF TIME IN EXCESS OF THREE YEARS. BETWEEN 0.5 TO 1.0 MOLE PERCENT THE DIHYDROXYNAPHTHALENE IS ADDED TO THE UNCURED POLYESTER SYSTEMS.
摘要:
A FLOWABLE STABLE HIGH EXPANSION FOAM COMPOSITION BASED ON A UREA-FORMALDEHYDE RESIN IS PROVIDED HAVING GOOD STRENGHT PROPERTIES AND A RETARDED SETTING TIME. IN ADDITION A PROCESS OF FOAMING IS PROVIDED WHICH PRODUCES A HIGH STRENGTH, HIGH EXPANSION FOAM FROM A NUMBER OF FOAM SYSTEMS. THIS PROCESS ALSO ENABLES UMPROVED GENERATION AND TRANSPORT OF THE HIGH EXPANSION FOAMS THROUGH ENCLOSED AREAS BY INTERMITTENTLY FOAMING THE AQUEOUS PREFOAM COMPOSITION AND PASSING IT THROUGH AN ENCLOSED AREA.