公开(公告)号：US20240024849A1

公开(公告)日：2024-01-25

申请号：US18376245

申请日：2023-10-03

Applicant: Georgia Tech Research Corporation

Inventor： Ratayakorn Khunsupat ,  Christopher W. Jones ,  Sumit Bali

IPC: B01J20/26 ,  B01D53/62 ,  B01D53/02 ,  B01J20/28 ,  B01J20/10 ,  B01J20/08 ,  B01J20/32

CPC classification number: B01J20/262 ,  B01D53/62 ,  B01D53/02 ,  B01J20/28083 ,  B01J20/103 ,  B01J20/08 ,  B01J20/3204 ,  B01J20/3272 ,  B01J20/3282 ,  B01J20/28042 ,  B01D2258/0283 ,  B01D2253/25 ,  B01D2257/504 ,  B01D2253/202 ,  Y02A50/20 ,  Y02C20/40

Abstract: Supported amine polymer adsorbents based on polymers containing only or primarily primary amines sites are to be used as regenerable adsorbents for CO2 capture from ultra-dilute gas streams, such as ambient air, or from mixtures of gases containing preferably at least I 0% oxygen. and can also be useful for use at the moderate gas pressures found in typical post-combustion capture processes, such as flue gas from large point sources such as coal-fired power plants. Preferred supported solid amine adsorbents of this invention are based on poly(allylamine) (“PAA”) and poly(vinyl amine) (“PVAm”), both of which are linear polymers, and their derivatives, containing substantially all primary amine groups, supported on substrates. Preferred such substrates include silica mesocellular foam (MCF) and mesoporous-.gamma.-alumina, as well on mesoporous-.gamma.-alumina coated throughout the pores of MCF, most preferably of monolithic structure. Preferred derivatives include the guanidinylated and cross-linked poly(allylamine) materials.

公开(公告)号：US11059024B2

公开(公告)日：2021-07-13

申请号：US14063850

申请日：2013-10-25

Applicant: Georgia Tech Research Corporation

Inventor： Ratayakorn Khunsupat ,  Christopher W. Jones ,  Sumit Bali

IPC: B01J20/26 ,  B01J20/28 ,  B01J20/32 ,  B01J20/08 ,  B01J20/10 ,  B01D53/02 ,  B01D53/62

Abstract: Supported amine polymer adsorbents based on polymers containing only or primarily primary amines sites are to be used as regenerable adsorbents for CO2 capture from ultra-dilute gas streams, such as ambient air, or from mixtures of gases containing preferably at least 10% oxygen. and can also be useful for use at the moderate gas pressures found in typical post-combustion capture processes, such as flue gas from large point sources such as coal-fired power plants. Preferred supported solid amine adsorbents of this invention are based on poly(allylamine) (“PAA”) and poly(vinyl amine) (“PVAm”), both of which are linear polymers, and their derivatives, containing substantially all primary amine groups, supported on substrates. Preferred such substrates include silica mesocellular foam (MCF) and mesoporous-γ-alumina, as well on mesoporous-γ-alumina coated throughout the pores of MCF, most preferably of monolithic structure. Preferred derivatives include the guanidinylated and cross-linked poly(allylamine) materials.

公开(公告)号：US11850570B2

公开(公告)日：2023-12-26

申请号：US17373759

申请日：2021-07-12

Applicant: Georgia Tech Research Corporation

Inventor： Ratayakorn Khunsupat ,  Christopher W. Jones ,  Sumit Bali

IPC: B01J20/26 ,  B01J20/08 ,  B01J20/10 ,  B01J20/28 ,  B01J20/32 ,  B01D53/62 ,  B01D53/02

CPC classification number: B01J20/262 ,  B01D53/02 ,  B01D53/62 ,  B01J20/08 ,  B01J20/103 ,  B01J20/28042 ,  B01J20/28083 ,  B01J20/3204 ,  B01J20/3272 ,  B01J20/3282 ,  B01D2253/202 ,  B01D2253/25 ,  B01D2257/504 ,  B01D2258/0283 ,  Y02A50/20 ,  Y02C20/40

Abstract: Supported amine polymer adsorbents based on polymers containing only or primarily primary amines sites are to be used as regenerable adsorbents for CO.sub.2 capture from ultra-dilute gas streams, such as ambient air, or from mixtures of gases containing preferably at least 10% oxygen. and can also be useful for use at the moderate gas pressures found in typical post-combustion capture processes, such as flue gas from large point sources such as coal-fired power plants. Preferred supported solid amine adsorbents of this invention are based on poly(allylamine) (“PAA”) and poly(vinyl amine) (“PVAm”), both of which are linear polymers, and their derivatives, containing substantially all primary amine groups, supported on substrates. Preferred such substrates include silica mesocellular foam (MCF) and mesoporous-.gamma.-alumina, as well on mesoporous-.gamma.-alumina coated throughout the pores of MCF, most preferably of monolithic structure. Preferred derivatives include the guanidinylated and cross-linked poly(allylamine) materials.

公开(公告)号：US20140241966A1

公开(公告)日：2014-08-28

申请号：US14063850

申请日：2013-10-25

Applicant: Georgia Tech Research Corporation

Inventor： Ratayakorn Khunsupat ,  Christopher W. Jones ,  Sumit Bali

IPC: B01J20/26 ,  B01D53/62

CPC classification number: B01J20/262 ,  B01D53/02 ,  B01D53/62 ,  B01D2253/202 ,  B01D2253/25 ,  B01D2257/504 ,  B01D2258/0283 ,  B01J20/08 ,  B01J20/103 ,  B01J20/28042 ,  B01J20/28083 ,  B01J20/3204 ,  B01J20/3272 ,  B01J20/3282 ,  Y02A50/2342 ,  Y02C10/04 ,  Y02C10/08

Abstract: Supported amine polymer adsorbents based on polymers containing only or primarily primary amines sites are to be used as regenerable adsorbents for CO2 capture from ultra-dilute gas streams, such as ambient air, or from mixtures of gases containing preferably at least 10% oxygen. and can also be useful for use at the moderate gas pressures found in typical post-combustion capture processes, such as flue gas from large point sources such as coal-fired power plants. Preferred supported solid amine adsorbents of this invention are based on poly(allylamine) (“PAA”) and poly(vinyl amine) (“PVAm”), both of which are linear polymers, and their derivatives, containing substantially all primary amine groups, supported on substrates. Preferred such substrates include silica mesocellular foam (MCF) and mesoporous-γ-alumina, as well on mesoporous-γ-alumina coated throughout the pores of MCF, most preferably of monolithic structure. Preferred derivatives include the guanidinylated and cross-linked poly(allylamine) materials.

Abstract translation: 用于仅含有或主要为伯胺位点的聚合物的负载的胺聚合物吸附剂将用作可从超稀释气流（例如环境空气）或从优选至少10％氧气的气体混合物中捕获CO 2的可再生吸附剂。 并且也可用于在典型的燃烧后捕获过程中发现的中等气体压力下使用，例如来自诸如燃煤发电厂等大型点的烟道气。 本发明优选的负载型固体胺吸附剂基于聚（烯丙胺）（“PAA”）和聚（乙烯基胺）（“PVAm”），它们都是直链聚合物，它们的衍生物含有基本上所有的伯胺基团， 支撑在基板上。 优选的这种底物包括二氧化硅中孔泡沫（MCF）和中孔γ-氧化铝，以及涂覆在MCF的整个孔中的中孔γ-氧化铝，最优选为整体结构。 优选的衍生物包括胍基化和交联的聚（烯丙胺）材料。