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    CATALYTIC PYROLYSIS OF SOLID BIOMASS AND RELATED BIOFUELS, AROMATIC, AND OLEFIN COMPOUNDS
    1.
    发明申请
    CATALYTIC PYROLYSIS OF SOLID BIOMASS AND RELATED BIOFUELS, AROMATIC, AND OLEFIN COMPOUNDS 有权
    固体生物质和相关生物燃料，芳香和烯烃化合物的催化热解

    公开(公告)号：US20090227823A1

    公开(公告)日：2009-09-10

    申请号：US12397303

    申请日：2009-03-03

    申请人： George W. Huber ,  Yu-Ting Cheng ,  Torren Carlson ,  Tushar Vispute ,  Jungho Jae ,  Geoff Tompsett

    发明人： George W. Huber ,  Yu-Ting Cheng ,  Torren Carlson ,  Tushar Vispute ,  Jungho Jae ,  Geoff Tompsett

    IPC分类号： C07C1/00

    CPC分类号： C10G1/002 ,  C10G1/08 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10G2300/305 ,  C10G2400/02 ,  C10G2400/20 ,  C10G2400/30 ,  Y02P30/42

    摘要： This invention relates to compositions and methods for fluid hydrocarbon product, and more specifically, to compositions and methods for fluid hydrocarbon product via catalytic pyrolysis. Some embodiments relate to methods for the production of specific aromatic products (e.g., benzene, toluene, naphthalene, xylene, etc.) via catalytic pyrolysis. Some such methods may involve the use of a composition comprising a mixture of a solid hydrocarbonaceous material and a heterogeneous pyrolytic catalyst component. In some embodiments, the mixture may be pyrolyzed at high temperatures (e.g., between 500° C. and 1000° C.). The pyrolysis may be conducted for an amount of time at least partially sufficient for production of discrete, identifiable biofuel compounds. Some embodiments involve heating the mixture of catalyst and hydrocarbonaceous material at high rates (e.g., from about 50° C. per second to about 1000° C. per second). The methods described herein may also involve the use of specialized catalysts. For example, in some cases, zeolite catalysts may be used; optionally, the catalysts used herein may have high silica to alumina molar ratios. In some instances, the composition fed to the pyrolysis reactor may have a relatively high catalyst to hydrocarbonaceous material mass ratio (e.g., from about 5:1 to about 20:1).

    摘要翻译： 本发明涉及流体烃产物的组合物和方法，更具体地说，涉及通过催化裂解的流化烃产物的组合物和方法。 一些实施方案涉及通过催化热解生产特定芳族产物（例如苯，甲苯，萘，二甲苯等）的方法。 一些这样的方法可以涉及使用包含固体烃类材料和非均相热解催化剂组分的混合物的组合物。 在一些实施方案中，混合物可在高温（例如500℃至1000℃）之间热解。 热解可以进行至少部分足以产生离散的，可识别的生物燃料化合物的时间量。 一些实施方案涉及以高速率（例如，每秒约50℃至约1000℃/秒）加热催化剂和含烃材料的混合物。 本文所述的方法还可以涉及使用专门的催化剂。 例如，在某些情况下，可以使用沸石催化剂; 任选地，本文使用的催化剂可具有高二氧化硅与氧化铝的摩尔比。 在一些情况下，进料到热解反应器的组合物可具有相对较高的催化剂与烃质量比（例如约5:1至约20:1）。

    Catalytic pyrolysis of solid biomass and related biofuels, aromatic, and olefin compounds
    4.
    发明授权
    Catalytic pyrolysis of solid biomass and related biofuels, aromatic, and olefin compounds 有权
    固体生物质和相关生物燃料，芳烃和烯烃化合物的催化裂解

    公开(公告)号：US08277643B2

    公开(公告)日：2012-10-02

    申请号：US12397303

    申请日：2009-03-03

    申请人： George W. Huber ,  Yu-Ting Cheng ,  Torren Carlson ,  Tushar Vispute ,  Jungho Jae ,  Geoff Tompsett

    发明人： George W. Huber ,  Yu-Ting Cheng ,  Torren Carlson ,  Tushar Vispute ,  Jungho Jae ,  Geoff Tompsett

    IPC分类号： C07C1/00

    CPC分类号： C10G1/002 ,  C10G1/08 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10G2300/305 ,  C10G2400/02 ,  C10G2400/20 ,  C10G2400/30 ,  Y02P30/42

    摘要： This invention relates to compositions and methods for fluid hydrocarbon product, and more specifically, to compositions and methods for fluid hydrocarbon product via catalytic pyrolysis. Some embodiments relate to methods for the production of specific aromatic products (e.g., benzene, toluene, naphthalene, xylene, etc.) via catalytic pyrolysis. Some such methods may involve the use of a composition comprising a mixture of a solid hydrocarbonaceous material and a heterogeneous pyrolytic catalyst component. In some embodiments, the mixture may be pyrolyzed at high temperatures (e.g., between 500° C. and 1000° C.). The pyrolysis may be conducted for an amount of time at least partially sufficient for production of discrete, identifiable biofuel compounds. Some embodiments involve heating the mixture of catalyst and hydrocarbonaceous material at high rates (e.g., from about 50° C. per second to about 1000° C. per second). The methods described herein may also involve the use of specialized catalysts. For example, in some cases, zeolite catalysts may be used; optionally, the catalysts used herein may have high silica to alumina molar ratios. In some instances, the composition fed to the pyrolysis reactor may have a relatively high catalyst to hydrocarbonaceous material mass ratio (e.g., from about 5:1 to about 20:1).

    摘要翻译： 本发明涉及流体烃产物的组合物和方法，更具体地说，涉及通过催化裂解的流化烃产物的组合物和方法。 一些实施方案涉及通过催化热解生产特定芳族产物（例如苯，甲苯，萘，二甲苯等）的方法。 一些这样的方法可以涉及使用包含固体烃类材料和非均相热解催化剂组分的混合物的组合物。 在一些实施方案中，混合物可在高温（例如500℃至1000℃）之间热解。 热解可以进行至少部分足以产生离散的，可识别的生物燃料化合物的时间量。 一些实施方案涉及以高速率（例如，每秒约50℃至约1000℃/秒）加热催化剂和含烃材料的混合物。 本文所述的方法还可以涉及使用专门的催化剂。 例如，在某些情况下，可以使用沸石催化剂; 任选地，本文使用的催化剂可具有高二氧化硅与氧化铝的摩尔比。 在一些情况下，进料到热解反应器的组合物可具有相对较高的催化剂与烃质量比（例如约5:1至约20:1）。