公开(公告)号：US07528214B2

公开(公告)日：2009-05-05

申请号：US11261262

申请日：2005-10-28

申请人： Gautam Chatterjee ,  Patrick J. McCloskey ,  Warren W. Reilly ,  William D. Richards ,  Subash Scindia ,  Gokul Srinivasan ,  Yatin Tayalia

发明人： Gautam Chatterjee ,  Patrick J. McCloskey ,  Warren W. Reilly ,  William D. Richards ,  Subash Scindia ,  Gokul Srinivasan ,  Yatin Tayalia

IPC分类号： C08G63/02 ,  C08G63/00

CPC分类号： C08G64/04 ,  C08G64/12 ,  C08G64/14 ,  C08G64/307 ,  C08G64/403

摘要： A method for producing a transparent article comprises the steps of melt transesterifying a monomer mixture in the presence of a transesterification catalyst to produce a hydroquinone polycarbonate copolymer product comprising greater than 45 mole percent of structural units derived from the hydroquinone. The monomer mixture comprises a hydroquinone, at least one aromatic dihydroxy compound other than the hydroquinone, and a carbonic acid diester. The hydroquinone polycarbonate copolymer product is then heated to a highest processing temperature of 5° C. to 20° C. above a maximum melting melt temperature for the hydroquinone copolymer product for a sufficient period of time to render the hydroquinone polycarbonate copolymer product transparent upon cooling to ambient temperature; and cooling the hydroquinone polycarbonate copolymer product to produce the transparent article. The method can also be used for producing transparent hydroquinone polycarbonate copolymers, which can be used for producing the transparent articles.

摘要翻译： 制备透明制品的方法包括在酯交换催化剂存在下熔融酯交换单体混合物以产生包含大于45摩尔％的衍生自对苯二酚的结构单元的氢醌聚碳酸酯共聚物产物的步骤。 单体混合物包含氢醌，至少一种除氢醌以外的芳族二羟基化合物和碳酸二酯。 然后将对苯二酚聚碳酸酯共聚物产物加热至高于氢醌共聚物产物的最大熔融熔融温度的5℃至20℃的最高加工温度足够的时间以使氢醌聚碳酸酯共聚物产品在冷却时透明 到环境温度; 并冷却氢醌聚碳酸酯共聚物产物以制备透明制品。 该方法也可用于生产可用于生产透明制品的透明氢醌聚碳酸酯共聚物。

公开(公告)号：US20070100118A1

公开(公告)日：2007-05-03

申请号：US11261262

申请日：2005-10-28

申请人： Gautam Chatterjee ,  Patrick McCloskey ,  Warren Reilly ,  William Richards ,  Subash Scindia ,  Gokul Srinivasan ,  Yatin Tayalia

发明人： Gautam Chatterjee ,  Patrick McCloskey ,  Warren Reilly ,  William Richards ,  Subash Scindia ,  Gokul Srinivasan ,  Yatin Tayalia

IPC分类号： C08G64/00

CPC分类号： C08G64/04 ,  C08G64/12 ,  C08G64/14 ,  C08G64/307 ,  C08G64/403

摘要： A method for producing a transparent article comprises the steps of melt transesterifying a monomer mixture in the presence of a transesterification catalyst to produce a hydroquinone polycarbonate copolymer product comprising greater than 45 mole percent of structural units derived from the hydroquinone. The monomer mixture comprises a hydroquinone, at least one aromatic dihydroxy compound other than the hydroquinone, and a carbonic acid diester. The hydroquinone polycarbonate copolymer product is then heated to a highest processing temperature of 5° C. to 20° C. above a maximum melting melt temperature for the hydroquinone copolymer product for a sufficient period of time to render the hydroquinone polycarbonate copolymer product transparent upon cooling to ambient temperature; and cooling the hydroquinone polycarbonate copolymer product to produce the transparent article. The method can also be used for producing transparent hydroquinone polycarbonate copolymers, which can be used for producing the transparent articles.

摘要翻译： 制备透明制品的方法包括在酯交换催化剂存在下熔融酯交换单体混合物以产生包含大于45摩尔％的衍生自对苯二酚的结构单元的氢醌聚碳酸酯共聚物产物的步骤。 单体混合物包含氢醌，至少一种除氢醌以外的芳族二羟基化合物和碳酸二酯。 然后将对苯二酚聚碳酸酯共聚物产物加热至高于氢醌共聚物产物的最大熔融熔融温度的5℃至20℃的最高加工温度足够的时间以使氢醌聚碳酸酯共聚物产品在冷却时透明 到环境温度; 并冷却氢醌聚碳酸酯共聚物产物以制备透明制品。 该方法也可用于生产可用于生产透明制品的透明氢醌聚碳酸酯共聚物。

公开(公告)号：US20070123682A1

公开(公告)日：2007-05-31

申请号：US11288995

申请日：2005-11-29

申请人： T. Raj ,  A.S. Radhakrishna ,  Jan-Pleun Lens ,  Subrahmanya K. ,  Umesh Hasyagar ,  Subash Scindia

发明人： T. Raj ,  A.S. Radhakrishna ,  Jan-Pleun Lens ,  Subrahmanya K. ,  Umesh Hasyagar ,  Subash Scindia

IPC分类号： C08G18/00 ,  C08G64/00

CPC分类号： C08G63/64 ,  C08G59/26 ,  C08G63/6856 ,  C08G64/12

摘要： A polymer comprising structural units derived from a polycyclic dihydroxy compound of Formula (I) wherein R1, R2 and R3 are independently at each occurrence selected from the group consisting of a cyano functionality, a halogen, an aliphatic functionality having 1 to 10 carbons, a cycloaliphatic functionality having 3 to 10 carbons, and an aromatic functionality having 6 to 10 carbons; wherein each occurrence of “n”, “m”, and “p” independently has a value of 0, 1, 2, 3, or 4; and wherein the polymer is substantially linear.

摘要翻译： 包含衍生自式（I）的多环二羟基化合物（其中R 1，R 2和R 3）的结构单元的聚合物各自独立地 选自氰基官能团，卤素，具有1至10个碳的脂族官能团，具有3至10个碳的脂环族官能团和具有6至10个碳的芳族官能团; 其中每次出现的“n”，“m”和“p”独立地具有0,1,2,3或4的值; 并且其中所述聚合物基本上是线性的。

公开(公告)号：US07375177B2

公开(公告)日：2008-05-20

申请号：US11289210

申请日：2005-11-29

申请人： Nagarajan Arumugam ,  Radhakrishna Arakali Srinivasarao ,  Jan Pleun Lens ,  Tilak Raj ,  Binod Sahoo ,  Subash Scindia

发明人： Nagarajan Arumugam ,  Radhakrishna Arakali Srinivasarao ,  Jan Pleun Lens ,  Tilak Raj ,  Binod Sahoo ,  Subash Scindia

IPC分类号： C08G64/00

CPC分类号： C08G64/12 ,  C08G63/6856 ,  C08G64/14 ,  C08G71/04

摘要： A polymer comprising at least one structural unit derived from a dihydroxy compound of Formula (I) wherein R1 is an aromatic divalent functionality having 6 to 60 carbons, R2 can be the same or different at each occurrence and is independently at each occurrence selected from the group consisting of a cyano functionality, a nitro functionality, a halogen, an aliphatic functionality having 1 to 10 carbons, a cycloaliphatic functionality having 3 to 10 carbons and an aromatic functionality having 6 to 10 carbons and “n” is an integer having a value 0 to 3.

摘要翻译： 包含衍生自式（I）的二羟基化合物的至少一种结构单元的聚合物，其中R 1是具有6至60个碳的芳族二价官能团，R 2 2可以是 在每次出现时相同或不同，并且在每次出现时独立地选自氰基官能度，硝基官能度，卤素，具有1至10个碳的脂族官能团，具有3至10个碳的脂环族官能团和芳族 具有6至10个碳的官能团和“n”是0至3的整数。

公开(公告)号：US07642335B2

公开(公告)日：2010-01-05

申请号：US11830216

申请日：2007-07-30

申请人： Subash Scindia ,  Subarna Shyamroy

发明人： Subash Scindia ,  Subarna Shyamroy

IPC分类号： C08G65/38 ,  C08G64/00

CPC分类号： C08G64/081 ,  Y10T428/31504 ,  Y10T428/31507

摘要： An aromatic polycarbonate having a high refractive index and good processing and mechanical properties is provided. The aromatic polycarbonate comprises a thiodiphenol monomer and a biphenyl monomer. The refractive index of the polycarbonate may be greater than 1.670.

摘要翻译： 提供了具有高折射率和良好加工性能和机械性能的芳族聚碳酸酯。 芳族聚碳酸酯包括硫代二酚单体和联苯单体。 聚碳酸酯的折射率可以大于1.670。

公开(公告)号：US20070123683A1

公开(公告)日：2007-05-31

申请号：US11289210

申请日：2005-11-29

申请人： Nagarajan Arumugam ,  Radhakrishna As ,  Jan Lens ,  Tilak Raj ,  Binod Sahoo ,  Subash Scindia

发明人： Nagarajan Arumugam ,  Radhakrishna As ,  Jan Lens ,  Tilak Raj ,  Binod Sahoo ,  Subash Scindia

IPC分类号： C08G18/00 ,  C08G64/00

CPC分类号： C08G64/12 ,  C08G63/6856 ,  C08G64/14 ,  C08G71/04

摘要： A polymer comprising at least one structural unit derived from a dihydroxy compound of Formula (I) wherein R1 is an aromatic divalent functionality having 6 to 60 carbons, R2 can be the same or different at each occurrence and is independently at each occurrence selected from the group consisting of a cyano functionality, a nitro functionality, a halogen, an aliphatic functionality having 1 to 10 carbons, a cycloaliphatic functionality having 3 to 10 carbons and an aromatic functionality having 6 to 10 carbons and “n” is an integer having a value 0 to 3.

摘要翻译： 包含衍生自式（I）的二羟基化合物的至少一种结构单元的聚合物，其中R 1是具有6至60个碳的芳族二价官能团，R 2 2可以是 在每次出现时相同或不同，并且在每次出现时独立地选自氰基官能度，硝基官能度，卤素，具有1至10个碳的脂族官能团，具有3至10个碳的脂环族官能团和芳族 具有6至10个碳的官能团和“n”是0至3的整数。

公开(公告)号：US20090036633A1

公开(公告)日：2009-02-05

申请号：US11830216

申请日：2007-07-30

申请人： Subash Scindia ,  Subarna Shyamroy

发明人： Subash Scindia ,  Subarna Shyamroy

IPC分类号： C08G75/28 ,  C08G65/40

CPC分类号： C08G64/081 ,  Y10T428/31504 ,  Y10T428/31507

摘要： An aromatic polycarbonate having a high refractive index and good processing and mechanical properties is provided. The aromatic polycarbonate comprises a thiodiphenol monomer and a biphenyl monomer. The refractive index of the polycarbonate may be greater than 1.670.

摘要翻译： 提供了具有高折射率和良好加工性能和机械性能的芳族聚碳酸酯。 芳族聚碳酸酯包括硫代二酚单体和联苯单体。 聚碳酸酯的折射率可以大于1.670。

公开(公告)号：US07425603B2

公开(公告)日：2008-09-16

申请号：US11288995

申请日：2005-11-29

申请人： T. Tilak Raj ,  Radhakrishna Arakali Srinivasarao ,  Jan-Pleun Lens ,  Subrahmanya Bhat K. ,  Umesh Hasyagar ,  Subash Scindia

发明人： T. Tilak Raj ,  Radhakrishna Arakali Srinivasarao ,  Jan-Pleun Lens ,  Subrahmanya Bhat K. ,  Umesh Hasyagar ,  Subash Scindia

IPC分类号： C08G64/00

CPC分类号： C08G63/64 ,  C08G59/26 ,  C08G63/6856 ,  C08G64/12

摘要： A polymer comprising structural units derived from a polycyclic dihydroxy compound of Formula (I) wherein R1, R2 and R3 are independently at each occurrence selected from the group consisting of a cyano functionality, a halogen, an aliphatic functionality having 1 to 10 carbons, a cycloaliphatic functionality having 3 to 10 carbons, and an aromatic functionality having 6 to 10 carbons; wherein each occurrence of “n”, “m”, and “p” independently has a value of 0, 1, 2, 3, or 4; and wherein the polymer is substantially linear.

摘要翻译： 包含衍生自式（I）的多环二羟基化合物（其中R 1，R 2和R 3）的结构单元的聚合物各自独立地 选自氰基官能团，卤素，具有1至10个碳的脂族官能团，具有3至10个碳的脂环族官能团和具有6至10个碳的芳族官能团; 其中每次出现的“n”，“m”和“p”独立地具有0,1,2,3或4的值; 并且其中所述聚合物基本上是线性的。