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    Method For Producing Bridged Manganese Complexes Of Triazacyclononane
    2.
    发明申请
    Method For Producing Bridged Manganese Complexes Of Triazacyclononane 有权
    生产三氮杂环壬烷锰配合物的方法

    公开(公告)号：US20120202990A1

    公开(公告)日：2012-08-09

    申请号：US13394968

    申请日：2010-09-10

    申请人： Gerd Reinhardt ,  Michael Best ,  Christian Sidot

    发明人： Gerd Reinhardt ,  Michael Best ,  Christian Sidot

    IPC分类号： C07F13/00

    CPC分类号： C07F13/005 ,  B01J31/182 ,  B01J31/2208 ,  B01J2531/0216

    摘要： The invention relates to a method for producing manganese complex compounds of the general formula (1), wherein M, X, L, z, Y and q are defined as in claim 1. The method is characterized by the following steps: a) reacting one or more bivalent metal salts with the ligand L in water as the solvent to form a coordination compound from the one or more bivalent metal salt and the ligand L, the one or more bivalent metal salts being selected from bivalent manganese salts and iron salts and at least one bivalent metal salt being a bivalent manganese salt, b) oxidizing the coordination compound of step a) with an oxidant while at the same time maintaining a pH of 11 to 14, to transform the metal M from the bivalent to the trivalent and/or tetravalent form, c) reducing the pH of the reaction mixture to a pH of 4 to 9 and removing any metal oxides or metal hydroxides of the metal M formed and d) adding, at a pH of 4 to 9, a salt of the formula MezYq, wherein Me represents an alkali metal ion, ammonium ion or an alkanol ammonium ion, and Y, z and q are defined as in formula (1).

    摘要翻译： 本发明涉及一种制备通式（1）的锰络合物的方法，其中M，X，L，Z，Y和q如权利要求1中所定义。该方法的特征在于以下步骤：a） 一种或多种二价金属盐与水中的配体L作为溶剂，以从一种或多种二价金属盐和配体L形成配位化合物，一种或多种二价金属盐选自二价锰盐和铁盐，以及 至少一种二价金属盐是二价锰盐，b）用氧化剂氧化步骤a）的配位化合物，同时保持pH为11至14，以将金属M从二价转化成三价和 /或四价形式，c）将反应混合物的pH降低至4至9的pH，并除去形成的金属M的任何金属氧化物或金属氢氧化物，以及d）在pH4至9的条件下，加入 式MezYq，其中Me表示碱金属离子，a 铵离子或烷醇铵离子，Y，Z和q如式（1）所定义。

    Bleach catalyst compounds, method for the production thereof and use thereof
    3.
    发明授权
    Bleach catalyst compounds, method for the production thereof and use thereof 有权
    漂白催化剂化合物，其制备方法和用途

    公开(公告)号：US08889611B2

    公开(公告)日：2014-11-18

    申请号：US13513729

    申请日：2010-11-30

    申请人： Gerd Reinhardt ,  Michael Best

    发明人： Gerd Reinhardt ,  Michael Best

    IPC分类号： C11D7/26 ,  C11D7/32 ,  C11D7/54 ,  C07F13/00 ,  C11D17/06 ,  C11D17/00 ,  C11D3/16 ,  C11D3/39 ,  D21C9/10 ,  D21C9/16

    CPC分类号： C07F13/005 ,  C11D3/168 ,  C11D3/3932 ,  C11D17/0052 ,  C11D17/06 ,  C11D17/065 ,  D21C9/10 ,  D21C9/163

    摘要： The invention relates to compounds in solid form, containing a) one or more manganese complex compounds of the general formula (1), where M is independently selected from manganese in the III or IV oxidation state, X is independently a co-ordinating or bridging species selected from H2O, O22−, O2−, O2−, OH−, HO2−, SH−, S2−, SO, Cl−, N3−, SCN−, N3−, RCOO−, NH2− and NR3, where R is a radical selected from H, alkyl and aryl, L are independently organic ligands, each of which contains at least two nitrogen atoms co-ordinated on manganese, z is an integer from −4 to +4, Y is a monovalent or multivalent counter-ion selected from chloride, sulphate, hydrogen sulphate, nitrate and acetate, which leads to charge neutrality of the complex, and q is an integer from 1 to 4, and b) one or more salts of the general formula R′—C6H4—SO3Me, where R′ is CH3 or C2H5 and denotes Me, Na, K, Ca or Mg, characterized in that the molar ratio of the manganese complex compound of the general formula (1) to salt of the general formula R′—C6H4—SO3Me is 1:0.5 to 1:5. The invention also describes a method for producing the compounds and to the use thereof as oxidation catalysts or bleach catalysts, in particular in detergents or cleaning agents.

    摘要翻译： 本发明涉及固体形式的化合物，其包含a）一种或多种通式（1）的锰络合物，其中M独立地选自III或IV氧化态的锰，X独立地为配位或桥接 选自H2O，O22-，O​​2-，O2-，OH-，HO2-，SH-，S2-，SO，Cl-，N3-，SCN-，N3-，RCOO-，NH2-和NR3的物质，其中R 是选自H，烷基和芳基的基团，L独立为有机配体，每个含有至少两个在锰上配位的氮原子，z为-4至+4的整数，Y为单价或多价计数器 其选自氯化物，硫酸盐，硫酸氢盐，硝酸盐和乙酸盐，这导致络合物的电荷中性，q是1至4的整数，b）一种或多种通式R'-C6H4- SO 3 Me，其中R'是CH 3或C 2 H 5，并且表示Me，Na，K，Ca或Mg，其特征在于锰络合物 通式（1）表示的化合物与通式R'-C6H4-SO3Me的盐为1:0.5至1:5。 本发明还描述了一种制备化合物的方法及其用作氧化催化剂或漂白催化剂的用途，特别是在洗涤剂或清洁剂中。

    Bleach Catalyst Compounds, Method For The Production Thereof And Use Thereof
    4.
    发明申请
    Bleach Catalyst Compounds, Method For The Production Thereof And Use Thereof 有权
    漂白催化剂化合物，其生产方法和用途

    公开(公告)号：US20120302490A1

    公开(公告)日：2012-11-29

    申请号：US13513729

    申请日：2010-11-30

    申请人： Gerd Reinhardt ,  Michael Best

    发明人： Gerd Reinhardt ,  Michael Best

    IPC分类号： B01J31/22 ,  C11D3/30

    CPC分类号： C07F13/005 ,  C11D3/168 ,  C11D3/3932 ,  C11D17/0052 ,  C11D17/06 ,  C11D17/065 ,  D21C9/10 ,  D21C9/163

    摘要： The invention relates to compounds in solid form, containing a) one or more manganese complex compounds of the general formula (I), where M is independently selected from manganese in the III or IV oxidation state, X is independently a co-ordinating or bridging species selected from H2O, O22−, O2−, O2−, OH−, HO2−, SH−, S2−, SO, Cl−, N3−, SCN−, N3−, RCOO−, NH2− and NR3, where R is a radical selected from H, alkyl and aryl, L are independently organic ligands, each of which contains at least two nitrogen atoms co-ordinated on manganese, z is an integer from −4 to +4, Y is a monovalent or multivalent counter-ion selected from chloride, sulphate, hydrogen sulphate, nitrate and acetate, which leads to charge neutrality of the complex, and q is an integer from 1 to 4, and b) one or more salts of the general formula R′—C6H4—SO3Me, where R′ is CH3 or C2H5 and denotes Me, Na, K, Ca or Mg, characterised in that the molar ratio of the manganese complex compound of the general formula (1) to salt of the general formula R′—C6H4—SO3Me is 1:0.5 to 1:5. The invention also describes a method for producing the compounds and to the use thereof as oxidation catalysts or bleach catalysts, in particular in detergents or cleaning agents.

    摘要翻译： 本发明涉及固体形式的化合物，其包含a）一种或多种通式（I）的锰络合物，其中M独立地选自III或IV氧化态的锰，X独立地为配位或桥接 选自H2O，O22-，O​​2-，O2-，OH-，HO2-，SH-，S2-，SO，Cl-，N3-，SCN-，N3-，RCOO-，NH2-和NR3的物质，其中R 是选自H，烷基和芳基的基团，L独立为有机配体，每个含有至少两个在锰上配位的氮原子，z为-4至+4的整数，Y为单价或多价计数器 其选自氯化物，硫酸盐，硫酸氢盐，硝酸盐和乙酸盐，其导致络合物的电荷中性，q是1至4的整数，b）一种或多种通式R'-C6H4- SO 3 Me，其中R'是CH 3或C 2 H 5，并且表示Me，Na，K，Ca或Mg，其特征在于锰络合物 通式（1）表示的化合物与通式R'-C6H4-SO3Me的盐为1:0.5至1:5。 本发明还描述了一种制备化合物的方法及其用作氧化催化剂或漂白催化剂的用途，特别是在洗涤剂或清洁剂中。

    Method for producing bridged manganese complexes of triazacyclononane
    5.
    发明授权
    Method for producing bridged manganese complexes of triazacyclononane 有权
    三氮杂环壬烷桥联锰配合物的制备方法

    公开(公告)号：US09012630B2

    公开(公告)日：2015-04-21

    申请号：US13394968

    申请日：2010-09-10

    申请人： Gerd Reinhardt ,  Michael Best ,  Christian Sidot

    发明人： Gerd Reinhardt ,  Michael Best ,  Christian Sidot

    IPC分类号： C07F13/00 ,  B01J31/18 ,  B01J31/22

    CPC分类号： C07F13/005 ,  B01J31/182 ,  B01J31/2208 ,  B01J2531/0216

    摘要： The invention relates to a method for producing manganese complex compounds of the general formula (1), wherein M, X, L, z, Y and q are defined as in claim 1. The method is characterized by the following steps: a) reacting one or more bivalent metal salts with the ligand L in water as the solvent to form a coordination compound from the one or more bivalent metal salt and the ligand L, the one or more bivalent metal salts being selected from bivalent manganese salts and iron salts and at least one bivalent metal salt being a bivalent manganese salt, b) oxidizing the coordination compound of step a) with an oxidant while at the same time maintaining a pH of 11 to 14, to transform the metal M from the bivalent to the trivalent and/or tetravalent form, c) reducing the pH of the reaction mixture to a pH of 4 to 9 and removing any metal oxides or metal hydroxides of the metal M formed and d) adding, at a pH of 4 to 9, a salt of the formula MezYq, wherein Me represents an alkali metal ion, ammonium ion or an alkanol ammonium ion, and Y, z and q are defined as in formula (1).

    摘要翻译： 本发明涉及一种制备通式（1）的锰络合物的方法，其中M，X，L，Z，Y和q如权利要求1中所定义。该方法的特征在于以下步骤：a） 一种或多种二价金属盐与水中的配体L作为溶剂，以从一种或多种二价金属盐和配体L形成配位化合物，一种或多种二价金属盐选自二价锰盐和铁盐，以及 至少一种二价金属盐是二价锰盐，b）用氧化剂氧化步骤a）的配位化合物，同时保持pH为11至14，以将金属M从二价转化成三价和 /或四价形式，c）将反应混合物的pH降低至4至9的pH，并除去形成的金属M的任何金属氧化物或金属氢氧化物，以及d）在pH4至9的条件下，加入 式MezYq，其中Me表示碱金属离子，a 铵离子或烷醇铵离子，Y，Z和q如式（1）所定义。

    Process For Producing 3,7-Diaza-Bicyclo[3.3.1]Nonane-Metal Complexes
    6.
    发明申请
    Process For Producing 3,7-Diaza-Bicyclo[3.3.1]Nonane-Metal Complexes 审中-公开
    制备3,7-二氮杂双环[3.3.1]壬烷 - 金属络合物的方法

    公开(公告)号：US20130072685A1

    公开(公告)日：2013-03-21

    申请号：US13575747

    申请日：2011-01-28

    申请人： Gerd Reinhardt ,  Miriam Ladwig ,  Michael Best ,  Thorsten Schneider ,  Ernst Spicker

    发明人： Gerd Reinhardt ,  Miriam Ladwig ,  Michael Best ,  Thorsten Schneider ,  Ernst Spicker

    IPC分类号： C07F15/02 ,  C07F13/00

    CPC分类号： C07F15/025 ,  C07D471/08 ,  C07F13/005

    摘要： The invention describes a process for producing metal complexes of the general formula (2): [MaLxXn]Ym (2), where M is a metal from the group comprising Mn(II), Mn(III), Mn(IV), Fe(II), Fe(III) or Fe(IV), X is a coordinated compound selected from mono- bi- or tri-charged anions or neutral molecules which are able to coordinate with a metal mono- bi- or tri-dentate, Y represents a non-coordinated counter-ion which ensures charge equalization of the complex, L represents a ligand of the general formula (1) or the protonized or de-protonized form thereof, and a, x, n, m, R, R1, R2, R3 and z have the meaning specified in claim 1. Said process is characterized in that the reaction of a ligand of the formula (1) with an iron or manganese salt in a heterogeneous reaction is carried out in water, where the reaction is carried out in a temperature range of 35 to 50° C. and the pH value of the reaction mixture is from 1 to 3 after the addition of the iron or manganese salt.

    摘要翻译： 本发明描述了一种制备通式（2）金属络合物的方法：[MaLxXn] Ym（2），其中M是包含Mn（II），Mn（III），Mn（IV），Fe （II），Fe（III）或Fe（IV），X是选自单 - 或三 - 电荷的阴离子或中性分子的配位化合物，其能够与金属单 - 或三 - Y表示非配位的抗衡离子，其确保络合物的电荷均衡，L表示通式（1）的配体或其质子化或去质子化形式，以及a，x，n，m，R，R 1 R 2，R 3和Z具有权利要求1中所述的含义。所述方法的特征在于式（1）的配体与非均相反应中的铁或锰盐的反应在水中进行，其中反应 在35〜50℃的温度范围内进行，加入铁盐或锰盐后，反应混合物的pH值为1〜3。

    Method For Producing Acyloxy Benzoic Acids
    9.
    发明申请
    Method For Producing Acyloxy Benzoic Acids 有权
    生产甲氧基苯甲酸的方法

    公开(公告)号：US20130217911A1

    公开(公告)日：2013-08-22

    申请号：US13816686

    申请日：2011-08-06

    申请人： Melanie Sajitz ,  Gerd Reinhardt ,  Isabel Scheffer ,  Werner Janitschek ,  Ina Herrgen

    发明人： Melanie Sajitz ,  Gerd Reinhardt ,  Isabel Scheffer ,  Werner Janitschek ,  Ina Herrgen

    IPC分类号： C07C67/14

    CPC分类号： C07C67/14 ,  C07C69/017 ,  C07C69/24 ,  C07C69/78

    摘要： The invention relates to a method for producing acyloxy benzoic acids of the formula (I), in which R1 is a linear or branched saturated alkyl group with 6 to 30 carbon atoms, a linear or branched mono- or polyunsaturated alkenyl group with 6 to 30 carbon atoms, or an aryl group with 6 to 30 carbon atoms. The acyloxy benzoic acids of the formula (I) are produced from para-hydroxy benzoic acid and a corresponding carboxylic acid halide in the presence of an alkali hydroxide.

    摘要翻译： 本发明涉及一种制备式（I）的酰氧基苯甲酸的方法，其中R 1为具有6至30个碳原子的直链或支链饱和烷基，具有6至30个直链或支链单或多不饱和链烯基 碳原子或具有6至30个碳原子的芳基。 式（I）的酰氧基苯甲酸由对羟基苯甲酸和相应的羧酸卤化物在碱金属氢氧化物存在下制备。

    Bleach Granules Comprising An Active Coating
    10.
    发明申请
    Bleach Granules Comprising An Active Coating 有权
    含有活性涂料的漂白剂

    公开(公告)号：US20120058927A1

    公开(公告)日：2012-03-08

    申请号：US13263028

    申请日：2010-04-01

    申请人： Georg Borchers ,  Gerd Reinhardt ,  Andreas Schottstedt

    发明人： Georg Borchers ,  Gerd Reinhardt ,  Andreas Schottstedt

    IPC分类号： C11D3/60 ,  C11D17/00

    CPC分类号： C11D3/3932 ,  C11D3/3935 ,  C11D17/0039 ,  C11D17/06

    摘要： The invention relates to co-granules containing a granule core and a sheath or coating layer surrounding the granule core. Said co-granules are characterised in that the granule core contains a) at least one bleach activator, a2) between 0 and 20 wt. % of the total quantity of at least one bleach catalyst contained in the co-granule, and c) at least one binding agent, and the sheath or coating layer contains d) between 80 and 100 wt. % of the total quantity of the at least one bleach catalyst contained in the co-granule, and e) at least one coating agent. The co-granules are advantageously suitable for producing cleaning products and detergents and especially products for washing crockery in a machine.

    摘要翻译： 本发明涉及包含颗粒核心和围绕颗粒核心的鞘或包衣层的共颗粒剂。 所述共颗粒的特征在于颗粒核含有a）至少一种漂白活化剂，a2）0-20wt。 包含在共颗粒中的至少一种漂白催化剂总量的百分比，和c）至少一种粘合剂，并且所述护套或涂层含有d）80-100重量份。 包含在共颗粒中的至少一种漂白催化剂的总量的％，以及e）至少一种涂布剂。 共混颗粒有利地适用于生产清洁产品和洗涤剂，特别是用于在机器中洗涤陶器的产品。