公开(公告)号：US3691233A

公开(公告)日：1972-09-12

申请号：US3691233D

申请日：1971-01-13

Applicant: GULF RESEARCH DEVELOPMENT CO

Inventor： ELLIS ALAN F ,  SEEKIRCHER RICHARD

IPC: C07C51/25 ,  C07C51/00 ,  C07C51/32

CPC classification number: C07C51/25 ,  C07C53/126

Abstract: An improvement in a process for converting an unsaturated, acyclic hydrocarbon to a carboxylic acid in which the unsaturated, acyclic hydrocarbon is reacted with oxygen containing a small amount of ozone at a low temperature to obtain an intermediate product in a first stage and the intermediate product is oxidized in a second stage with molecular oxygen at a higher temperature to obtain the desired carboxylic acid, which involves employing a solvent mixture comprising a major amount of a carboxylic acid solvent having a boiling point as high or higher than the highest boiling point of a carboxylic acid formed during the reaction and a minor amount of lower carboxylic acid solvent or a lower alcohol solvent, whereby fogging during the first stage of the process is reduced.

公开(公告)号：US3910996A

公开(公告)日：1975-10-07

申请号：US27068472

申请日：1972-07-11

Applicant: GULF RESEARCH DEVELOPMENT CO

Inventor： ONOPCHENKO ANATOLI ,  SCHULZ JOHANN G D ,  SEEKIRCHER RICHARD

IPC: C07C45/36 ,  C07C51/265 ,  C07C63/04

CPC classification number: C07C51/265 ,  C07C45/36 ,  C07C63/04 ,  C07C65/32

Abstract: A process for selectively oxidizing the methyl substituent on a benzenoid structure carrying a nuclear methyl substituent and a higher alkyl substituent which involves heating the benzenoid structure with oxygen in the presence of cobaltic ions dissolved in a lower carboxylic acid solvent.

Abstract translation: 用于选择性氧化携带核甲基取代基的苯型结构上的甲基取代基和高级烷基取代基的方法，该方法涉及在溶解在低级羧酸溶剂中的钴离子存在下用氧加热苯类结构。

公开(公告)号：US3644512A

公开(公告)日：1972-02-22

申请号：US3644512D

申请日：1969-10-10

Applicant: GULF RESEARCH DEVELOPMENT CO

Inventor： ONOPCHENKO ANATOLI ,  SCHULZ JOHANN G D ,  SEEKIRCHER RICHARD

IPC: C07C51/215 ,  C07C53/08

CPC classification number: C07C51/215 ,  C07C53/08

Abstract: A PROCESS FOR CONVERTING BUTANE TO ACETIC ACID WHICH COMPRISES SUBJECTING BUTANE TO REACTION WITH MOLECULAR OXYGEN IN ACETIC ACID IN THE PRESENCE OF A COBALT COMPOUND SOLUBLE IN THE REACTION MIXTURE AND A XYLENE, SUCH AS PARA XYLENE.

公开(公告)号：US3641132A

公开(公告)日：1972-02-08

申请号：US3641132D

申请日：1969-01-23

Applicant: GULF RESEARCH DEVELOPMENT CO

Inventor： SCHULZ JOHANN G D ,  SEEKIRCHER RICHARD

IPC: C07C205/61 ,  C07C79/36 ,  C07C79/46

CPC classification number: C07C201/12 ,  C07C201/14 ,  C07C205/45 ,  C07C205/61

Abstract: A PROCESS FOR PREPARING NITRO BENZOPHENONES WHICH INVOLVES ADDING NITRIC ACID TO A DIARYLALKANE AND MAINTAINING THE RESULTING MIXTURE AT THE REACTION TEMPERATURE FOR A TIME SUFFICIENT TO CONVERT THE DIARYLALKANE TO THE CORRESPONDING NITRO BENZOPHENONE.

公开(公告)号：US3676489A

公开(公告)日：1972-07-11

申请号：US3676489D

申请日：1969-11-28

Applicant: GULF RESEARCH DEVELOPMENT CO

Inventor： ELLIS ALAN F ,  KRESGE ALFRED N ,  SEEKIRCHER RICHARD

IPC: C07C51/25 ,  C07C51/32

CPC classification number: C07C51/25 ,  C07C53/126

Abstract: An improvement in a process for converting an unsaturated, acyclic hydrocarbon to an acid in which the unsaturated, acyclic hydrocarbon is reacted with oxygen containing a small amount of ozone at a low temperature to obtain an intermediate product in a first stage and the intermediate product is oxidized in a second stage with molecular oxygen at a higher temperature to obtain the desired carboxylic acid, which involves heating the intermediate product in the absence of additional oxygen prior to the second stage oxidation, whereby explosive hazards in the second stage are minimized.

Abstract translation: 将不饱和的无环烃转化为酸的方法的改进，其中不饱和的非环状烃与低温下含有少量臭氧的氧反应，以获得第一阶段的中间产物，中间产物为 在第二阶段用分子氧在较高温度下氧化，得到所需的羧酸，其包括在第二阶段氧化之前在不存在额外的氧气的情况下加热中间产物，由此使第二阶段的爆炸危险最小化。

公开(公告)号：US3641136A

公开(公告)日：1972-02-08

申请号：US3641136D

申请日：1970-05-08

Applicant: GULF RESEARCH DEVELOPMENT CO

Inventor： ONOPCHENKO ANATOLI ,  SCHULZ JOHANN G D ,  SEEKIRCHER RICHARD

IPC: C07C51/265 ,  C07C63/02 ,  C07C65/20

CPC classification number: C07C51/265 ,  C07C63/331

Abstract: A PROCESS OF OXIDIZING A 1,1-BIS(ALKYLPHENYL)ALKANE TO CONVERT ALKYL SUBSTITUENTS TO CARBOXYLIC ACID SUBSTIUENTS WHICH INVOLVES CONTACTING THE 1,1-BIS(ALKYLPHENYL)ALKANE WITH OXYGEN IN A LOWER CARBOXYLIC ACID CONTAINING COBALT AND A METHYLENIC KETONE.

公开(公告)号：US3641135A

公开(公告)日：1972-02-08

申请号：US3641135D

申请日：1970-05-08

Applicant: GULF RESEARCH DEVELOPMENT CO

Inventor： ONOPCHENKO ANATOLI ,  SCHULZ JOHANN G D ,  SEEKIRCHER RICHARD

IPC: C07C51/265 ,  C07C63/02 ,  C07C65/20

CPC classification number: C07C51/265 ,  C07C63/331

Abstract: A PROCESS FOR OXIDIZING A 1,1-BIS(ALKYLPHENYL)ALKANE, WHEREIN THE ALKANE BRIDGE HAS AT LEAST TWO CARBON ATOMS, TO CONVERT ALKYL SUBSTITUENTS TO CARBOXYLIC ACID SUBSTITUENTS WHICH INVOLVES CONTACTING THE 1,1-BIS-(ALKYPHENYL) ALKANE WITH OXYGEN IN A LOWER CARBOXYLIC ACID CONTAINING COBALT AND AN ALIPHATIC HYDROCARBON HAVING FROM THREE TO SIX CARBON ATOMS.