Polyester resin composition with a long shelf life
    1.
    发明授权
    Polyester resin composition with a long shelf life 失效
    聚酯树脂组合物与长寿命寿命

    公开(公告)号:US3657387A

    公开(公告)日:1972-04-18

    申请号:US3657387D

    申请日:1970-04-29

    申请人: GRACE W R & CO

    IPC分类号: C08K5/136 C08F21/02 C08F45/58

    CPC分类号: C08K5/136 C08L67/06

    摘要: UNCURED, CURABLE, UNSATURATED POLYESTER RESIN COMPOSITIONS CONSISTING ESSENTIALLY OF AN UNSATURATED POLYESTER, AN ETHYLENICALLY UNSATURATED MONOMER SUCH AS STYREME OR A SIMILAR MONOMER, AND ABOUT 0.1-1.5 MOLE PERCENT OF AN INHIBITOR SELECTED FROM A GROUP CONSISTING OF TETRACH''OROCATECHOL, TETRACHIOROHYDROQUINONE, TETRABROMOCATECHOL, AND TETRABROMOOHYDROQUINONE HAVE SHELF LIVES IN EXCESS OF ABOUT 100 DAYS OF ABOUT 70*C.

    Burn-resistant plastic compositions
    3.
    发明授权
    Burn-resistant plastic compositions 失效
    耐烧塑料组合物

    公开(公告)号:US3867344A

    公开(公告)日:1975-02-18

    申请号:US37270171

    申请日:1971-02-16

    申请人: GRACE W R & CO

    IPC分类号: C08G59/40 C08G79/02 C08G30/14

    CPC分类号: C08G59/4071 C08G79/025

    摘要: Solid burn-resistant polymeric compositions are formed by reacting substances such as Cl(PNCl2)9PCl4 and (PNCl2)3 4 with epoxy resins to form PNCl2-epoxy pre polymers. These prepolymers are blended with orgainc liquid prepolymers such as phenolics, epoxies, polyurethanes and polyesters and the blends are cured to form fire resistant plastics, wherein initial P,N, and Cl contents are wholly retained. Those two components, i.e., PNCl2 component and epoxy resin are admixed with liquid organic prepolymers (and polymerization catalysts therefor) and the system is then cured, usually by heating, whereby the PNCl2-epoxy polymer is formed in situ along with the matrix polymer, or in some cases chemically bonded to the organic polymeric crosslinked plastic.

    摘要翻译: 通过将物质如Cl(PNCl 2)9 PCl 4和(PNCl 2)3-4与环氧树脂反应形成固体耐燃聚合物组合物以形成PNCl 2 - 环氧预聚物。 这些预聚物与有机液体预聚物如酚醛树脂,环氧树脂,聚氨酯和聚酯共混,并将共混物固化形成耐火塑料,其中初始的P,N和Cl含量被完全保留。 将这两种组分,即PNCl 2组分和环氧树脂与液体有机预聚物(及其聚合催化剂)混合,然后通常通过加热固化体系,由此PNCI-环氧聚合物与基质聚合物一起原位形成, 或在某些情况下化学键合到有机聚合物交联塑料上。

    Curable liquid composition of polyene,polymercaptan and acrylic acid
    6.
    发明授权
    Curable liquid composition of polyene,polymercaptan and acrylic acid 失效
    聚烯烃,聚氨酯和丙烯酸的可固化液体组合物

    公开(公告)号:US3662022A

    公开(公告)日:1972-05-09

    申请号:US3662022D

    申请日:1970-11-02

    申请人: GRACE W R & CO

    发明人: LARD EDWIN W

    IPC分类号: C08G75/04 C08G45/04 C08F27/06

    摘要: A CURABLE LIQUID COMPOSITION CONSISTING ESSENTIALLY OF; (A) A POLYENE HAVING THE FORMULA

    CH2=CH-CH2-N(-CH2-CH=CH2)-CH2-CH(-OH)-CH2-

    (O-(1,4-PHENYLENE)-C(-CH3)2-(1,4-PHENYLENE)-O-CH2-

    CH(-OH)-CH2)(N+1)-N(-CH2-CH=CH2)-CH2-CH=CH2

    AND N IS ESSENTIALLY 0 OR GREATER (E.G., 0-20); AND (B) A POLYTHIOL, THE EQUIVALENT RATIO OF THE POLYENE TO POLYTHIOL BEING ABOUT 1:0.5-1.5; AND (C) A MEMBER SELECTED FROM A GROUP CONSISTING OF A MONOMERIC ACID HAVING THE FORMULA

    H2C=C(-R)-COOH

    WHERE R IS H, CH3 OR C2H5 OR A HOMOPOLYMER OR COPOLYMER OF SUCH MONOMERIC ACID HAVING AN AVERAGE MOLECULAR WEIGHT OF ABOUT 140-1000, THE GROUP MEMBER CONSTITUTING ABOUT 2-10% BY WEIGHT OF THE COMPOSITION. THE ABOVE COMPOSITION CAN CONTAIN AN EFFECTIVE AMOUNT OF A PHOTOCURING RATE ACCELERATOR.

    Burn-resistant plastic compositions
    7.
    发明授权
    Burn-resistant plastic compositions 失效
    耐燃塑料组合物

    公开(公告)号:US3641193A

    公开(公告)日:1972-02-08

    申请号:US3641193D

    申请日:1969-04-17

    申请人: GRACE W R & CO

    IPC分类号: C08G59/40 C08G79/02 C08G45/06

    摘要: SOLID BURN-RESISTANT POLYMERIC COMPOSITIONS ARE FORMED BY REACTING SUBSTANCES SUCH AS C1(PNCL2)9PCL4 AND (PNCL2)3-4 WITH EPOXY RESINS TO FORM PNCL2-EPOXY PREPOLYMERS. THESE PREPOLYMERS ARE BLENDED WITH ORGANIC LIQUID PREPOLYMERS SUCH AS PHENOLICS, EPOXIES, POLYURETHANES AND POLYESTERS AND THE BLENDS ARE CURED TO FORM FIRE RESISTANT PLASTICS, WHEREIN INITIAL P, N, AND CL CONTENTS ARE WHOLLY RETAINED. THOSE TWO COMPONENTS, I.E., PNCL2 COMPONENT AND EPOXY RESIN ARE ADMIXED WITH LIQUID ORGANIC PREPOLYMERS (AND POLYMERIZATION CATALYSTS THEREFOR) AND THE SYSTEM IS THEN CURED, USUALLY BY HEATING, WHEREBY THE PNCL2-EPOXY POLYMER IS FORMED IN SITU ALONG WITH THE MATRIX POLYMER, OR IN SOME CASES CHEMICALLY BONDED TO THE ORGANIC POLYMERIC CROSS-LINKED PLASTIC.

    Stable high expansion foam composition and process of foaming
    9.
    发明授权
    Stable high expansion foam composition and process of foaming 失效
    稳定的高膨胀泡沫组合物和泡沫的过程

    公开(公告)号:US3554936A

    公开(公告)日:1971-01-12

    申请号:US3554936D

    申请日:1968-03-26

    申请人: GRACE W R & CO

    IPC分类号: C08J9/30 C08F47/10 C08J1/16

    CPC分类号: C08J9/30 C08J2361/24

    摘要: A FLOWABLE STABLE HIGH EXPANSION FOAM COMPOSITION BASED ON A UREA-FORMALDEHYDE RESIN IS PROVIDED HAVING GOOD STRENGHT PROPERTIES AND A RETARDED SETTING TIME. IN ADDITION A PROCESS OF FOAMING IS PROVIDED WHICH PRODUCES A HIGH STRENGTH, HIGH EXPANSION FOAM FROM A NUMBER OF FOAM SYSTEMS. THIS PROCESS ALSO ENABLES UMPROVED GENERATION AND TRANSPORT OF THE HIGH EXPANSION FOAMS THROUGH ENCLOSED AREAS BY INTERMITTENTLY FOAMING THE AQUEOUS PREFOAM COMPOSITION AND PASSING IT THROUGH AN ENCLOSED AREA.