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公开(公告)号：US4602033A
公开(公告)日：1986-07-22
申请号：US688492
申请日：1985-01-03
IPC分类号： A01N47/22 , C07D307/86 , A01N43/16 , A01N43/12 , C07D307/79
CPC分类号： A01N47/22 , C07D307/86
摘要： Aryl N-oxalyl-N-methyl-carbamates of the general formula ##STR1## in which X represents an alkoxy, alkenoxy, alkinoxy, aryloxy, alkylthio, alkenylthio, alkinylthio or arylthio radical, each of which may be optionally substituted or represents a radical of the general formula --N R.sup.3 R.sup.4, wherein R.sup.3 and R.sup.4 are identical or different and represent a hydrogen atom or an alkyl, alkenyl, alkinyl, cycloalkyl, cycloalkenyl or aryl radical, each of which may be optionally substituted, or the radicals R.sup.3 and R.sup.4, together with the N atom to which they are bonded, form an optionally substituted heterocyclic ring, andR.sup.1 represents an aryl radical which is optionally substituted,are novel and find use as pesticides, especially for combating insects, acarids and nematodes.
摘要翻译： 其中X表示烷氧基，链烯氧基，烷氧基，芳氧基，烷硫基，烯硫基，炔基硫基或芳硫基，其各自可以任选被取代，或者 表示通式-NR 3 R 4的基团，其中R 3和R 4相同或不同，表示氢原子或烷基，烯基，炔基，环烷基，环烯基或芳基，其各自可以被任意取代，或者基团 R3和R4与它们所键合的N原子一起形成任选取代的杂环，R 1代表任选取代的芳基，是新颖的，可用作杀虫剂，尤其用于防治昆虫，螨虫和线虫。
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2.发明授权
公开(公告)号：US4507292A
公开(公告)日：1985-03-26
申请号：US461368
申请日：1983-01-27
IPC分类号： A01N47/22 , C07D307/86 , A01N43/84 , C07D295/14
CPC分类号： A01N47/22 , C07D307/86
摘要： Aryl N-oxalyl-N-methyl-carbamates of the general formula ##STR1## in which X represents an alkoxy, alkenoxy, alkinoxy, aryloxy, alkylthio, alkenylthio, alkinylthio or arylthio radical, each of which may be optionally substituted, or represents a radical of the general formula --N R.sup.3 R.sup.4, wherein R.sup.3 and R.sup.4 are identical or different and represent a hydrogen atom or an alkyl, alkenyl, alkinyl, cycloalkyl, cycloalkenyl or aryl radical, each of which may be optionally substituted,or the radicals R.sup.3 and R.sup.4, together with the N atom to which they are bonded, form an optionally substituted heterocyclic ring, andR.sup.1 represents an aryl radical which is optionally substituted,are novel and find use as pesticides, especially for combating insects, acarids and nematodes.
摘要翻译： 其中X表示烷氧基，链烯氧基，烷氧基，芳氧基，烷硫基，烯硫基，炔基硫基或芳硫基，其中每一个可以被任选地取代，通式为（I）的N-乙酰基-N-草酰基-N-甲基 - 或表示通式-NR 3 R 4的基团，其中R 3和R 4相同或不同，表示氢原子或烷基，烯基，炔基，环烷基，环烯基或芳基，其各自可以被任选取代，或者 基团R 3和R 4与它们所键合的N原子一起形成任选取代的杂环，并且R 1表示任选取代的芳基，是新颖的，可用作农药，特别是用于防治昆虫，螨虫和线虫 。
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公开(公告)号：US4357329A
公开(公告)日：1982-11-02
申请号：US276406
申请日：1981-06-22
CPC分类号： A01N57/18 , C07F9/4065 , C07F9/65181
摘要： N-Phosphonylcarbonyl-N-methylcarbamic acid esters of the formula ##STR1## in which R.sup.1 and R.sup.2 can be identical or different and each represents alkyl, alkenyl or alkynyl, it being possible for any of these radicals to be substituted by halogen, andR.sup.3 represents alkyl, phenyl, naphthyl, benzodioxolanyl, dihydrobenzofuranyl or indanyl, it being possible for any of these radicals to carry one or more substituents selected from alkyl, alkenyl, alkynyl, alkoxy, alkenoxy, alkynoxy, alkylthio, alkenylthio, alkynylthio, dialkylamino, halogenoalkyl, halogen, nitro, cyano, cycloalkyl, formamidino, dioxanyl and dioxolanyl, orR.sup.3 represents a radical of the formula ##STR2## in which R.sup.4 and R.sup.5 can be identical or different and each represents alkyl, alkoxy, alkylthio, alkylthioalkyk, cyano, alkoxycarbonyl, dialkylcarbamoyl, dialkoxyphosphoryl or triazolyl, orR.sup.4 and R.sup.5, together with the C atom to which they are bonded, form a dithiolane, dithiane, oxythiolane or oxathiane ring which is optionally substituted by methyl or phenyl,which are pesticidally active.
摘要翻译： 其中R 1和R 2可以相同或不同并且各自代表烷基，烯基或炔基，这些基团中的任何一个可以被卤素取代的N-膦酰基羰基-N-甲基氨基甲酸酯， 代表烷基，苯基，萘基，苯并二恶烷基，二氢苯并呋喃基或茚满基，这些基团中的任何一个可以携带一个或多个选自烷基，烯基，炔基，烷氧基，链烯氧基，炔氧基，烷硫基，烯硫基，炔硫基，二烷基氨基，卤代烷基 ，卤素，硝基，氰基，环烷基，甲脒基，二烷基和二氧戊环基，或R 3表示下式的基团，其中R 4和R 5可以相同或不同，并且各自表示烷基，烷氧基，烷硫基，烷硫基烷基，氰基， ，二烷基氨基甲酰基，二烷氧基磷酰基或三唑基，或者R4和R5与它们所键合的C原子一起形成二硫杂环戊烷，二噻烷，氧硫杂环丁烷或氧硫杂环， 由甲基或苯基取代，它们具有杀虫活性。
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4.发明授权N-Methyl-N-(sulphonic acid amide-n'-sulphenyl)-carbamic acid esters 失效N-甲基-N-（磺酰胺 - 正 - 硫苯基） - 氨基甲酸酯
公开(公告)号：US4212887A
公开(公告)日：1980-07-15
申请号：US948190
申请日：1978-10-02
IPC分类号： A01N47/24 , A01P5/00 , A01P7/02 , A01P7/04 , C07C67/00 , C07C325/00 , C07C381/08 , C07D307/86 , C07D317/08 , C07D317/24 , C07D317/46 , C07D339/06 , A01N9/16 , A01N57/06 , C07C119/18 , C07F9/02
CPC分类号： C07D317/24 , A01N47/24 , C07D307/86 , C07D339/06
摘要： N-Methyl-N-(sulphonic acid amide-N'-sulphenyl)-carbamic acid esters of the formula ##STR1## in which R.sup.1 is dialkylamino with 1 to 4 carbon atoms in each alkyl radical, phenyl or phenyl carrying at least one halogen, alkyl with 1 to 4 carbon atoms, nitro or trihalogenomethyl substituent,R.sup.2 is alkyl with 2 to 8 carbon atoms, cycloalkyl, phenyl or cycloalkyl or phenyl carrying at least one halogen, alkyl with 1 to 4 carbon atoms, nitro or trifluoromethyl substituent, andR.sup.3 is phenyl, naphthyl, benzodioxolanyl, dihydrobenzofuranyl or indanyl; phenyl, naphthyl, benzodioxolanyl, dihydrobenzofuranyl or indanyl substituted at least once by trihalogenomethyl, halogen, nitro, cyano, cycloalkyl, formamidino, dioxanyl or dioxolanyl, or by alkyl, alkenyl, alkynyl, alkoxy, alkenoxy, alkynoxy, alkylmercapto, alkenylmercapto, alkynylmercapto or dialkylamino, each with up to 4 carbon atoms per aliphatic moiety, or an oxime radical of the formula ##STR2## R.sup.4 and R.sup.5 each independently is cyano or alkyl, alkoxy, alkylthio, alkoxycarbonyl, dialkylcarbamoyl or dialkoxyphosphoryl with up to 4 carbon atoms per alkyl moiety, orR.sup.4 and R.sup.5, conjointly with the adjacent carbon atom, form an optionally methyl- or phenyl-substituted dithiolane, dithiane, oxathiolane or oxathiane ring.
摘要翻译： 具有式（I）的N-甲基-N-（磺酰胺-N'-硫苯基） - 氨基甲酸酯，其中R 1是每个烷基中具有1至4个碳原子的二烷基氨基，苯基或苯基 至少一个卤素，具有1至4个碳原子的烷基，硝基或三卤代甲基取代基，R 2是具有2至8个碳原子的烷基，环烷基，苯基或环烷基或带有至少一个卤素的苯基，具有1至4个碳原子的烷基，硝基或 三氟甲基取代基，R 3为苯基，萘基，苯并二恶烷基，二氢苯并呋喃基或茚满基; 苯基，萘基，苯并二氧杂环戊烷基，二氢苯并呋喃基或茚满烷基，其被三卤代甲基，卤素，硝基，氰基，环烷基，甲酰氨基，二烷基或二氧戊环，或烷基，烯基，炔基，烷氧基，链烯氧基，炔氧基，烷基巯基，烯基巯基，炔基巯基或 每个脂族部分具有至多4个碳原子的二烷基氨基，或下式的肟基团R 4和R 5各自独立地为氰基或烷基，烷氧基，烷硫基，烷氧基羰基，二烷基氨基甲酰基或每烷基具有至多4个碳原子的二烷氧基磷酰基 部分，或R 4和R 5与相邻的碳原子一起形成任选的甲基 - 或苯基取代的二硫戊环，二噻烷，氧硫杂环戊烷或氧硫杂环。
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5.发明授权Certain 2,3-dihydrobenzofuranyl esters of certain N-sulfenylated carbamic acids 失效某些N-亚磺酰基化氨基甲酸的某些2,3-二氢苯并呋喃基酯
公开(公告)号：US3980673A
公开(公告)日：1976-09-14
申请号：US498675
申请日：1974-08-19
IPC分类号： A01N47/22 , A01N47/24 , A01P7/02 , A01P7/04 , C07C67/00 , C07C313/32 , C07C325/00 , C07D307/86
CPC分类号： C07D307/86 , A01N47/24
摘要： N-sulfenylated 2,3-dihydrobenzofuranyl-7-N-methylcarbamates of the formula ##EQU1## in which R.sup.1 is hydrogen or C.sub.1 -C.sub.6 alkyl,R.sup.2 is C.sub.1 -C.sub.6 alkyl, andR.sup.3 is phenyl; phenyl substituted by at least one of halogen, C.sub.1 -C.sub.6 alkyl and trihalogenomethyl; methoxycarbonyl; or the radical ##EQU2## wherein R.sup.4 is alkylamino, dialkylamino, phenyl, or phenyl substituted by at least one of halogen, C.sub.1 -C.sub.6 alkyl or trihalogenomethyl,Which possess insecticidal and acaricidal properties.
摘要翻译： 其中R 1是氢或C 1 -C 6烷基，R 2是C 1 -C 6烷基，和R 3是苯基的N-磺酰化2,3-二氢苯并呋喃基-7-N-甲基氨基甲酸酯，其中R 1是氢或C 1 -C 6烷基， ; 由至少一个卤素，C 1 -C 6烷基和三卤甲基取代的苯基; 甲氧基羰基 或其中R 4为烷基氨基，二烷基氨基，苯基或被至少一个卤素，C 1 -C 6烷基或三卤代甲基取代的苯基的基团-N-SO 2 -R 4 CH 3，其具有无定形杀虫剂和杀油性质。
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6.发明授权N-Methyl-N-(sulphonic acid amide-n'-sulphenyl)-carbamic acid esters 失效N-甲基-N-（磺酸酰胺-n {40-磺苯基） - 氨基甲酸酯
公开(公告)号：US4148910A
公开(公告)日：1979-04-10
申请号：US756049
申请日：1976-12-30
IPC分类号： A01N47/24 , A01P5/00 , A01P7/02 , A01P7/04 , C07C67/00 , C07C325/00 , C07C381/08 , C07D307/86 , C07D317/08 , C07D317/24 , C07D317/46 , C07D339/06
CPC分类号： C07D317/24 , A01N47/24 , C07D307/86 , C07D339/06
摘要： N-Methyl-N-(sulphonic acid amide-N'-sulphenyl)-carbamic acid esters of the formula ##STR1## in which R.sup.1 is dialkylamino with 1 to 4 carbon atoms in each alkyl radical, phenyl or phenyl carrying at least one halogen, alkyl with 1 to 4 carbon atoms, nitro or trihalogenomethyl substituent,R.sup.2 is alkyl with 2 to 8 carbon atoms, cycloalkyl, phenyl or cycloalkyl or phenyl carrying at least one halogen, alkyl with 1 to 4 carbon atoms, nitro or trifluoromethyl substituent, andR.sup.3 is phenyl, naphthyl, benzodioxolanyl, dihydrobenzofuranyl or indanyl; phenyl, naphthyl, benzodioxolanyl, dihydrobenzofuranyl or indanyl substituted at least once by trihalogenomethyl, halogen, nitro, cyano, cycloalkyl, formamidino, dioxanyl or dioxolanyl, or by alkyl, alkenyl, alkynyl, alkoxy, alkenoxy, alkynoxy, alkylmercapto, alkenylmercapto, alkynylmercapto or dialkylamino, each with up to 4 carbon atoms per aliphatic moiety, or an oxime radical of the formula ##STR2## R.sup.4 and R.sup.5 each independently is cyano or alkyl, alkoxy, alkylthio, alkoxycarbonyl, dialkylcarbamoyl or dialkoxyphosphoryl with up to 4 carbon atoms per alkyl moiety, orR.sup.4 and R.sup.5, conjointly with the adjacent carbon atom, form an optionally methyl- or phenyl-substituted dithiolane, dithiane, oxathiolane or oxathiane ring.
摘要翻译： 具有式（I）的N-甲基-N-（磺酰胺-N'-硫苯基） - 氨基甲酸酯，其中R 1是每个烷基中具有1至4个碳原子的二烷基氨基，苯基或苯基 至少一个卤素，具有1至4个碳原子的烷基，硝基或三卤代甲基取代基，R 2是具有2至8个碳原子的烷基，环烷基，苯基或环烷基或带有至少一个卤素的苯基，具有1至4个碳原子的烷基，硝基或 三氟甲基取代基，R 3为苯基，萘基，苯并二恶烷基，二氢苯并呋喃基或茚满基; 苯基，萘基，苯并二氧杂环戊烷基，二氢苯并呋喃基或茚满烷基，其被三卤代甲基，卤素，硝基，氰基，环烷基，甲酰氨基，二烷基或二氧戊环，或烷基，烯基，炔基，烷氧基，链烯氧基，炔氧基，烷基巯基，烯基巯基，炔基巯基或 每个脂族部分具有至多4个碳原子的二烷基氨基，或下式的肟基团R 4和R 5各自独立地为氰基或烷基，烷氧基，烷硫基，烷氧基羰基，二烷基氨基甲酰基或每烷基具有至多4个碳原子的二烷氧基磷酰基 部分，或R 4和R 5与相邻的碳原子一起形成任选的甲基 - 或苯基取代的二硫戊环，二噻烷，氧硫杂环戊烷或氧硫杂环。
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7.发明授权
公开(公告)号：US4113876A
公开(公告)日：1978-09-12
申请号：US592860
申请日：1975-07-02
IPC分类号： A01N47/24 , A01P5/00 , A01P7/02 , A01P7/04 , C07C67/00 , C07C325/00 , C07C381/08 , C07D307/86 , C07D317/18 , C07D317/24 , C07D317/46 , A01N9/16 , C07D317/28
CPC分类号： C07D317/24 , A01N47/24 , C07D317/46
摘要： Sulfonic acid-N'-methylamido-N'-sulfenyl-N-methyl-carbamic acid esters of the formula ##STR1## in which R.sup.1 is dialkylamino with 1-4 carbon atoms in each alkyl group, phenyl substituted in the o- or m-position by halogen or by alkyl with 1-4 carbon atoms, or phenyl substituted in the o-, m- or p-position by NO.sub.2, CF.sub.3 or CN, andR.sup.2 is phenyl, naphthyl, benzodioxolanyl or indanyl; phenyl, naphthyl, benzodioxolanyl or indanyl substituted by trihalogenomethyl, halogen, nitro, cyano, formamidino, dioxanyl or dioxolanyl, or by alkyl, alkenyl, alkynyl, alkoxy, alkenoxy, alkynoxy, alkylmercapto, alkenylmercapto or dialkylamino wherein each hydrocarbon portion has 1-4 carbon atoms; cycloalkyl of 5-7 carbon atoms, or ##STR2## in which R.sup.3 and R.sup.4 each independently is cyano or alkyl, alkoxy, alkylthio or alkoxycarbonyl with 1-4 carbon atoms in each alkyl group, or R.sup.3 and R.sup.4 together form a ring, or, provided that R.sup.1 is a NO.sub.2 -substituted phenyl, R.sup.2 may be dihydrobenzofuranyl or dihydrobenzofuranyl substituted by alkyl of 1-4 cabon atoms,Which possess insecticidal, acaricidal, nematicidal, fungicidal and herbicidal properties.
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8.发明授权N-methyl-N-(3-trifluoromethylphenylsulfenyl)-carbonyloxime-carbamates 失效N-甲基-N-（3-三氟甲基苯基硫基） - 羰基肟 - 氨基甲酸酯
公开(公告)号：US4008328A
公开(公告)日：1977-02-15
申请号：US552502
申请日：1975-02-24
IPC分类号： A01N47/24 , C07C67/00 , C07C313/00 , C07C313/32 , C07D339/06 , A01N9/00 , C07C83/08
CPC分类号： A01N47/24 , C07D339/06
摘要： N-methyl-N-(3-trifluoromethylphenylsulfenyl)-carbonyloxime-carbamates of the formula ##STR1## in which R.sup.1 and R.sup.2 each independently is hydrogen, alkyl, alkenyl, alkynyl, alkoxy, alkylthio, alkoxycarbonyl, aminocarbonyl or alkylthioalkyl, or together are ##STR2## R.sub.3 is hydrogen or halogen, R.sub.4 is hydrogen or C.sub.1 -C.sub.4 alkyl, andX is oxygen or sulfur,Which possess insecticidal, acaricidal, nematicidal, fungicidal and bactericidal properties.
摘要翻译： 式（I）的N-甲基-N-（3-三氟甲基苯基硫基） - 羰基肟 - 氨基甲酸酯其中R 1和R 2各自独立地为氢，烷基，烯基，炔基，烷氧基，烷硫基，烷氧基羰基，氨基羰基或烷硫基烷基， 或者一起是R 3是氢或卤素，R 4是氢或C 1 -C 4烷基，X是氧或硫，其具有杀虫剂，杀虫剂，杀虫剂，杀真菌剂和杀菌剂的特性。
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9.发明授权Sulfonic acid-N'-methylamido-N'-sulfenyl-N-methyl-carbamic acid esters 失效磺酸-N'-甲基酰氨基-N'-磺酰基-N-甲基 - 氨基甲酸酯
公开(公告)号：US4212883A
公开(公告)日：1980-07-15
申请号：US900386
申请日：1978-04-24
IPC分类号： A01N47/24 , C07D317/24 , C07D317/46 , A01N9/16 , C07D339/02
CPC分类号： C07D317/24 , A01N47/24 , C07D317/46
摘要： Sulfonic acid-N'-methylamide-N'-sulfenyl-N-methyl-carbamic acid esters of the formula ##STR1## in which R.sup.1 is dialkylamino with 1-4 carbon atoms in each alkyl group, phenyl substituted in the o- or m-position by halogen or by alkyl with 1-4 carbon atoms, or phenyl substituted in the o-, m- or p-position by NO.sub.2, CF.sub.3 or CN, andR.sup.2 is phenyl, naphthyl, benzodioxolanyl or indanyl; phenyl, naphthyl, benzodioxolanyl or indanyl substituted by trihalogenomethyl, halogen, nitro, cyano, formamidino, dioxanyl or dioxolanyl, or by alkyl, alkenyl, alkynyl, alkoxy, alkenoxy, alkynoxy, alkylmercapto, alkenylmercapto or dialkylamino wherein each hydrocarbon portion has 1-4 carbon atoms; cycloalkyl of 5-7 carbon atoms, or ##STR2## in which R .sup.3 and R.sup.4 each independently is cyano or alkyl, alkoxy, alkylthio or alkoxycarbonyl with 1-4 carbon atoms in each alkyl group, or R.sup.3 and R.sup.4 together form a ring, or, provided that R.sup.1 is a NO.sub.2 -substituted phenyl, R.sup.3 and R.sup.4 may be dihydrobenzofuranyl or dihydrobenzofuranyl substituted by alkyl of 1-4 carbon atoms,which possess insecticidal, acaricidal, nematicidal, fungicidal and herbicidal properties.
摘要翻译： 其中R 1是每个烷基中具有1-4个碳原子的二烷基氨基，在o取代的苯基的磺酸-N'-甲酰胺-N'-磺酰基-N-甲基 - 氨基甲酸酯 - 或 - 位置被卤素或具有1-4个碳原子的烷基取代，或在由O-，m-或p-位置被NO 2，CF 3或CN取代的苯基，R 2是苯基，萘基，苯并二恶烷基或茚满基; 苯基，萘基，苯并二氧杂环戊烷基或被三卤甲基，卤素，硝基，氰基，甲酰氨基，二烷基或二氧戊环基取代的茚满基，或被烷基，烯基，炔基，烷氧基，链烯氧基，炔氧基，烷基巯基，烯基巯基或二烷基氨基取代， 碳原子 或者其中R 3和R 4各自独立地为氰基或烷基，烷氧基，烷硫基或烷基中具有1-4个碳原子的烷氧基羰基，或者R 3和R 4一起形成环， 或者如果R 1是NO 2取代的苯基，则R 3和R 4可以是被1-4个碳原子的烷基取代的二氢苯并呋喃基或二氢苯并呋喃基，其具有杀虫，杀螨，杀线虫，杀真菌和除草性质。
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10.发明授权N-sulfenylate-N-methyl-carbamic acid esters of 2-oximino-alkanecarboxylic acid nitriles 失效2-肟基 - 链烷羧酸腈的N-亚磺酰基-N-甲基 - 氨基甲酸酯
公开(公告)号：US3939192A
公开(公告)日：1976-02-17
申请号：US441599
申请日：1974-02-11
IPC分类号： A01N47/24 , C07C67/00 , C07C313/00 , C07C313/32 , C07C119/00
CPC分类号： A01N47/24
摘要： N-sulfenylated-N-methyl-carbamic acid esters of 2-oximino-alkanecarboxylic acid nitriles of the formula ##EQU1## in which R.sub.1 is alkyl, cycloalkyl, or alkyl-substituted cycloalkyl, andR.sub.2 is a C.sub.1-8 aliphatic radical substituted by halogen; aryl; aryl substituted by halogen, methyl, trifluoromethyl or nitro; or the radical of the formula ##EQU2## wherein R.sub.3 is alkyl, andR.sub.4 is alkyl, haloalkyl, aryl, or aryl substituted by halogen, methyl or nitro,Which possess insecticidal, acaricidal, fungicidal and bactericidal properties.
摘要翻译： 式中R 1是烷基，环烷基或烷基取代的环烷基的2-肟基 - 亚烷基羧酸腈的N-亚磺酰化N-甲基 - 氨基甲酸酯R 1 -C = NOC-N ANGLE ，R2为被卤素取代的C1-8脂族基团; 芳基; 被卤素，甲基，三氟甲基或硝基取代的芳基; 或式R 3 | R 4 -SO 2 -N-的基团，其中R 3是烷基，且R 4是被卤素，甲基或硝基取代的烷基，卤代烷基，芳基或芳基，其具有杀虫剂，杀虫剂，杀真菌剂和杀真菌性质。
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