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1.发明授权公开(公告)号：US07397241B2
公开(公告)日：2008-07-08
申请号：US11119413
申请日：2005-04-29
IPC分类号： G01V3/00
摘要： A method is described for determination of the content of at least one component of a sample by means of a nuclear magnetic resonance pulse spectrometer, with the magnetization of the sample being influenced by a sequence of radio-frequency pulses such that the signal amplitudes to be observed can be determined. The magnetization of the sample is initially saturated, and the signal amplitudes which are determined at each time by the longitudinal and transverse relaxation times T1 and T2 and/or T2* and/or T1p, from which a value for the content of the at least one component is determined, are measured at the same time in a cohesive experimental procedure.
摘要翻译： 描述了通过核磁共振脉冲光谱仪确定样品的至少一个组分的含量的方法，其中样品的磁化受到一系列射频脉冲的影响，使得信号幅度为 观察可以确定。 样品的磁化最初饱和，并且每次通过纵向和横向弛豫时间T 1和T 2和/或T 2确定的信号幅度， 在粘性实验过程中同时测量从其中确定至少一种组分的含量的值的第二个和第二个碱基和/或T 1p 。
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2.发明授权Method and apparatus for investigating the imperishability of liquid foodstuffs by means of electron spin resonance 有权通过电子自旋共振研究液体食品的不均匀性的方法和装置公开(公告)号：US06462546B1
公开(公告)日：2002-10-08
申请号：US09700929
申请日：2000-11-21
IPC分类号： G01V300
CPC分类号： G01R33/307 , G01R33/60
摘要： A method and an apparatus for investigating the imperishability of n liquid foodstuffs using electron spin resonance (ESR) exposes samples of the foodstuffs to an elevated temperature for an extended time-period. At predetermined intervals during the period, the intensity of an ESR signal of each sample is measured and plotted vs. time in a diagram for that sample. The time of a superproportional increase in intensity is detected for each foodstuff. The number n of different foodstuffs is determined by dividing the predetermined interval by the measurement time. The n samples are investigated simultaneously by sequentially cycling the n samples through a common sample vessel. Each time, the intensity of the ESR signal of the sample is measured and then plotted in a diagram unique to that foodstuff. The sequence of foodstuffs are cycled through the sample vessel until a predetermined number m of measuring points per foodstuff has been attained.
摘要翻译： 使用电子自旋共振（ESR）研究n种液体食品不均匀性的方法和装置将食品样品暴露于升高的温度下延长时间。 在该期间的预定间隔，测量每个样品的ESR信号的强度，并对该样品的图中的时间作图。 每种食品都会检测到强度超比例增加的时间。 通过将预定间隔除以测量时间来确定不同食物的数量n。 通过将n个样品顺序循环通过普通的样品容器来同时研究n个样品。 每次测量样品的ESR信号的强度，然后绘制在该食品独特的图中。 食物的顺序循环通过样品容器，直到达到每个食物预定数量的测量点。
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3.发明授权Resonator apparatus for electron spin resonance (ESR) measurements and method for measuring electron spin resonance (ESR) signals 有权用于电子自旋共振（ESR）测量的谐振器装置和用于测量电子自旋共振（ESR）信号的方法公开(公告)号：US07391212B2
公开(公告)日：2008-06-24
申请号：US10197236
申请日：2002-07-15
IPC分类号： G01V3/00
CPC分类号： G01R33/307 , G01R33/34 , G01R33/60
摘要： A resonator apparatus and a method for electron spin resonance (ESR) measurements are disclosed. The resonator apparatus comprises a dielectric resonator and a sample vessel extending through the resonator. The sample vessel is configured as one single flexible tube. Means are provided for conveying a liquid sample substance through the flexible tube. According to the method a liquid sample substance is guided through the sample vessel, wherein the sample substance is gated by cyclically conveying and stopping, resp., a flow of the sample substance. A measurement is conducted within the resonator when the flow of sample substance is stopped.
摘要翻译： 公开了一种用于电子自旋共振（ESR）测量的谐振器装置和方法。 谐振器装置包括介质谐振器和延伸穿过谐振器的样品容器。 样品容器配置为单个柔性管。 提供用于通过柔性管输送液体样品物质的装置。 根据该方法，液体样品物质被引导通过样品容器，其中通过循环输送和停止或样品物质的流动来选择样品物质。 当样品物质的流动停止时，在谐振器内进行测量。
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4.发明授权公开(公告)号：US07838298B2
公开(公告)日：2010-11-23
申请号：US11252223
申请日：2005-10-17
CPC分类号： G01N24/08 , G01R33/30 , G01R33/343
摘要： A method and an apparatus serve the purpose of determining the fat or oil content of a sample. The sample is dried under the action of a microwave field and is examined under the action of a radio-frequency signal and of a constant magnetic field by means of nuclear magnetic resonance. The sample is exposed to the microwave field, the radio-frequency signal and the magnetic field at the same measuring place in a common measuring chamber. The apparatus has a microwave source for drying the sample, a magnetic system for generating a nuclear magnetic resonance magnetic field in the sample, and a nuclear magnetic resonance measuring arrangement for irradiating radio-frequency signals into the sample and for receiving excited nuclear magnetic resonance signals from the sample. The microwave source, the magnetic system and the nuclear magnetic resonance measuring arrangement are connected to a common measuring chamber in which the sample is located.
摘要翻译： 方法和装置用于确定样品的脂肪或油含量的目的。 样品在微波场作用下干燥，并通过核磁共振在射频信号和恒定磁场的作用下进行检测。 样品暴露于微波场，射频信号和在同一测量室中相同测量位置处的磁场。 该装置具有用于干燥样品的微波源，用于在样品中产生核磁共振磁场的磁系统和用于将射频信号照射到样品中并用于接收激发的核磁共振信号的核磁共振测量装置 从样品。 微波源，磁系统和核磁共振测量装置连接到样品所在的公共测量室。
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5.发明申请公开(公告)号：US20070010021A1
公开(公告)日：2007-01-11
申请号：US11252223
申请日：2005-10-17
IPC分类号： G01N33/92
CPC分类号： G01N24/08 , G01R33/30 , G01R33/343
摘要： A method and an apparatus serve the purpose of determining the fat or oil content of a sample. The sample is dried under the action of a microwave field and is examined under the action of a radio-frequency signal and of a constant magnetic field by means of nuclear magnetic resonance. The sample is exposed to the microwave field, the radio-frequency signal and the magnetic field at the same measuring place in a common measuring chamber. The apparatus has a microwave source for drying the sample, a magnetic system for generating a nuclear magnetic resonance magnetic field in the sample, and a nuclear magnetic resonance measuring arrangement for irradiating radio-frequency signals into the sample and for receiving excited nuclear magnetic resonance signals from the sample. The microwave source, the magnetic system and the nuclear magnetic resonance measuring arrangement are connected to a common measuring chamber in which the sample is located.
摘要翻译： 方法和装置用于确定样品的脂肪或油含量的目的。 样品在微波场作用下干燥，并通过核磁共振在射频信号和恒定磁场的作用下进行检测。 样品暴露于微波场，射频信号和在同一测量室中相同测量位置处的磁场。 该装置具有用于干燥样品的微波源，用于在样品中产生核磁共振磁场的磁系统和用于将射频信号照射到样品中并用于接收激发的核磁共振信号的核磁共振测量装置 从样品。 微波源，磁系统和核磁共振测量装置连接到样品所在的公共测量室。
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6.发明申请公开(公告)号：US20050270026A1
公开(公告)日：2005-12-08
申请号：US11119413
申请日：2005-04-29
摘要： A method is described for determination of the content of at least one component of a sample by means of a nuclear magnetic resonance pulse spectrometer, with the magnetization of the sample being influenced by a sequence of radio-frequency pulses such that the signal amplitudes to be observed can be determined. The magnetization of the sample is initially saturated, and the signal amplitudes which are determined at each time by the longitudinal and transverse relaxation times T1 and T2 and/or T2* and/or T1p, from which a value for the content of the at least one component is determined, are measured at the same time in a cohesive experimental procedure.
摘要翻译： 描述了通过核磁共振脉冲光谱仪确定样品的至少一个组分的含量的方法，其中样品的磁化受到一系列射频脉冲的影响，使得信号幅度为 观察可以确定。 样品的磁化最初饱和，并且每次通过纵向和横向弛豫时间T 1和T 2和/或T 2确定的信号幅度， 在粘性实验过程中同时测量从其中确定至少一种组分的含量的值的第二个和第二个碱基和/或T 1p 。
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7.发明授权公开(公告)号：US06791324B2
公开(公告)日：2004-09-14
申请号：US10197629
申请日：2002-07-17
申请人： Diether Maier , Dieter Schmalbein , Jin Jie Jiang , Ralph T. Weber , Andreas Kamlowski , Thomas Schmidt
发明人： Diether Maier , Dieter Schmalbein , Jin Jie Jiang , Ralph T. Weber , Andreas Kamlowski , Thomas Schmidt
IPC分类号： G01V300
CPC分类号： G01R33/28 , G01R33/30 , G01R33/443 , G01R33/60
摘要： A probehead for an electron spin resonance (ESR) dosimeter comprises a resonator and an insert extending into the resonator. The insert has a guide channel for bringing a sample into the resonator. The sample comprises a dosimeter substance. The guide channel is configured for receiving and guiding a test strip. The insert is provided with a first machine-readable code imprint. The insert is provided with at least one reference sample. A pressurized air unit is provided for blowing the sample out of the resonator after completion of a measurement. The insert has an opening on an upper side of the resonator. The opening is openly accessible for manually inserting dosimeter pills thereinto. The insert, further, is provided on the upper side with a pressurized air connector. The pressurized air connector is connected to an orifice via a pressurized air channel within the insert. The orifice is located within a lower, otherwise closed bottom of the guide channel. The sample substance comprises a chromium-doped magnesium oxide (Cr:MgO). The magnesium oxide is doped with the isotope 52Cr.
摘要翻译： 用于电子自旋共振（ESR）剂量计的探头包括谐振器和延伸到谐振器中的插入件。 插入件具有用于将样品带入谐振器的引导通道。 样品包含剂量计物质。 引导通道被配置为用于接收和引导测试条。 该插入件具有第一机器可读代码印记。 插入件具有至少一个参考样品。 提供加压空气单元，用于在完成测量之后将样品吹出谐振器。 插入件在谐振器的上侧具有开口。 开口是公开的手动插入剂量计药丸。 此外，插入件在上侧设置有加压空气连接器。 加压空气连接器通过插入件内的加压空气通道连接到孔口。 孔口位于引导通道的下部或另外封闭的底部。 样品物质包含掺杂铬的氧化镁（Cr：MgO）。 氧化镁掺杂有同位素<52> Cr。
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8.发明授权Analysis system with GPC and NMR spectroscopy coupling, in particular for the analysis of samples having polymers 有权具有GPC和NMR光谱耦合的分析系统，特别是用于分析具有聚合物的样品公开(公告)号：US08624599B2
公开(公告)日：2014-01-07
申请号：US12929748
申请日：2011-02-14
IPC分类号： G01V3/00
CPC分类号： G01R33/307 , G01N30/467 , G01N30/62 , G01N30/78 , G01R33/46
摘要： An analysis system (1) for the analysis of a sample, comprises a gel permeation chromatograph (14) that is coupled with a nuclear magnetic resonance (=NMR) spectrometer. The chromatograph (14) has a gel permeation chromatography (=GPC) separating column system (6a) that is filled with porous particles (21). The NMR spectrometer is configured as a low-field NMR spectrometer (8) with a permanent magnet system (9) for generating a B0 field of the NMR spectrometer. The low-field NMR spectrometer (8) comprises a shim system (10) with which homogeneity of the B0 field of at least 0.5 ppm can be achieved in a right circular cylindrical sample volume (27) having a diameter of at least 5 mm and a length of at least 15 mm. The system permits the quantitative and qualitative chemical analysis of samples containing substances of different molecular size using a less expensive apparatus.
摘要翻译： 用于分析样品的分析系统（1）包括与核磁共振（= NMR）光谱仪耦合的凝胶渗透色谱仪（14）。 色谱仪（14）具有填充有多孔颗粒（21）的凝胶渗透色谱（= GPC）分离柱系统（6a）。 NMR光谱仪被配置为具有用于产生NMR光谱仪的B0场的永磁体系统（9）的低场NMR光谱仪（8）。 低场NMR光谱仪（8）包括垫片系统（10），其直径为至少5mm的右圆形圆柱形样品体积（27）可以实现至少0.5ppm的B0场的均匀性， 长度至少为15毫米。 该系统允许使用较便宜的装置对含有不同分子尺寸的物质的样品进行定量和定性化学分析。
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9.发明申请Analysis system with GPC and NMR spectroscopy coupling, in particular for the analysis of samples having polymers 有权具有GPC和NMR光谱耦合的分析系统，特别是用于分析具有聚合物的样品公开(公告)号：US20110204894A1
公开(公告)日：2011-08-25
申请号：US12929748
申请日：2011-02-14
CPC分类号： G01R33/307 , G01N30/467 , G01N30/62 , G01N30/78 , G01R33/46
摘要： An analysis system (1) for the analysis of a sample, comprises a gel permeation chromatograph (14) that is coupled with a nuclear magnetic resonance(=NMR) spectrometer. The chromatograph (14) has a gel permeation chromatography(=GPC) separating column system (6a) that is filled with porous particles (21). The GPC separating column system (6a) includes at least the one GPC separating column (6), the GPC separating columns (6) of the GPC separating column system (6a) having an overall combined internal volume of at least 45 cm3, preferably at least 100 cm3. The NMR spectrometer is configured as a low-field NMR spectrometer (8) with a permanent magnet system (9) for generating a B0 field of the NMR spectrometer. The low-field NMR spectrometer (8) comprises a shim system (10) with which homogeneity of the B0 field of 0.5 ppm or better, preferably 0.1 ppm or better, can be achieved in a right circular cylindrical sample volume (27) having a diameter of at least 5 mm and a length of at least 15 mm. The low-field NMR spectrometer (8) further comprises a lock function (29) to compensate for a drift of the B0 field. The invention permits the quantitative and qualitative chemical analysis of samples containing substances of different molecular size with less expensive apparatus.
摘要翻译： 用于分析样品的分析系统（1）包括与核磁共振（= NMR）光谱仪耦合的凝胶渗透色谱仪（14）。 色谱仪（14）具有填充有多孔颗粒（21）的凝胶渗透色谱（= GPC）分离柱系统（6a）。 GPC分离塔系统（6a）至少包括一个GPC分离塔（6），GPC分离塔系统（6a）的GPC分离柱（6）的总体内部体积至少为45cm 3，优选地 至少100 cm3。 NMR光谱仪被配置为具有用于产生NMR光谱仪的B0场的永磁体系统（9）的低场NMR光谱仪（8）。 低场NMR光谱仪（8）包括一个垫片系统（10），其中B0场的均匀性在0.5ppm或更好，优选0.1ppm或更好的情况下可以在具有 直径至少为5mm，长度至少为15mm。 低场NMR光谱仪（8）还包括用于补偿B0场漂移的锁定功能（29）。 本发明允许对具有不同分子尺寸的物质的样品进行定量和定性化学分析，其中较便宜的装置。
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