公开(公告)号：US20070238846A1

公开(公告)日：2007-10-11

申请号：US11401171

申请日：2006-04-10

申请人： Gary Davis ,  James Mahood ,  Matthew Pixton ,  Niles Rosenquist ,  James Silva ,  Joshua Stone

发明人： Gary Davis ,  James Mahood ,  Matthew Pixton ,  Niles Rosenquist ,  James Silva ,  Joshua Stone

IPC分类号： C08G77/448 ,  C08L83/04

CPC分类号： C08G64/186 ,  C08G77/448 ,  C08L83/10

摘要： Disclosed herein are polysiloxane-polycarbonate copolymer articles. In one embodiment, a ⅛th inch thick bar formed from the thermoplastic composition has a B-Y ratio of less than or equal to about 1.75. This article, which has a dimension that is greater than or equal to 1.5 cm, comprises the thermoplastic composition which comprises a polysiloxane-polycarbonate copolymer, wherein the copolymer comprises repeating diorganosiloxane units of formula (1): wherein each R is, independently, a C1-13 monovalent organic group; and E has an average value of 20 to 35.

摘要翻译： 本文公开的是聚硅氧烷 - 聚碳酸酯共聚物制品。 在一个实施方案中，由热塑性组合物形成的1/8英寸厚的棒具有小于或等于约1.75的B-Y比。 具有大于或等于1.5cm的尺寸的该制品包含包含聚硅氧烷 - 聚碳酸酯共聚物的热塑性组合物，其中所述共聚物包含重复式（1）的二有机硅氧烷单元：其中每个R独立地为 C 1-13 一价有机基团; E的平均值为20〜35。

公开(公告)号：US20070155945A1

公开(公告)日：2007-07-05

申请号：US11324949

申请日：2006-01-04

申请人： Gary Davis ,  James Mahood ,  James Silva ,  Joshua Stone

发明人： Gary Davis ,  James Mahood ,  James Silva ,  Joshua Stone

IPC分类号： C08G64/00

CPC分类号： C08G64/1608 ,  C08G63/64 ,  C08G64/186 ,  Y10T428/31504 ,  Y10T428/31507 ,  Y10T428/31855

摘要： A polycarbonate such as aliphatic/aromatic polycarbonate comprises repeating structural carbonate units of the formula (H-1): in which Rh is a radical having the formula (H-2): wherein each of R11, R12, R13, R14, R15, R16, R17, R18, R19, R20, R21, R22, R23, R24, R25, R26, R27, and R28 is independently a hydrogen, a C1-C6 alkyl group, or a halogen substituted C1-C6 alkyl group. The polycarbonate, and a thermoplastic composition thereof, have improved thermal stability, cost-effectiveness, and exhibit improved manufacturability such as, for example, minimum cyclic carbonate formation and minimum amine acceptor requirement.

摘要翻译： 聚碳酸酯如脂族/芳族聚碳酸酯包括重复式（H-1）的结构碳酸酯单元：其中R hh是具有式（H-2）的基团：其中R' R 11，R 12，R 13，R 14，R 15，R 15， R 16，R 17，R 18，R 19，R 20，R 17， R 21，R 22，R 23，R 24，R 25，R 24， R 26，R 27和R 28独立地是氢，C 1 -C 6烷基， 烷基，或卤素取代的C 1 -C 6烷基。 聚碳酸酯及其热塑性组合物具有改进的热稳定性，成本效益，并且显示出改进的可制造性，例如最小的环状碳酸酯形成和最小的胺受体要求。

公开(公告)号：US20060084822A1

公开(公告)日：2006-04-20

申请号：US10968773

申请日：2004-10-19

申请人： Gary Davis ,  Joshua Stone ,  James Silva ,  James Mahood ,  David Dardaris

发明人： Gary Davis ,  Joshua Stone ,  James Silva ,  James Mahood ,  David Dardaris

IPC分类号： C07C69/96

CPC分类号： C07D493/04 ,  C07C68/02 ,  C07J9/00 ,  C08G64/1608 ,  C08G64/24 ,  C08G64/28 ,  C07C69/96

摘要： A method for preparing an aliphatic chloroformate comprising, introducing a mixture of at least one aliphatic hydroxyl compound, phosgene, at least one solvent, and optionally at least one organic base into a flow reactor to obtain a unidirectional flowing reaction mixture. The at least one aliphatic hydroxyl compound comprises at least one aliphatic hydroxyl group. The unidirectional flowing reaction mixture is maintained at a temperature between about 0° C. and about 60° C. to produce a single product stream comprising an aliphatic chloroformate.

摘要翻译： 一种制备脂族氯甲酸酯的方法，包括将至少一种脂族羟基化合物，光气，至少一种溶剂和任选的至少一种有机碱的混合物引入流动反应器中以获得单向流动的反应混合物。 所述至少一种脂族羟基化合物包含至少一个脂族羟基。 将单向流动反应混合物保持在约0℃至约60℃之间的温度下，以产生包含脂族氯甲酸酯的单一产物流。

公开(公告)号：US5514742A

公开(公告)日：1996-05-07

申请号：US383043

申请日：1995-02-03

申请人： Pamela Gardner ,  James Mahood

发明人： Pamela Gardner ,  James Mahood

IPC分类号： C08K5/17 ,  C08K5/52 ,  C08K5/524 ,  C08K5/527 ,  C08L101/00 ,  C08K5/526

CPC分类号： C08K5/527 ,  C08K5/17

摘要： A polymer composition is provided comprising an ultraviolet light sensitive phosphite and an amount of a polyamine effective to enhance the resistance of the color formation upon exposure to ultraviolet light. A process is also provided for applying ink to a thermoplastic substrate involving ultraviolet light curing of the ink. The thermoplastic compositions are useful for making article which contain UV sensitive phosphites for oxidative stability and also exhibit resistance to ultraviolet light yellowing of the phosphite. The inking process resists detrimental yellowing of the composition upon exposure to high levels of ultraviolet light radiation.

摘要翻译： 提供了一种聚合物组合物，其包含紫外光敏感的亚磷酸酯和一定量的多胺，其有效地增强了暴露于紫外光下的着色性能。 还提供了一种用于将油墨施加到涉及墨水的紫外光固化的热塑性基材上的方法。 热塑性组合物可用于制备含有紫外线敏感的亚磷酸酯用于氧化稳定性的物品，并且还表现出对亚磷酸盐的紫外线光黄变的抗性。 上墨过程在暴露于高水平的紫外线辐射时抵抗组合物的有害黄化。

公开(公告)号：US5424348A

公开(公告)日：1995-06-13

申请号：US307545

申请日：1994-09-16

申请人： James Mahood

发明人： James Mahood

IPC分类号： B29C47/68 ,  C07F9/6571 ,  C07F9/6574 ,  C08J9/18 ,  C08K5/52 ,  C08K5/526 ,  C08K5/527 ,  C08L101/00 ,  D01F1/10 ,  D01F6/04 ,  D01F6/06

CPC分类号： C08J9/18 ,  C07F9/65742 ,  C08K5/527 ,  D01F1/10 ,  D01F6/04 ,  D01F6/06 ,  C08J2323/02

摘要： A phosphite is provided having the formula: ##STR1## wherein Y.sup.1 is an alkyl group and Y.sup.2 is selected from the group consisting of sec-butyl and tert-butyl. The phosphite exhibits enhanced stability including hydrolytic and UV stability, and is useful in stabilizing thermoplastic compositions.

摘要翻译： 提供了具有下式的亚磷酸酯：其中Y 1是烷基，Y 2选自仲丁基和叔丁基。 亚磷酸酯表现出增强的稳定性，包括水解和UV稳定性，并且可用于稳定热塑性组合物。

公开(公告)号：US20070100113A1

公开(公告)日：2007-05-03

申请号：US11261279

申请日：2005-10-28

申请人： Jan Kamps ,  Jan-Pleun Lens ,  James Mahood ,  A.S. Radhakrishna ,  T. Raj ,  Ravindra Singh

发明人： Jan Kamps ,  Jan-Pleun Lens ,  James Mahood ,  A.S. Radhakrishna ,  T. Raj ,  Ravindra Singh

IPC分类号： C08G18/00 ,  C08G64/00

CPC分类号： C08G64/14 ,  C08G63/64 ,  C08G64/06 ,  C08G64/24 ,  C08G64/28

摘要： A polycarbonate comprises structural units derived from a polycyclic dihydroxy compound of Formula (I) wherein R1 is selected from the group consisting of a cyano functionality, a nitro functionality, an aliphatic functionality having 1 to 10 carbons, an aliphatic ester functionality having 2 to 10 carbons, a cycloaliphatic ester functionality having 4 to 10 carbons and an aromatic ester functionality having 4 to 10 carbons; R2 is selected from the group consisting of a cyano functionality, a nitro functionality, an aliphatic ester functionality having 2 to 10 carbons, a cycloaliphatic ester functionality having 4 to 10 carbons and an aromatic ester functionality having 4 to 10 carbons; and R3 and R4 are independently at each occurrence a hydrogen, an aliphatic functionality having 1 to 10 carbons or a cycloaliphatic functionality having 3 to 10 carbons.

摘要翻译： 聚碳酸酯包括衍生自式（I）的多环二羟基化合物的结构单元，其中R 1选自氰基官能团，硝基官能团，具有1至10个碳的脂族官能团， 具有2至10个碳的脂族酯官能团，具有4至10个碳的脂环族酯官能团和具有4至10个碳的芳族酯官能团; R 2选自氰基官能团，硝基官能团，具有2至10个碳的脂族酯官能团，具有4至10个碳的脂环族酯官能团和具有4个碳原子的芳族酯官能团 至10个碳; R 3和R 4在每次出现时独立地为氢，具有1至10个碳的脂族官能团或具有3至10个碳的脂环族官能团。

公开(公告)号：US20070123688A1

公开(公告)日：2007-05-31

申请号：US11291195

申请日：2005-11-30

申请人： James Mahood ,  Jon Malinoski

发明人： James Mahood ,  Jon Malinoski

IPC分类号： C08G64/00

CPC分类号： C08G64/12 ,  C08G64/28

摘要： A copolycarbonate of the formula wherein 5 to 75 mole percent of the total number of R1 groups is derived from a high Tg monomer of formula (2) wherein R2 and R3 are each independently a halogen or a C1-6 alkyl group, R4 is a methyl or phenyl, and c is 0 to 4; and 25 to 95 mole percent of the R1 groups are derived from a dihydroxy compound of formula HO—R5—OH, wherein at least 60% of the R5 groups are aromatic, and the dihydroxy compound of formula (3) is not the same as the high Tg monomer of formula (2), and wherein the copolycarbonate comprises at least 10% fewer carbonate linkages of formula (4) than would be theoretically obtained in a random copolymer made from the same ratio of the high Tg monomer of formula (2) and the dihydroxy compound of formula (3).

摘要翻译： 一种下式的共聚碳酸酯，其中R 1〜5个基团总数的5〜75摩尔％来自式（2）的高Tg单体，其中R 2和R 2 3个独立地为卤素或C 1-6烷基，R 4为甲基或苯基，c为0至4 ; 并且25至95摩尔％的R 1基团衍生自式HO-R 5 -OH的二羟基化合物，其中至少60％的R“ > 5个基团是芳族的，并且式（3）的二羟基化合物与式（2）的高Tg单体不同，并且其中共聚碳酸酯包含至少10％的式（4）的碳酸酯键 ）比在式（2）的高Tg单体和式（3）的二羟基化合物的相同比例制备的无规共聚物中理论上获得。

公开(公告)号：US06462146B2

公开(公告)日：2002-10-08

申请号：US09681379

申请日：2001-03-27

申请人： James Mahood

发明人： James Mahood

IPC分类号： C08L6900

CPC分类号： C08G64/24 ,  C08G64/06 ,  C08L69/00

摘要： Copolymers of BPA and menthane bisphenols such as BPT1 and BPT2 can be used as a compatabilizer to allow the formation of homogeneous blends of BPA with menthane bisphenol polycarbonates such as poly-BPT1 or poly-BPT2 or copolymers thereof. Thus, a compatible polycarbonate blend is made by combining a bisphenol A polycarbonate, a menthane bisphenol polycarbonate and a BPA/menthane bisphenol copolymer compatabilizer, and mixing the combined materials to form a blend. The compatabilizer may contain one or more species of menthane bisphenol. In a specific example, BPT1 and BPT2 are used in the compatabilizer in a ratio, BPT1/BPT2, in the range of 70/30 to 10/90, preferably less than or equal to 1/1, for example around 30/70. By adjusting the relative amounts and the properties of the bisphenol A polycarbonate and the menthane bisphenol polycarbonate, the glass transition temperature and the toughness of the blend can be selected.

摘要翻译： BPA和薄荷烷双酚（如BPT1和BPT2）的共聚物可以用作一种组合物，以使BPA与薄荷烷双酚聚碳酸酯如聚-BPT1或聚-BPT2或其共聚物的均匀共混物形成。 因此，通过组合双酚A聚碳酸酯，薄荷烷双酚聚碳酸酯和BPA /薄荷烷双酚共聚物混合物制备相容的聚碳酸酯共混物，并混合组合的材料以形成共混物。 化合物可以含有一种或多种薄荷烷双酚。 在具体实例中，BPT1和BPT2以比例BPT1 / BPT2在70/30至10/90，优选小于或等于1/1，例如约30/70的比例用于配制剂。 通过调节双酚A聚碳酸酯和薄荷烷双酚聚碳酸酯的相对量和性能，可以选择共混物的玻璃化转变温度和韧性。

公开(公告)号：US20070260033A1

公开(公告)日：2007-11-08

申请号：US11693314

申请日：2007-03-29

申请人： Jan Kamps ,  Jan-Pleun Lens ,  James Mahood ,  Arakali Radhakrishna ,  T. Raj ,  Ravindra Singh

发明人： Jan Kamps ,  Jan-Pleun Lens ,  James Mahood ,  Arakali Radhakrishna ,  T. Raj ,  Ravindra Singh

IPC分类号： C08G64/04

CPC分类号： C07C69/757 ,  C07C45/69 ,  C07C45/74 ,  C07C67/343 ,  C07C67/347 ,  C07C2601/14 ,  C08G64/14 ,  C07C49/223

摘要： Disclosed herein is a process for preparing a polymer comprising structural units derived from polycyclic dihydroxy compound having Formula (I), wherein R1 is selected from the group consisting of a cyano functionality, a nitro functionality, an aliphatic functionality having 1 to 10 carbons, an aliphatic ester functionality having 2 to 10 carbons, a cycloaliphatic ester functionality having 4 to 10 carbons and an aromatic ester functionality having 4 to 10 carbons; R2 is selected from the group consisting of a cyano functionality, a nitro functionality, an aliphatic ester functionality having 2 to 10 carbons, a cycloaliphatic ester functionality having 4 to 10 carbons and an aromatic ester functionality having 4 to 10 carbons; and each R3 and R4, at each occurrence, can be the same or different and are independently at each occurrence an aliphatic functionality having 1 to 10 carbons or a cycloaliphatic functionality having 3 to 10 carbons, “n” is an integer having a value 0 to 4 and “m” is an integer having a value 0 to 4. The process comprises subjecting a polycyclic dihydroxy compound of Formula (I) to polymerization.

摘要翻译： 本文公开了一种制备包含衍生自具有式（I）的多环二羟基化合物的结构单元的聚合物的方法，其中R 1选自氰基官能团，硝基官能团，脂族基团 具有1至10个碳的官能团，具有2至10个碳的脂族酯官能团，具有4至10个碳的脂环族酯官能团和具有4至10个碳的芳族酯官能团; R 2选自氰基官能团，硝基官能团，具有2至10个碳的脂族酯官能团，具有4至10个碳的脂环族酯官能团和具有4个碳原子的芳族酯官能团 至10个碳; 并且每次出现时，每个R 3和R 4可以相同或不同，并且在每次出现时独立地为具有1至10个碳的脂族官能团或脂环族官能团 具有3至10个碳，“n”是0至4的整数，“m”是0至4的整数。该方法包括使式（I）的多环二羟基化合物进行聚合。

公开(公告)号：US20070213498A1

公开(公告)日：2007-09-13

申请号：US11372804

申请日：2006-03-10

申请人： James Mahood

发明人： James Mahood

IPC分类号： C08G64/00

CPC分类号： C08G64/04 ,  C08G64/28

摘要： A copolycarbonate of the formula wherein 5 to 50 mole percent of the total number of R1 groups is derived from a monomer of formula (2) wherein each Rf is independently at each occurrence a halogen atom, a hydrocarbon group having 1 to 10 carbons, or a halogen substituted hydrocarbon group having 1 to 10 carbons, and n is 0 to 4; and 50 to 95 mole percent of the R1 groups are derived from a dihydroxy compound of formula HO—R5—OH, wherein at least 60% of the R5 groups are aromatic, and the dihydroxy compound of formula (3) is not a compound of formula (2), and wherein the copolycarbonate comprises at least 10% fewer carbonate linkages of formula (4) than would be theoretically obtained in a random copolymer made from the same ratio of the monomer of formula (2) and the dihydroxy compound of formula (3).

摘要翻译： 一种下式的共聚碳酸酯，其中R 1〜5个基团总数的5〜50摩尔％来自式（2）的单体，其中每个R f独立地为 每个出现卤原子，碳原子数为1〜10的烃基或碳数为1〜10的卤素取代烃基，n为0〜4。 并且50至95摩尔％的R 1基团衍生自式HO-R 5 -OH的二羟基化合物，其中至少60％的R 0 > 5个基团是芳族的，并且式（3）的二羟基化合物不是式（2）的化合物，并且其中共聚碳酸酯包括比理论上更少的式（4）的碳酸酯键的至少10％ 由与式（2）的单体和式（3）的二羟基化合物的比例相同的无规共聚物获得。