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    Reforming with two fixed-bed units, each having a moving-bed tail reactor sharing a common regenerator
    1.
    发明授权
    Reforming with two fixed-bed units, each having a moving-bed tail reactor sharing a common regenerator 失效
    用两台固定床单元进行改造，每个固定床单元具有一个共同使用共同的再生器的移动床尾反应器

    公开(公告)号：US5417843A

    公开(公告)日：1995-05-23

    申请号：US245844

    申请日：1994-05-18

    申请人： Gerrit S. Swart ,  Stuart S. Goldstein ,  Paul W. Kamienski ,  George A. Swan, III

    发明人： Gerrit S. Swart ,  Stuart S. Goldstein ,  Paul W. Kamienski ,  George A. Swan, III

    IPC分类号： C10G59/00 ,  C10G35/085

    CPC分类号： C10G59/00

    摘要： A process for reforming a gasoline boiling range naphtha stream using a reforming process unit comprised of two independent process units, each of which are operated in two stages. The first stage is operated in a fixed-bed mode and is comprised of a plurality of serially connected fixed bed reactors, and the second stage is operated in a moving bed continuous catalyst regeneration mode. A hydrogen-rich stream is recycled through both stages for each process unit and the moving-bed reforming zones share a common regeneration zone.

    摘要翻译： 使用由两个独立的处理单元组成的重整处理单元重整汽油沸程石脑油流的方法，每个独立的处理单元分两个阶段进行操作。 第一阶段以固定床模式操作，并且由多个串联连接的固定床反应器组成，第二阶段在移动床连续催化剂再生模式下操作。 对于每个处理单元，富氢流被循环通过两个阶段，并且移动床重整区共享共同的再生区。

    Fixed-bed/moving-bed two stage catalytic reforming
    3.
    发明授权
    Fixed-bed/moving-bed two stage catalytic reforming 失效
    固定床/移动床两级催化重整

    公开(公告)号：US5354451A

    公开(公告)日：1994-10-11

    申请号：US805360

    申请日：1991-12-09

    申请人： Stuart S. Goldstein ,  Paul W. Kamienski ,  David W. Staubs ,  Gerrit S. Swart ,  George A. Swan, III

    发明人： Stuart S. Goldstein ,  Paul W. Kamienski ,  David W. Staubs ,  Gerrit S. Swart ,  George A. Swan, III

    IPC分类号： C10G59/02 ,  C10G35/04

    CPC分类号： C10G59/02

    摘要： A two stage process for catalytically reforming a gasoline boiling range hydrocarbonaceous feedstock. The reforming is conducted in two stages wherein the first stage is operated in a fixed-bed mode, and the second stage is operated in a moving-bed continual catalyst regeneration mode. A gaseous stream comprised of hydrogen and predominantly C.sub.4.sup.-- hydrocarbon gases are separated between stages. A portion of the hydrogen-rich gaseous stream is recycled and the remaining portion along with the C.sub.5.sup.+ stream are sent to second stage reforming.

    摘要翻译： 催化重整汽油沸程烃原料的两阶段方法。 重整在两个阶段进行，其中第一阶段以固定床模式操作，第二阶段以移动床连续催化剂再生模式操作。 由氢和主要是C4-烃气体组成的气流在两个阶段之间分离。 一部分富氢气流被再循环，剩余部分与C5 +流一起送入第二级重整。

    Fixed-bed/moving-bed two stage catalytic reforming with interstage aromatics removal
    4.
    发明授权
    Fixed-bed/moving-bed two stage catalytic reforming with interstage aromatics removal 失效
    固定床/移动床两级催化重整与阶段芳烃去除

    公开(公告)号：US5211838A

    公开(公告)日：1993-05-18

    申请号：US805334

    申请日：1991-12-09

    申请人： Staubs, David W. ,  Stuart S. Goldstein ,  Paul W. Kamienski ,  Gerrit S. Swart ,  George A. Swan, III ,  Kenneth R. Clem

    发明人： Staubs, David W. ,  Stuart S. Goldstein ,  Paul W. Kamienski ,  Gerrit S. Swart ,  George A. Swan, III ,  Kenneth R. Clem

    IPC分类号： C10G59/02

    CPC分类号： C10G59/02

    摘要： A two stage process for catalytically reforming a gasoline boiling range hydrocarbonaceous feedstock. The reforming is conducted in two stages wherein the first stage is operated in a fixed bed mode, and the second stage is operated in a moving bed continual catalyst regeneration mode. A gaseous stream comprised of hydrogen and predominantly C.sub.4.sup.- and a C.sub.5.sup.+ liquid stream are produced between stages. A portion of the hydrogen-rich stream is recycled and the and the remaining portion and an aromatics-lean stream, which is obtained during aromatics separation between stages, is sent to second stage reforming.

    摘要翻译： 催化重整汽油沸程烃原料的两阶段方法。 重整在两个阶段进行，其中第一阶段以固定床模式操作，第二阶段在移动床连续催化剂再生模式下操作。 在级之间产生由氢气和主要为C4-和C5 +液体流组成的气流。 一部分富氢流被再循环，并且在阶段之间的芳烃分离期间获得的剩余部分和贫芳烃流被送到第二阶段重整。

    Production of methanol via catalytic coal gasification
    7.
    发明授权
    Production of methanol via catalytic coal gasification 失效
    通过催化煤气化生产甲醇

    公开(公告)号：US4348487A

    公开(公告)日：1982-09-07

    申请号：US317358

    申请日：1981-11-02

    申请人： Stuart S. Goldstein ,  William J. Calvin ,  Harry A. Marshall

    发明人： Stuart S. Goldstein ,  William J. Calvin ,  Harry A. Marshall

    IPC分类号： C07C29/151 ,  C10J3/54 ,  C07C27/06 ,  C07C31/04

    CPC分类号： C10J3/482 ,  C07C29/1518 ,  C10J3/54 ,  C10K1/101 ,  C10J2300/0903 ,  C10J2300/093 ,  C10J2300/0973 ,  C10J2300/0986 ,  C10J2300/1665 ,  C10J2300/1807 ,  C10J2300/1823 ,  C10J2300/1853 ,  C10J2300/1884 ,  C10J2300/1892

    摘要： Methanol is produced by gasifying a carbonaceous feed material with steam in the presence of a carbon-alkali metal catalyst and added hydrogen and carbon monoxide at a temperature between about 1000.degree. F. and about 1500.degree. F. and at a pressure in excess of about 100 psia to produce a raw product gas comprising methane, steam, carbon dioxide, carbon monoxide, hydrogen and hydrogen sulfide; withdrawing the raw product gas from the gasifier and treating it for the removal of steam, particulates, hydrogen sulfide and carbon dioxide to produce a treated gas containing primarily carbon monoxide, hydrogen and methane; separating the treated gas into a methane-rich gas stream and a gas stream containing primarily carbon monoxide and hydrogen; passing the gas stream containing primarily carbon monoxide and hydrogen to a methanol synthesis reactor where the carbon monoxide is reacted with the hydrogen in the presence of a methanol synthesis catalyst to form methanol; recovering methanol product from the effluent exiting the methanol synthesis reactor thereby leaving a gas comprised of carbon monoxide, hydrogen, methane and carbon dioxide; and passing a portion of this gas to a steam reforming furnace wherein at least a portion of the methane is reacted with steam to produce hydrogen and carbon monoxide which is then passed from the steam reforming furnace into the gasifier. Preferably, at least a portion of the methane-rich gas produced in the separation step is used as fuel for the steam reforming furnace.

    摘要翻译： 甲醇是通过在碳 - 碱金属催化剂的存在下用蒸汽气化碳质进料而生成的，并在约1000°F至约1500°F的温度下加入氢和一氧化碳，并且在超过约 100psia以产生包含甲烷，蒸汽，二氧化碳，一氧化碳，氢气和硫化氢的原始产物气体; 从气化器中取出原始产物气体并处理它以除去蒸汽，微粒，硫化氢和二氧化碳，以产生主要包含一氧化碳，氢气和甲烷的处理气体; 将处理的气体分离成富甲烷气流和主要包含一氧化碳和氢气的气流; 将主要包含一氧化碳和氢气的气流通入甲醇合成反应器，在甲醇合成反应器中，一氧化碳在甲醇合成催化剂存在下与氢气反应形成甲醇; 从离开甲醇合成反应器的流出物中回收甲醇产物，从而留下由一氧化碳，氢气，甲烷和二氧化碳组成的气体; 并将该气体的一部分通入蒸汽重整炉，其中至少一部分甲烷与蒸汽反应以产生氢气和一氧化碳，然后将其从蒸汽重整炉送入气化器。 优选地，在分离步骤中产生的至少一部分富甲烷气体用作蒸汽重整炉的燃料。

    Production of methanol via catalytic coal gasification
    9.
    发明授权
    Production of methanol via catalytic coal gasification 失效
    通过催化煤气化生产甲醇

    公开(公告)号：US4348486A

    公开(公告)日：1982-09-07

    申请号：US296713

    申请日：1981-08-27

    申请人： William J. Calvin ,  Stuart S. Goldstein ,  Harry A. Marshall

    发明人： William J. Calvin ,  Stuart S. Goldstein ,  Harry A. Marshall

    IPC分类号： C07C29/151 ,  C10J3/54 ,  C07C27/06

    CPC分类号： C10J3/54 ,  C07C29/1518 ,  C10K1/101 ,  C10J2300/1615

    摘要： Methanol is produced by gasifying a carbonaceous feed material with steam in the presence of a carbon-alkali metal catalyst and added hydrogen and carbon monoxide at a temperature between about 1000.degree. F. and about 1500.degree. F. and at a pressure in excess of about 100 psia to produce a raw product gas comprising methane, steam, carbon dioxide, carbon monoxide, hydrogen and hydrogen sulfide; withdrawing the raw product gas from the gasifier and treating it for the removal of steam, particulates, hydrogen sulfide and carbon dioxide to produce a treated gas containing primarily carbon monoxide, hydrogen and methane; separating the treated gas into a methane-rich gas stream and a gas stream containing primarily carbon monoxide and hydrogen; passing the methane-rich gas stream to a steam reforming furnace wherein a portion of the methane is reacted with steam to produce hydrogen and carbon monoxide which is then passed from the steam reforming furnace into the gasifier; passing the gas stream containing primarily carbon monoxide and hydrogen to a methanol synthesis reactor where the carbon monoxide is reacted with the hydrogen in the presence of a methanol synthesis catalyst to form methanol; recovering methanol product from the effluent exiting the methanol synthesis reactor thereby leaving a gas comprised of carbon monoxide, hydrogen, methane and carbon dioxide; and recycling at least a portion of this gas to the separation step of the process.

    摘要翻译： 甲醇是通过在碳 - 碱金属催化剂的存在下用蒸汽气化碳质进料而生成的，并在约1000°F至约1500°F的温度下加入氢和一氧化碳，并且在超过约 100psia以产生包含甲烷，蒸汽，二氧化碳，一氧化碳，氢气和硫化氢的原始产物气体; 从气化器中取出原始产物气体并处理它以除去蒸汽，微粒，硫化氢和二氧化碳，以产生主要包含一氧化碳，氢气和甲烷的处理气体; 将处理的气体分离成富甲烷气流和主要包含一氧化碳和氢气的气流; 将富甲烷气流送至蒸汽重整炉，其中一部分甲烷与蒸汽反应产生氢气和一氧化碳，然后将其从蒸汽重整炉送入气化器; 将主要包含一氧化碳和氢气的气流通入甲醇合成反应器，在甲醇合成反应器中，一氧化碳在甲醇合成催化剂存在下与氢气反应形成甲醇; 从离开甲醇合成反应器的流出物中回收甲醇产物，从而留下由一氧化碳，氢气，甲烷和二氧化碳组成的气体; 并将该气体的至少一部分再循环至该方法的分离步骤。